• Journal of the Korea Safety Management & Science
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• v.16 no.4
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• pp.159-165
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• 2014

For the hydrogen economy system being tried starting with the 21st century, the fields that was not dealt with so far, such as the safety measure for large leakage accidents, the safety problem at infrastructures like a hydrogen station, the safety problem in terms of automobiles depending on introduction of hydrogen cars, the safety problem in a supply for homes like fuel cells, etc., are being deeply reviewed. In order to establish a safety control system, an essential prerequisite in using and commercializing hydrogen gas as an efficient energy source, it is necessary to conduct an analysis, such as analysis of hydrogen accident examples, clarification of physical mechanisms, qualitative and quantitative evaluation of safety, development of accident interception technologies, etc. This study prepared scenarios of hydrogen gas leakage that can happen at hydrogen stations, and predicted damage when hydrogen leaks by using PHAST for this.

• Korean Journal of Environmental Agriculture
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• v.38 no.1
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• pp.54-60
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• 2019

BACKGROUND: Hydrogen fluoride is one of the 97 accident preparedness substances regulated by the Ministry of Environment (Republic of Korea) and chemical accidents should be managed centrally due to continual occurrence. Especially, hydrogen fluoride has a characteristic of rapid diffusion and very toxic when leaking into the environment. Therefore, it is important to predict the impact range quickly and to evaluate the residual contamination immediately to minimize the human and environmental damages. METHODS AND RESULTS: In order to estimate the accident impact range, the off-site consequence analysis (OCA) was performed to the worst and alternative scenarios. Also, in order to evaluate the residual contamination of hydrogen fluoride in crop, the samples in accident site were collected from 15-divided regions (East direction from accident sites based on the main wind direction), and the concentration was measured by fluoride ($F^-$) ion-selective electrode potentiometer (ISE). As a result of the OCA, the affected distance by the worst scenario was estimated to be >10 km from the accident site and the range by the alternative scenario was estimated to be about 1.9 km. The residual contamination of hydrogen fluoride was highest in the samples near the site of the accident (E-1, 276.82 mg/kg) and tended to decrease as it moved eastward. Meanwhile, the concentrations from SE and NE (4.96~28.98 mg/kg) tended to be lower than the samples near the accident site. As a result, the concentration of hydrogen fluoride was reduced to a low concentration within 2 km from the accident site (<5 mg/kg), and the actual damage range was estimated to be around 2.2 km. Therefore, it is suggested that the results are similar to those of alternative accident scenarios calculated by OCA (about 1.9 km). CONCLUSION: It is difficult to estimate the chemical accident-affecting range/region by the OCA evaluation, because it is not possible to input all physicochemical parameters. However simultaneous measurement of the residual contamination in the environment will be very helpful in determining the diffusion range of actual chemical accident.

• Journal of computational fluids engineering
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• v.17 no.3
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• pp.75-86
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• 2012

We developed a preliminary CFD analysis methodology to predict a pressure build up due to hydrogen flame acceleration in the APR1400 IRWST on the basis of CFD analysis results for test data of hydrogen flame acceleration in a scaled-down test facility performed by Korea Atomic Energy Research Institute. We found out that ANSYS CFX-13 with a combustion model of the so-called turbulent flame closure and a model constant of A = 5.0, a grid model with a hexahedral cell length of 5.0 mm, and a time step size of $1.0{\times}10^{-5}$ s can be a useful tool to predict the pressure build up due to the hydrogen flame acceleration in the test results. Through the comparison of the simulated results with the test results, we found out that the proposed CFD analysis methodology enables us to predict the peak pressure within an error range of about ${\pm}29%$ for the hydrogen concentration of 19.5%. However, the error ranges of the peak pressure for the hydrogen concentration of 15.4% and 18.6% were about 66% and 51%, respectively. To reduce the error ranges in case of the hydrogen concentration of 15.4% and 18.6%, some uncertainties of the test conditions should be clarified. In addition, an investigation for a possibility of flame extinction in the test results should be performed.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.6
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• pp.605-613
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• 2020

In July and October of this year, the government announced the 'Green new deal plan within the Korean new deal policy' and 'Strategies for proliferation of future vehicles and market preoccupation'. And, in response to changes in the global climate agreement, it has decided to expand green mobility such as electric vehicles and hydrogen electric vehicles with the aim of a "net-zero" society. Accordingly, the goal is to build 310 hydrogen refueling stations along with the supply of 60,000 hydrogen vehicles in 2022, and the hydrogen infrastructure is being expanded. however, it is difficult to secure hydrogen infrastructure due to expensive construction costs and difficulty the selection of a site. In Korea, it is possible to build a mobile hydrogen station according to the safety standards covering special case of the Ministry of Industry. Since the mobile hydrogen station can be charged while moving between authorized place, it has the advantage of being able to meet a large number of demands with only one hydrogen refueling station, so it is proposed as a model suitable for the early market of hydrogen infrastructure. This study demonstrates the establishment of a hydrogen refueling station by deriving a virtual accident scenario for leakage and catastrupture for each facility for the risk factors in a mobile hydrogen station, and performing a quantitative risk assessment through the derived scenario. Through the virtual accident scenario, direction of demonstration and implications for the construction of a mobile hydrogen refueling station were derived.

• Nuclear Engineering and Technology
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• v.55 no.5
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• pp.1742-1756
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• 2023

The hydrogen behavior in a nuclear containment vessel is a significant issue when discussing the potential of hydrogen combustion during a severe accident. After the Fukushima-Daiichi accident in Japan, we have investigated in-depth the hydrogen transport mechanisms by utilizing experimental and numerical approaches. Computational fluid dynamics is a powerful tool for better understanding the transport behavior of gas mixtures, including hydrogen. This paper describes a Large-eddy simulation of gas mixing driven by a high-buoyancy flow. We focused on the interaction behavior of heat and mass transfers driven by the horizontal high-buoyant flow during density stratification. For validation, the experimental data of the Containment InteGral effects Measurement Apparatus (CIGMA) facility were used. With a high-power heater for the gas-injection line in the CIGMA facility, a high-temperature flow of approximately 390 ℃ was injected into the test vessel. By using the CIGMA facility, we can extend the experimental data to the high-temperature region. The phenomenological discussion in this paper helps understand the heat and mass transfer induced by the high-buoyancy flow in the containment vessel during a severe accident.

• Journal of the Korean Institute of Gas
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• v.24 no.6
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• pp.70-76
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• 2020

In this study, we suggested the direction to lower the risk by analyzing the risk factors for each process for the hydrogen refueling station to be installed in Chungju. HyRAM, one of the quantitative risk assessment tools for hydrogen gas, was used to analyze the hazards. By evaluating the frequency of accidents and consequences for each process, the most dangerous processes and accident factors were presented, and the risk mitigation factors were synthesized. Hydrogen refueling stations are currently in the global infrastructure expansion period, and the lack of accident data could be an alternative to this risk assessment and is expected to be used as a reference for the future expansion of hydrogen refueling stations.

• Journal of the Korean Institute of Gas
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• v.24 no.6
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• pp.83-90
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• 2020

This study conducted a risk assessment using the HyKoRAM program created by international joint research. Risk assessment was conducted based on accident scenarios and worst-case scenarios that could occur in the facility, reflecting design specifications of major facilities and components such as compressors, storage tanks, and hydrogen pipes in the hydrogen charging station, and environmental conditions around the demonstration complex. By identifying potential risks of hydrogen charging stations, we are going to derive the worst leakage, fire, explosion, and accident scenarios that can occur in hydrogen storage tanks, treatment facilities, storage facilities, and analyze the possibility of accidents and the effects of damage on human bodies and surrounding facilities to review safety.

• Korean Journal of Hazardous Materials
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• v.2 no.1
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• pp.1-5
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• 2014

Acidic chemicals like sulfuric acid, nitric acid and hydrogen chloride take up 37% of the total chemical accidents which took place for the past 10 years. When an acidic chemical leak happens, fume is generated, diffusing into the air, which might cause serious damage to health of local residents and the environment. However, we have only little reference data for production and using of acidic chemicals. In this study, we investigated characteristics of production and using for acidic chemicals with high accident frequency. As a results, domestic chemical accidents were categorized according to chemical types and production, using, and handling characteristics of acidic chemicals were identified. Sulfuric acid was handled in the largest amount, followed in the order of hydrogen chloride, nitric acid, acrylic acid, and hydrogen fluoride. Sulfuric acid is used in the industry of manufacturing composite fertilizer and mainly used for manufacturing fertilizer. Hydrogen chloride is used in the industry of manufacturing basic chemicals for petrochemical family and mainly used for pH regulator. It is expected that this results could be used as preliminary data for making decisions on facilities required intensive management in order to prevent chemical accidents and prepare countermeasures against such accidents.

• Journal of the Korean Society of Safety
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• v.31 no.6
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• pp.32-38
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• 2016

In general, lots of containers including various dangerous materials are transported to the port located in big cities such as Busan where massive residents live. Thus, it's really important how to make the emergency response for the leak accidents of dangerous materials and evaluate the direct or indirect damages to adjacent areas. In this study, in order to make reasonable emergency plans, CA (Consequence Analysis) is employed after selecting a key hazardous and noxious material, hydrogen fluroide. This material accounts for the third largest portion of cargo volume among all dangerous materials and can cause a huge damage in case of leakages. As a case study, Busan North port is selected as a test port since the portion of dangerous materials is higher than that of other ports in Busan. It is assumed that 1 ton of hydrogen fluoride is spilled at Busan North port. CA is performed to assess the impact of this accident. Throughout CA, the ERPG-2 range of a leak accident can be evaluated and this result can be used for decision making tools for mitigating the impact of a leak accident. To mitigate the damage of this accident, suitable a protective equipment and resident evacuation procedures should be prepared. Finally, this study can provide a systematic approach to make the emergency plan for reducing economical and personal losses.

• Journal of the Korean Institute of Gas
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• v.12 no.4
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• pp.29-33
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• 2008

The focus of this study is to develop a virtual reality program for safe training and virtual reality of hydrogen station. This programme consists of 4 modules such as hydrogen and safety module, hydrogen station module, hypothetical experience module, and accident scenarios module for hydrogen experts. User can experience with principles and operation condition and collect the information of hydrogen station by this programme and can simultaneously study the probable scenarios, emergency response plan/standard operating procedure about hydrogen stations. It makes it possible to educate and safety publicity for the trainee. This virtual reality program will be expected to be helpful for hydrogen station's construction propagation and technology development which is essential for hydrogen energy induction.