• Title/Summary/Keyword: Hydrogen addition

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A Performance Study of Portable Hydrogen Storage Tank (휴대용 수소 저장체 성능 특성 연구)

  • Park, Joon-Ho;Hwang, Yong-Sheen;Jee, Sang-Hoon;Kim, Sung-Han;Cha, Suk-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.315-318
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    • 2009
  • Hydrogen is the ideal candidate as an alternative energy carrier, so many hydrogen storage methods are investigated. The hydrogen storage method using metal hydride is good candidate as energy sources for portable devices because hydrogen-storage as metal hydride shows large volumetric storage density. In this study, we investigated the variations of hydrogen charging/discharging performance of metal hydride tanks at different temperature conditions. We charged metal hydride tanks with hydrogen in low temperature because of the exothermic reactions of hydrogen absorption while we discharged in high temperature to provide sufficient heat because of the endothermic reactions of desorption. In addition, we investigated the difference of hydrogen charging/discharging performance between two tanks having different sizes.

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Effects of Hydrogen Injection by In-Situ and Plasma Post-Treatment on Properties of a ZnO Channel Layer in Transparent Thin Film Transistors (증착시 및 플라즈마 후처리에 의한 수소 주입이 투명 박막 트랜지스터에서 산화아연 채널층의 물성에 미치는 영향)

  • Bang, Jung-Hwan;Kim, Won;Uhm, Hyun-Seok;Park, Jin-Seok
    • Journal of the Semiconductor & Display Technology
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    • v.9 no.1
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    • pp.35-40
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    • 2010
  • We have investigated the effects of hydrogen injection via in-situ gas addition ($O_2$, $H_2$, or $O_2$ + $H_2$ gas) and plasma post-treatment (Ar or Ar + H plasma) on material properties of ZnO that is considered to be as a channel layer in transparent thin film transistors. The variations in the electrical resistivity, optical transmittance and bandgap energy, and crystal quality of ZnO thin films were characterized in terms of the methods and conditions used in hydrogen injection. The resistivity was significantly decreased by injection of hydrogen; approximately $10^6\;{\Omega}cm$ for as-grown, $1.2\;{\times}\;10^2\;{\Omega}cm$ for in-situ with $O_2/H_2\;=\;2/3$ addition, and $0.1\;{\Omega}cm$ after Ar + H plasma treatment of 90 min. The average transmittance of ZnO films measured at a wavelength of 400-700 nm was gradually increased by increasing the post-treatment time in Ar + H plasma. The optical bandgap energy of ZnO films was almost monotonically increased by decreasing the $O_2/H_2$ ratio in in-situ gas addition or by increasing the post-treatment time in Ar + H plasma, while the post-treatment using Ar plasma hardly affected the bandgap energy. The role of hydrogen in ZnO was discussed by considering the creation and annihilation of oxygen vacancies as well as the formation of shallow donors by hydrogen.

Laminar Burning Velocities and Flame Stability Analysis of Hydrocarbon/Hydrogen/Carbon Monoxide-air Premixed Flames (탄화수소/수소/일산화탄소-공기의 예혼합화염에서 층류화염전파속도와 화염안정성)

  • Vu, Tran Manh;Song, Won-Sik;Park, Jeong;Lee, Kee-Man
    • Journal of the Korean Society of Combustion
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    • v.16 no.2
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    • pp.23-32
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    • 2011
  • To investigate cell formation in hydrocarbon/hydrogen/carbon monoxide-air premixed flames, the outward propagation and cellular instabilities were experimentally studied in a constant pressure combustion chamber at room temperature and elevated pressures. Unstretched laminar burning velocities and Markstein lengths of the mixtures were obtained by analyzing high-speed schlieren images. In this study, hydrodynamic and diffusional- thermal instabilities were evaluated to examine their effects on flame instabilities. The experimentally-measured unstretched laminar burning velocities were compared to numerical predictions using the PREMIX code. Effective Lewis numbers of premixed flames with methane addition decreased for all of the cases; meanwhile, effective Lewis numbers with propane addition increased for lean and stoichiometric conditions and increased for rich and stoichiometric cases for hydrogen-enriched flames. With the addition of propane, the propensity for cell formation significantly was diminished, whereas cellular instabilities for hydrogen-enriched flames were promoted. However, similar behavior of cellularity was obtained with the addition of methane to the reactant mixtures.

A simple and effective method for addition silicone impression disinfection

  • Azevedo, Maria Joao;Correia, Ines;Portela, Ana;Sampaio-Maia, Benedita
    • The Journal of Advanced Prosthodontics
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    • v.11 no.3
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    • pp.155-161
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    • 2019
  • PURPOSE. Although dental impression disinfection is determinant to reduce the cross-infection risk, some studies have shown that, in real practice, the disinfection procedures vary considerably. Thus, the aim of this study was to evaluate the antimicrobial effectiveness and the impact on the dimensional stability of addition silicone' impressions of water wash and the most clinically used disinfection solutions: 3% hydrogen peroxide, commercial disinfectant MD520 (Durr) and 1% and 5.25% sodium hypochlorite. MATERIALS AND METHODS. For this investigation, dental impressions were taken on 16 volunteer dental students. The antimicrobial effectiveness of each procedure was evaluated by pour plate method. The dimensional stability was evaluated using a standardized stainless-steel model, according to ANSI/ADA nº19 specification. RESULTS. The study results showed that water wash does not alter the dimensional stability of addition silicone impressions but doesn't reduce the microbial load of the material (P>.05). On the other hand, addition silicone disinfection by immersion with 3% hydrogen peroxide, MD520 (Durr), or sodium hypochlorite at 1% and 5.25% does not alter the dimensional stability significantly but reduces > 99.9% of the microbial load of the impressions (P<.001). CONCLUSION. Addition silicone impressions should always be disinfected after water wash in order to reduce effectively the cross-infection risk. All disinfectants tested showed high antimicrobial efficiency without significant changes in three-dimensional shape of impressions. Hydrogen peroxide and sodium hypochlorite are of particular importance because are easily accessible in dental setting. The less explored hydrogen peroxide could be a valuable alternative for silicone impressions disinfection.

Effect of Hydrogen Addition on the Conversion of Hydrocarbon Gas to Pyrocarbon Nanoparticles (탄화수소가스 열분해법에 의한 탄소나노입자 생성에 있어서 수소의 영향에 관한 연구)

  • Kim, Soo Hyung
    • Korean Chemical Engineering Research
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    • v.46 no.6
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    • pp.1025-1028
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    • 2008
  • With the assistance of thermal pyrolysis process for hydrocarbon gases, the formation and growth of particulate carbon was systematically investigated as a function of temperature in the gas phase. The yield and average size of pyrocarbon particles were found to increase with increasing pyrolysis temperature. The difference in the yield of carbon particles generated by pyrolizing acetylene and ethylene gas posed a question about the role of hydrogen in the pyrolysis of hydrocarbon gases. In order to reveal the role of hydrogen, controlled amount of hydrogen was added to the acetylene pyrolysis, and then hydrogen addition was observed to suppress the formation and growth of carbon particles. One can control the size of pyrocarbon particles by controlling the hydrogen gas addition.

Economic Evaluation of Hydrogen Production by Fermentation (발효에 의한 수소생산의 경제성 평가)

  • Gim, Bong-Jin;Kim, Jong-Wook;Park, Sang-Yong
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.2
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    • pp.145-155
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    • 2008
  • This paper deals with an economic evaluation of hydrogen production by fermentation. We evaluate the economic feasibility of domestic hydrogen production by fermentation utilizing glucose and waste water sludge in terms of hydrogen production prices. In addition, we make some sensitivity analysis of hydrogen prices by changing the values of input factors such as the price of glucose, the capital cost of the hydrogen production system, and the hydrogen production yields. The estimated hydrogen prices of the two-step dark-light hydrogen production by fermentation utilizing glucose was $5,347won/kgH_2$, and the single-step hydrogen production by anaerobic fermentation utilizing waste water sludge was $4,255won/kgH_2$, respectively. It is expected that the hydrogen production price by anaerobic fermentation can be reduced if we produce methane or hydrogen utilizing by-products such as alcohols and organic acids, or the government imposes some legal regulations on the treatment of waste water sludge.

Hydrogen Embrittlement Characteristics by Slow Strain Rate Test of Aluminum Alloy for Hydrogen Valve of Hydrogen Fuel Cell Vehicle (수소연료전지 자동차의 수소밸브용 알루미늄 합금의 저변형율인장실험에 의한 수소취화특성 연구)

  • Hyun-Kyu, Hwang;Dong-Ho, Shin;Seong-Jong, Kim
    • Corrosion Science and Technology
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    • v.21 no.6
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    • pp.503-513
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    • 2022
  • As part of eco-friendly policies, interest in hydrogen vehicles is growing in the automotive industry to reduce carbon emissions. In particular, it is necessary to investigate the application of aluminum alloy for light weight hydrogen valves among hydrogen supply systems to improve the fuel efficiency of hydrogen vehicles. In this research, we investigated mechanical characteristics of aluminum alloys after hydrogen embrittlement considering the operating environment of hydrogen valves. In this investigation, experiments were conducted with strain rate, applied voltage, and hydrogen embrittlement time as variables that could affect hydrogen embrittlement. As a result, a brittle behavior was depicted when the strain rate was increased. A strain rate of 0.05 mm/min was selected for hydrogen embrittlement research because it had the greatest effect on fracture time. In addition, when the applied voltage and hydrogen embrittlement time were 5 V and 96 hours, respectively, mechanical characteristics presented dramatic decreases due to hydrogen embrittlement.

Effect of Allopurinol on Vascular Endothelial Cells Damaged by Hydrogen Peroxide In Vitro (Hydrogen Proxide에 의해 손상된 배양 혈관내피세포에 대한 Allopurinol의 영향)

  • Suk, Seung-Han
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.20 no.4
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    • pp.980-984
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    • 2006
  • In order to examine the effect of oxygen free radicals on the vascular endothelial cells, cell viability was measured by XTT assay after bovine pulmonary vascular endothelial cell line(BPVEC) was treated only with hydrogen peroxide. In addition, the antioxidant effect of allopurinol on cells treated with hydrogen peroxide was examined by colormetric assay. in this study, the BPVEC treated with hydrogen peroxide showed the significantly decreased cell viability compared with control. Whereas, the viability of cells treated with hydrogen peroxide and allopurinol has significantly increased when compared with that of cells treated only with hydrogen peroxide. These results suggested that hydrogen peroxide, one of the oxygen free radicals showed cytotoxic effect and allopurinol has protective effect on oxygen free radical-induced cytotoxicity.

Exploration of Hydrogen Research Trends through Social Network Analysis (연구 논문 네트워크 분석을 이용한 수소 연구 동향)

  • KIM, HYEA-KYEONG;CHOI, ILYOUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.4
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    • pp.318-329
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    • 2022
  • This study analyzed keyword networks and Author's Affiliation networks of hydrogen-related papers published in Korea Citation Index (KCI) journals from 2016 to 2020. The study investigated co-occurrence patterns of institutions over time to examine collaboration trends of hydrogen scholars. The study also conducted frequency analysis of keyword networks to identify key topics and visualized keyword networks to explore topic trends. The result showed Collaborative research between institutions has not yet been extensively expanded. However, collaboration trends were much more pronounced with local universities. Keyword network analysis exhibited continuing diversification of topics in hydrogen research of Korea. In addition centrality analysis found hydrogen research mostly deals with multi-disciplinary and complex aspects like hydrogen production, transportation, and public policy.