• Journal of Electrochemical Science and Technology
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• 제15권1호
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• pp.96-110
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• 2024

Polymer electrolyte membrane fuel cells (PEMFCs) are green energy conversion devices, for which commercial markets have been established, owing to their application in fuel cell vehicles (FCVs). Development of cathode electrocatalysts, replacing commercial Pt/C, plays a crucial role in factors such as cost reduction, high performance, and durability in FCVs. PtNi octahedral catalysts are promising for oxygen reduction reactions owing to their significantly higher mass activity (10-15 times) than that of Pt/C; however, their application in membrane electrode assemblies (MEAs) is challenged by their low stability. To overcome this durability issue, various approaches, such as third-metal doping, composition control, halide treatment, formation of a Pt layer, annealing treatment, and size control, have been explored and have shown promising improvements in stability in rotating disk electrode (RDE) testing. In this review, we aimed to compare the features of each strategy in terms of enhancing stability by introducing a stability improvement factor for a direct and reasonable comparison. The limitations of each strategy for enhancing stability of PtNi octahedral are also described. This review can serve as a valuable guide for the development of strategies to enhance the durability of octahedral PtNi.

• 전기학회논문지
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• 제60권5호
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• pp.1068-1072
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• 2011

Hydrogen Fuel Cell Vehicle(HFCV) is system that uses electrical energy of fuel cell stack to main power source, which is different system with other vehicles that use high-voltage, large-current. Isolation performance of this system which is connected with electrical fire and electrical shock is important point. Isolation resistance of electric installation is divided according to working voltage, it follows criterion more than $100{\Omega}$/VDC (or $500{\Omega}$/VAC) about system operation voltage in a hydrogen fuel cell vehicle. Although measurement of isolation resistance in a hydrogen fuel cell vehicle is two methods, it uses mainly measurement by megger. However, the present isolation resistance measurement system that is optimized to use in electrical facilities is unsuitable for isolation performance estimation of a hydrogen fuel cell vehicle because of limit of maximum short current and difference of measurement resolution. Therefore, this research developed the isolation resistance measurement system so that may be suitable in isolation performance estimation of a hydrogen fuel cell vehicle, verified isolation performance about known resistance by performance verification of laboratory level about developed system, and executed performance verification through comparing results of developed system by performance verification of vehicle level with ones of existing megger. Developed system is judged to aid estimation and upgrade of isolation performance in a hydrogen fuel cell vehicle hereafter.

• 한국수소및신에너지학회논문집
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• 제24권4호
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• pp.311-319
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• 2013

A clear understanding on cell voltage-reversal behavior due to local hydrogen starvation in a stack is of paramount importance to operate the fuel cell vehicle (FCV) stably since it affects significantly the cell performance and durability. In the present study, a novel experimental method to simulate the local cell voltage-reversal behavior caused by local hydrogen starvation, which typically occurs only one or several cells out of several hundred cells in a stack of FCV, has been proposed. Contrary to the conventional method of overall fuel starvation, the present method of local hydrogen starvation caused the local cell voltage-reversal behavior in a stack very well. Degradation of both membrane electrode assembly (i.e., pin-hole formation) and gas diffusion layer due to an excessive exothermic heat under voltage-reversal condition was also observed clearly.

• 한국수소및신에너지학회논문집
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• 제33권6호
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• pp.819-826
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• 2022

Fuel cell systems are being supplied to households and buildings to reduce greenhouse gases. The fuel cell systems have problems of high cost and slow startup due to fuel processors. Greenhouse gas reduction of the fuel cell systems is also limited by using natural gas. The problems can be solved by using a hydrogen generator consisting of a reformer and pressure swing adsorption (PSA). However, part load operation of the hydrogen generator is required depending on the hydrogen consumption. In this paper, PSA operation strategies are investigated for part load of the hydrogen generator. Adsorption and purge time were changed in the range of part load ratio between from 0.5 to 1.0. As adsorption time increased, hydrogen recovery increased from 29.09% to 48.34% at 0.5 of part load ratio. Hydrogen recovery and hydrogen purity were also improved by increasing adsorption and purge time. However, hydrogen recovery dramatically decreased to 35.01% at 0.5 of part load ratio.

• Bulletin of the Korean Chemical Society
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• 제33권2호
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• pp.375-376
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• 2012

• 한국철도학회:학술대회논문집
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• 한국철도학회 2005년도 춘계학술대회 논문집
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• pp.320-325
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• 2005

Power of fuel cell tram is supplied by only fuel cell system or hybrid system of fuel cell and battery/super capacity. Fuel cell is operated by hydrogen, which is fed directly from hydrogen tank or by reforming gasoline or methanol into hydrogen. Power system is preferred with hybrid of fuel cell and battery/super capacity since it improves total energy efficiency through interaction of hybrid components and restores energy regenerated by braking. Also, power supply system by fuel cell hybrid should be designed to output optimum energy efficiency depending on driving mode of fuel cell tram.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 추계학술대회 논문집
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• pp.152-155
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• 2007

Fuel cell electric vehicles (FCEVs) using hydrogen gas are zero emission vehicles, thus emission measurement for combustion vehicles is not applicable. The hydrogen gas consumption for fuel economy will be measured by the stabilized pressure/temperature method, mass flow method and electrical current method, etc. In this research, weight method with a newly manufactured test equipment is applied to measure the hydrogen consumption because above 3-methods have a deviation. The hydrogen consumption is directly calculated by the weight differences of the external hydrogen tank before and after the chassis dynamometer test. Ultimately the fuel economy for FCEVs is obtained with a deviation less than 1% in all chassis dynamometer tests.

• 한국수소및신에너지학회논문집
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• 제31권6호
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• pp.587-595
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• 2020

Nickel-based bimetallic catalysts were investigated for use in direct borohydride/hydrogen peroxide fuel cells. For anode and cathode, PdNi and AuNi catalysts were used, respectively. Nickel-based bimetallic catalysts have been investigated through various methods, such as inductively coupled plasma optical emission spectroscopy, transmission electron microscopy, scanning electron microscopy, and energy dispersive spectroscopy. The performance of the catalysts was evaluated through fuel cell tests. The maximum power density of the fuel cell with nickel-based bimetallic catalysts was found to be higher than that of the fuel cell with the monometallic catalysts. The nickel-based bimetallic catalysts also exhibited a stable performance up to 60 minutes.

• 한국수소및신에너지학회논문집
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• 제30권6호
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• pp.593-600
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• 2019

The combustion characteristics of methane/hydrogen pre-mixed flame have been investigated with swirl stabilized flame in a laboratory-scale pre-mixed combustor with constant heat load of 5.81 kW. Hydrogen/methane fuel and air were mixed in a pre-mixer and introduced to the combustor through a burner nozzle with different degrees of swirl angle. The effects of hydrogen addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using particle image velocimetry (PIV), micro-thermocouples, various optical interference filters and gas analyzers to provide information about flow velocity, temperature distributions, and species concentrations of the reaction field. The results show that higher swirl intensity creates more recirculation flow, which reduces the temperature of the reaction zone and, consequently, reduces the thermal NO production. The distributions of flame radicals (OH, CH, C₂) are dependent more on the swirl intensity than the percentage of hydrogen added to methane fuel. The NO concentration at the upper part of the reaction zone is increased with an increase in hydrogen content in the fuel mixture because higher combustibility of hydrogen assists to promote faster chemical reaction, enabling more expansion of the gases at the upper part of the reaction zone, which reduces the recirculation flow. The CO concentration in the reaction zone is reduced with an increase in hydrogen content because the amount of C content is relatively decreased.

• 한국기계가공학회지
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• 제19권11호
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• pp.1-7
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• 2020

Recently, hydrogen has gained considerable attention as an eco-friendly fuel, which helps in reducing carbon dioxide content. Specifically, there is a growing interest in vehicles powered by a hydrogen fuel cell, which is spotlighted as an environmental-friendly alternative. A hydrogen transport system, fuel cell system, fuel supply system, power management system, and hydrogen storage system are key parts of a hydrogen fuel cell truck. In this study, a hydrogen storage system is built and analyzed. The expansion length of the storage vessel at maximum operating pressure (87.5 MPa) was calculated with ABAQUS, and then the optimized system was designed and built. The leak and bubble tests were performed on the built storage system. The leakage of the system was measured to be under 5 cc/hr. Hence, it can be used as a research test for the safety evaluation of leading systems of hydrogen fuel-powered commercial vehicles.