• 한국수소및신에너지학회논문집
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• 제12권4호
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• pp.247-255
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• 2001

The relation between the deformation and the geometrical shape, and the effect of cold work on the hydrogen absorption behavior in palladium were investigated. The Pd specimens used were plates and wires as cold worked and annealed states. The palladium plates and wires were loaded with hydrogen by electrochemical method. Experimental analyses were carried out through X -ray diffraction, micrometer measurement and decimal balance measurement. As the results, it is found that the effect of cold work on hydrogen absorption capacity was relatively small. The deformation of the palladium plates in thickness direction is larger than in other lateral directions whereas the palladium wires showed the same deformation ratio in all radius directions because of the circular distribution of coexisting $\alpha$ and $\beta$ phases. The products of plastic deformation such as slip lines and voids etc. were observed abundantly in all specimens although the specimens had undergone only once of a hydrogen absorption and desorption.

• Nuclear Engineering and Technology
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• 제48권5호
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• pp.1174-1183
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• 2016

Hydrogen release during severe accidents poses a serious threat to containment integrity. Mitigating procedures are necessary to prevent global or local explosions, especially in large steel shell containments. The management of hydrogen safety and prevention of over-pressurization could be implemented through a hydrogen reduction system and spray system. During the course of the hypothetical large break loss-of-coolant accident in a nuclear power plant, hydrogen is generated by a reaction between steam and the fuel-cladding inside the reactor pressure vessel and also core concrete interaction after ejection of melt into the cavity. The MELCOR 1.8.6 was used to assess core degradation and containment behavior during the large break loss-of-coolant accident without the actuation of the safety injection system except for accumulators in Beznau nuclear power plant. Also, hydrogen distribution in containment and performance of hydrogen reduction system were investigated.

• 한국표면공학회지
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• 제46권1호
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• pp.48-53
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• 2013

In the present work, it was investigated a behavior of hydrogen embrittlement at the subsurface zones of 590 DP steels by using the micro-Vickers hardness test. The micro-Vickers hardnessess of DP steels were measured to evaluate the degree of embrittlement as the effective hardening depths of subsurface zones with hydrogen charging conditions. The results showed that the distributions of micro-Vickers hardness in width varied from maximum hardness 239.5 Hv to minimum hardness 174 Hv, while the depth of effective hardening layer at the subsurface zones of DP steels was from $320{\mu}m$ to $460{\mu}m$ with hydrogen charging conditions, respectively. It was proposed that the distribution of microhardness be used as the evaluation index of the degree of embrittlement. But the variations of martensite volume fractions were not affected along depth of hardening at the same changing time, hydrogen charging times were appeared as an effective factor of the degree of embrittlement. Therefore, the micro-Vickers hardness test is an attractive tool for evaluation of hydrogen embrittlement at the subsurface zones of these DP steels.

• 한국가스학회지
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• 제14권6호
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• pp.38-43
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• 2010

자원 부족과 환경규제의 강화에 따라 자동차 강판재의 고강도화와 박강판화가 주요 이슈로 대두되고 있다. 그러나 고강도 강판재 사용에 있어 수소취성은 기계적 성질 저하의 문제가 되고 있다. 본 연구에서는 개발중인 590MPa급 DP강을 대상으로 조성 및 조직특성에 따른 표면층에서의 수소의 거동에 대해 연구하였다. 수소주입은 음극전기분해법을 이용하여 강제 주입시켰고, 수소주입조건에 따른 수소주입량과 표면층 조직관찰 및 미소경도시험 결과의 관계로 부터 표면층의 수소거동을 평가하였다.

• 한국가스학회지
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• 제25권4호
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• pp.43-48
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• 2021

본 연구는 가스사고 전문해석 프로그램인 FLACS를 이용하여 진행하였다. 안전성해석 대상인 수소충전소는 압축설비, 저장탱크, 수소 배관 등으로 구성되어있다. 주요 시설 및 구성품의 설계 사양, 수소충전소 주변의 환경 조건 등을 반영한 후 잠재적 위험요인에 대한 안전성해석을 실시하였다. 국내 수소충전소는 2021년 기준 약 70여곳의 충전소가 보급되어있으며, 향후 2040년에는 1200기 도입이 예정되어있다. 수소충전소의 안전한 보급을 위해 잠재적 위험에 의한 발생 가능한 사고를 대비하고자 누출·확산 시나리오를 도출하여 안전성을 검토하고자 한다.

• 한국산학기술학회논문지
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• 제9권6호
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• pp.1768-1774
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• 2008

PWR 정지화학 조건에서 모사실험하여 니켈페라이트 입자의 거동을 조사하였다. 농도가 Li 0.1 ppm, B 2000 ppm인 모사실험 용액의 온도는 $300^{\circ}C$에서 $0.625^{\circ}C/min$의 비율로 $150^{\circ}C$까지 감소시킨 후 일정 시간 동안 $150^{\circ}C$를 유지하였고 이때의 압력은 2500psi 이하로 유지하였다. 수소 농도 5, 15, 25 cc/kg $H_2O$ 일 때 온라인으로 입자 분포를 측정하였고 용해된 니켈 농도도 분석하였다. 실험결과 온도 감소 시 세 가지 수소 농도일 때 모두 총입자 수는 큰 변화가 없었다. 그러나 온도가 감소하고 일정하게 유지될 때 입자는 작아졌다. 입자 크기 분포 변화의 정도는 $H_2$ 15cc/kg $H_2O$ 일 때가 가장 크게 나타났다. 니켈 이온의 농도는 온도가 감소하고 수소 15 cc/kg $H_2O$ 일 때 증가하였다. 이 결과 니켈 페라이트는 온도 변화 시, 수소 15 cc/kg $H_2O$ 일 때 불안정 한 것으로 보여 진다.

• 대한기계학회논문집A
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• 제26권6호
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• pp.1107-1113
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• 2002

This study presents the hydrogen emblittlement in the metal, which decreases the ductility and then induces the brittle fracture. The contribution deals with the effect of strain rate and notch geometry on hydrogen emblittlement of 1.25Cr-0.5Mo and 2.25Cr-1Mo steels, which are in use at high pressure vessel. Smooth and notched specimens were examined to obtain the elongation and tensile strength. For charging the hydrogen in the metal, the cathodic electrolytic method was used. In this process, current density is maintained constant. The amount of hydrogen penetrated in the specimen was detected by the hydrogen determenator(LECO RH404) with the various charging time. The distribution of hydrogen concentration penetrated in the specimen was obtained by finite element analysis. The amount of hydrogen is high in smooth specimen and tends to concentrate in the vicinity of surface. The elongation and tensile strength decreased with the passage of charging time in 1.25Cr-0.5Mo and 2.25Cr-1Mo steels. The elongation increased and tensile strength decreased as strain rate increased. As a result of this study, it is supposed that 1.25Cr-0.5Mo steel is more sensitive than 2.25Cr-lMo steel in hydrogen embrittlement. Hydrogen embrittlement susceptibility of notched specimen after hydrogen charging is more remarkable than that of smooth specimen.

• 시스템엔지니어링학술지
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• 제18권2호
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• pp.140-148
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• 2022

Hydrogen is expected to be widely applied in most sectors within the current energy system, such as transportation and logistics, and is expected to be economically and technologically utilized as a power source to achieve vehiclebon emission reduction. In particular, the construction of hydrogen charging station infrastructure will not only support the distribution of hydrogen electric vehicles, but also play an important role in building a hydrogen logistics system. Therefore, This paper suggest additional charging infrastructure areas in Seoul with a focus on supply according to the annual average growth rate (CAGR), centering on Seoul, where hydrogen vehicles are most widely distributed. As of February 2022, hydrogen charging infrastructures were installed in Gangseo-gu, Gangdong-gu, Mapo-gu, Jung-gu, and Seocho-gu in downtown Seoul. Next, looking at the number of hydrogen vehicles by administrative dong in Seoul from 2018 to 2022, Seocho-gu has the most with 246 as of 2022, and Dongjak-gu has the highest average growth rate of 215.4% with a CAGR of 215.4%. Therefore, as a result of CAGR analysis, Dongjak-gu is expected to supply the most hydrogen vehicles in the future, and Seocho-gu currently has the most hydrogen vehicles, so it is likely that additional hydrogen charging infrastructure will be needed between Dongjak-gu and Seocho-gu.

• 한국추진공학회지
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• 제26권2호
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• pp.47-59
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• 2022

비추력이 가장 높은 액체수소/액체산소 엔진은 발사체의 성능을 극대화하기 위하여 1950년대 부터 개발되어 현재까지 이용되고 있다. 최근 국내에도 수소 경제의 대두에 따라 세계 수준의 액체수소 생산, 운송 등 인프라 구축이 진행되고 있고, 이는 발사체 성능을 향상시킬 수 있는 절호의 기회다. 본 논문에서는 액체수소 엔진 개발을 위한 전반적인 측면을 살펴보았다. 추진제로서의 액체수소 적용의 타당성을 고찰하고, 국내의 액체수소 인프라 현황, 액체수소 엔진 개발을 위한 소요기술, 수소를 안전하게 다루기 위한 운용적 측면을 검토하고, 액체수소 엔진 개발을 위한 시험설비를 검토하였다.

• 한국수소및신에너지학회논문집
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• 제33권5호
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• pp.470-498
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• 2022

Recently, the world has been considering hydrogen energy as the primary energy transition means to achieve carbon neutrality by 2050. In order to achieve the goal of reducing greenhouse gas emissions, Korea is also promoting a clean hydrogen economy. However, it is necessary to introduce various clean hydrogen from overseas so that the projected demand can not meet the domestically produced. For this study, we conducted the policy comparison approach between countries other than the generally considered technical and economic approaches. The finding proposes the direction of bilateral cooperation for a strategy of securing overseas clean hydrogen from a geopolitical perspective. Germany was a target country for the policy comparison since it has a high proportion of manufacturing, like Korea, and is taking the lead in the renewable-based energy transition policy. According to the survey and analysis of the policy establishment status and new projects of the two countries, Germany is promoting bilateral international cooperation in the hydrogen area with about 33 countries based on 7 types of activities. In comparison, Korea is involved in bilateral cooperation with about 12 countries on relatively few activities. Among the types of bilateral cooperation, R&D cooperation with advanced countries for hydrogen technology was a common activity type. Germany preemptively promotes cooperation for demonstration and commercialization, considering geopolitical means and strengthening manpower training and assistance on policy and regulation to preoccupy the market for the future. Therefore, it is necessary to consider establishing a network of an entire life cycle of supply and demand network that links the future market with securing clean hydrogen considering the geopolitical distribution. To this end, Korea also needs to expand bilateral cooperation countries by activity type, and it seems necessary to seek various geopolitical-based bilateral cooperation and support measures for developing countries to diversify the supply sources of hydrogen.