• Transactions of the Korean hydrogen and new energy society
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• v.9 no.3
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• pp.93-100
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• 1998

The ortho-para $H_2$ catalytic conversion equipment has been developed to reduce the evaporation loss from stored liquid hydrogen. The ortho-para $H_2$ conversion heat is evaluated at liquid nitrogen temperature. This problem is of particular interest in the design of the ortho-para $H_2$ converter in a hydrogen liquefaction system. The ortho-para $H_2$ conversion equipment consists of a catalytic converter, a precooler, and a liquid nitrogen bath. 30-90 cc of $Fe(OH)_3$ are employed as a catalyst in the present converter. The conversion heat and conversion effectiveness are evaluated when mass flow rate of hydrogen is in the range of 0.05-l.6 g/min. It is found that the ortho-para conversion heat is increased while conversion effectiveness is decreased as the mass flow rate of hydrogen is increased. Both the ortho-para conversion heat and conversion effectiveness are increased with an increase in the amount of the catalyst.

• Applied Chemistry for Engineering
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• v.20 no.1
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• pp.104-108
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• 2009

In this study, for the flow of carbon dioxide/hydrogen mixture through a tubular type Pd-Ag membrane, hydrogen partial pressure, velocity profile, and concentration profile were simulated as a function of inlet flow rate using computational fluid dynamics (CFD) technique. The simulation results indicated that the mole fraction of carbon dioxide increased slowly in the longitudinal direction as the flow rate increased. In addition, the effects of inlet flow rate and the length of membrane on hydrogen recovery were investigated. At lower flow rate and for longer membrane, the hydrogen recovery was larger.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.10 no.4
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• pp.324-329
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• 2000

We investigated the effect of hydrogen ion beam on the formation of DLC thin film, which is deposited on the Si substrate with negative carbon ion by $Cs^+$ ion sputtering and positive hydrogen ion by Kauffmann type ion source. The amount of hydrogen in the DLC films increased as increasing hydrogen gas flow rate from 0 sccm to 12 sccm. As increasing hydrogen flow rate, $sp^2$bonding structure increased. The reason is that the hydrogen ions have relatively high energy, although total amount of hydrogen is very small compared with that of CVD process. These results suggest that the physical energy transfer plays a dominant role on the formation of DLC film.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.5
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• pp.534-540
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• 2022

Liquid hydrogen has the best storage capacity per unit mass and is economical among storage methods for using hydrogen as fuel. As the demand for hydrogen increases, the need to develop a storage and supply system of liquid hydrogen is emphasizing. In order to liquefy hydrogen, it is necessary to pre-cool it to a maximum inversion temperature of -253℃. The Gifford-McMahon (GM) refrigerator is the most reliable and commercialized refrigerator among small-capacity cryogenic refrigerators, which can extract high-efficiency hydrogen through liquefied hydrogen production and boil of gas re-liquefaction. Therefore, in this study, the optimal conditions for liquefying gas hydrogen were sought using the GM cryocooler. The process was simulated by PRO/II under various cooling capacities of the GM refrigerator. In addition, the flow rate of hydrogen was calculated by comparing with specific refrigerator capacity depending on the pressure and flow rate of a refrigerant medium, helium. Simulations were performed to investigate the optimal values of the liquefaction flow rate and compression pressure, which aim for the peak refrigeration effect. Based on this, a liquefaction system can be selected in consideration of the cycle configuration and the performance of the refrigerator.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.11
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• pp.942-948
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• 2007

Popular techniques for producing hydrogen by converting methane include steam reforming and catalyst reforming. However, these are high temperature and high pressure processes limited by equipment, cost and difficulty of operation. Low temperature plasma is projected to be a technique that can be used to produce high concentration hydrogen from methane. It is suitable for miniaturization and fur application in other technologies. In this research, the effect of changing each of the following variables was studied using an AC GlidArc system that was conceived by the research team: the gas components ratio, the gas flow rate, the catalyst reactor temperature and voltage. Results were obtained for methane and hydrogen yields and intermediate products. The system used in this research consisted of 3 electrodes and an AC power source. In this study, air was added fur the partial oxidation reaction of methane. The result showed that as the gas flow rate, the catalyst reactor temperature and the electric power increased, the methane conversion rate and the hydrogen concentration also increased. With $O_2/C$ ratio of 0.45, input flow rate of 4.9 l/min and power supply of 1 kW as the reference condition, the methane conversion rate, the high hydrogen selectivity and the reformer energy density were 69.2%, 32.6% and 35.2% respectively.

• Nuclear Engineering and Technology
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• v.55 no.5
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• pp.1742-1756
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• 2023

The hydrogen behavior in a nuclear containment vessel is a significant issue when discussing the potential of hydrogen combustion during a severe accident. After the Fukushima-Daiichi accident in Japan, we have investigated in-depth the hydrogen transport mechanisms by utilizing experimental and numerical approaches. Computational fluid dynamics is a powerful tool for better understanding the transport behavior of gas mixtures, including hydrogen. This paper describes a Large-eddy simulation of gas mixing driven by a high-buoyancy flow. We focused on the interaction behavior of heat and mass transfers driven by the horizontal high-buoyant flow during density stratification. For validation, the experimental data of the Containment InteGral effects Measurement Apparatus (CIGMA) facility were used. With a high-power heater for the gas-injection line in the CIGMA facility, a high-temperature flow of approximately 390 ℃ was injected into the test vessel. By using the CIGMA facility, we can extend the experimental data to the high-temperature region. The phenomenological discussion in this paper helps understand the heat and mass transfer induced by the high-buoyancy flow in the containment vessel during a severe accident.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.32 no.6
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• pp.446-454
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• 2008

The purpose of this paper is to analyze two-phase flows of the hydrogen recirculation system. Two-phase flow modeling is one of the great challenges in the classical sciences. As with most problems in engineering, the interest in two-phase flow is due to its extreme importance in various industrial applications. In hydrogen recirculation systems of fuel cell, the changes in pressure and temperature affect the phase change of mixture. Therefore, two-phase flow analysis of the hydrogen recirculation system is very important. Two-phase computation fluid dynamics (CFD) calculations, using a commercial CFD package FLUENT 6.2, were employed to calculate the gas-liquid flow. A two-phase flow calculation was conducted to solve continuity, momentum, energy equation for each phase. Then, the mass transfer between water vapor and liquid water was calculated. Through an experiment to measure production of liquid water with change of pressure, the analysis model was verified. The predictions of rate of condensed liquid water with change of pressure were within an average error of about 5%. A comparison of experimental and computed data was found to be in good agreement. The variations of performance, properties, mass fraction and two-phase flow characteristic of mixture with resepct to the fuel cell power were investigated.

• Transactions of the Korean hydrogen and new energy society
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• v.26 no.4
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• pp.301-307
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• 2015

We present a study of hydrogen liquefaction using the CFD (Computational Fluid Dynamics) program. Liquid hydrogen has been evaluated as the best storage method because of high energy per unit mass than gas hydrogen, but efficient hydrogen liquefaction and storage are needed in order to apply actual industrial. In this study, we use the CFD program that apply navier-stokes equation. A hydrogen is cooled by heat transfer with the while passing gas hydrogen through Cu tube. We change diameter and flow rate and observe a change of the temperature and flow rate of gas hydrogen passing through Cu tube. As a result of, less flow rate and larger diameter are confirmed that liquefaction is more well. Ultimately, When we simulate the hydrogen liquefaction by using CFD program, and find optimum results, it is expected to contribute to the more effective and economical aspects such as time and cost.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.5
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• pp.439-446
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• 2023

In this study, the computational fluid dynamics (CFD) simulations were conducted to verify the cooling capacity of the cryocooler used for pre-cooling of hydrogen gas. Based on the experimental results, the effect of the flow rate on a copper pipe attached to the bottom of the cryocooler was investigated. In this study, the temperature data was calculated through the change of boundary condition for heat flux in the copper pipe. In addition, the cooling capacity of the cryocooler for pre-cooling hydrogen gas was considered by calculating the cooling temperature according to the flow rate in the certified operating range. Consequently the pre-cooing system for hydrogen gas was validated with a reasonable accuracy through CFD simulations.

• Journal of IKEEE
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• v.23 no.3
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• pp.1033-1037
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• 2019

GaN-based sensors have been widely investigated thanks to its potential in detecting the presence of hydrogen. In this study, we fabricated hydrogen gas sensors with AlGaN/GaN heterojunction and investigated how the sensing performance to be affected by SiN surface passivation. The gas sensor employed a high electron mobility transistors (HEMTs) with 30 nm platinum catalyst as a gate to detect the hydrogen presence. SiN layer was deposited by inductively-coupled chemical vapor deposition as post-passivation. The sensors with SiN passivation exhibited hydrogen sensing characteristics with various gas flow rates and concentrations of hydrogen in inert background gas at $200^{\circ}C$ similar to the ones without passivation. Aside from quick response time for both sensors, there are differences in sensitivity and recovery time because of the existence of the passivation layer. The results also confirmed the dependence of sensing performance on gas flow rate and gas concentration.