• 한국광과학회:학술대회논문집
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• 한국광과학회 1995년도 학술대회지
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• pp.4-4
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• 1995

• 한국수소및신에너지학회논문집
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• 제34권6호
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• pp.741-747
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• 2023

In this study, the heat transfer characteristics were numerically analyzed to investigate the possibility of utilizing cooling water using liquid nitrogen. From the study, as the mass flow rate of the hot fluid increased, the heat transfer rate increased by 8.9-81.7%. And lowering the inlet temperature of the hot fluid resulted in increase in the heat transfer rate by 33.8-71.5%. As for the filling level of liquid nitrogen, as higher filling level led to a decrease in the outlet temperature and an increase in the overall heat transfer coefficient.

• 한국수소및신에너지학회논문집
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• 제24권2호
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• pp.113-120
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• 2013

A steam reformer is a chemical reactor to produce high purity hydrogen from fossil fuel. In the steam reformer, since endothermic steam reforming is heated by exothermic combustion of fossil fuel, the heat transfer between two reaction zones dominates conversion of fossil fuel to hydrogen. Steam Reforming is complex chemical reaction, mass and heat transfer due to the exothermic methane/air combustion reaction and the endothermic steam reforming reaction. Typically, a steam reformer employs burner to supply appropriate heat for endothermic steam reforming reaction which reduces system efficiency. In this study, the heat of steam reforming reaction is provided by anode-off gas combustion of stationary fuel cell. This paper presents a optimization of heat transfer effect and average temperature of cross-section using two-dimensional models of a coaxial cylindrical reactor, and analysis three-dimensional models of a coaxial cylindrical steam reformer with chemical reaction. Numerical analysis needs to dominant chemical reaction that are assumed as a Steam Reforming (SR) reaction, a Water-Gas Shift (WGS) reaction, and a Direct Steam Reforming(DSR) reaction. The major parameters of analysis are temperature, fuel conversion and heat flux in the coaxial reactor.

• BMB Reports
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• 제31권4호
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• pp.307-327
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• 1998

Cytochrome c peroxidase (CcP) is a yeast mitochondrial enzyme which catalyzes the reduction of hydrogen peroxide to water using two equivalents of ferrocytochrome c. The CcP/cytochrome c system has many features which make it a very useful model for detailed investigation of heme protein structure/function relationships including activation of hydrogen peroxide, protein-protein interactions, and long-range electron transfer. Both CcP and cytochrome c are single heme, single subunit proteins of modest size. High-resolution crystallographic structures of both proteins, of one-to-one complexes of the two proteins, and a number of active-site mutants are available. Site-directed mutagenesis studies indicate that the distal histidine in CcP is primarily responsible for rapid utilization of hydrogen peroxide implying significantly different properties of the distal histidine in the peroxidases compared to the globins. CcP and cytochrome c bind to form a dynamic one-to-one complex. The binding is largely electrostatic in nature with a small, unfavorable enthalpy of binding and a large positive entropy change upon complex formation. The cytochrome c-binding site on CcP has been mapped in solution by measuring the binding affinities between cytochrome c and a number of CcP surface mutations. The binding site for cytochrome c in solution is consistent with the crystallographic structure of the one-to-one complex. Evidence for the involvement of a second, low-affinity cytochrome c-binding site on CcP in long-range electron transfer between the two proteins is reviewed.

• 한국수소및신에너지학회논문집
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• 제34권3호
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• pp.274-282
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• 2023

This study conducted direct numerical simulations of the natural convection phenomena of gaseous hydrogen in a physical storage container containing four circular cylinders. Rayleigh numbers (Ra) in the range of 10⁴≤Ra≤10⁶ and a Prandtl number (Pr)=0.69 (gaseous hydrogen) were considered. The main parameter is a horizontal distance of four circular cylinders and the values of ε_h=0.1, 0.2, 0.3, 0.4, and 0.5 are considered. The flow and thermal structures and corresponding heat transfer characteristics are investigated with respect to the transition of the flow regime. The time- and surface-averaged Nusselt number on the cylinder surface and the wall of physical storage container increased by about 57% and 69% according to the Ra and ε_h, respectively. Thus, the horizontal distance has an influence on the heat transfer characteristics on natural convection of gaseous hydrogen.

• 천문학논총
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• 제22권1호
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• pp.21-33
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• 2007

Ever since the identification of 6830 and 7088 features as the Raman scattered O VI 1032, 1038 resonance doublets in symbiotic stars by Schmid (1989), Raman scattering by atomic hydrogen has been a very unique tool to investigate the mass transfer processes in symbiotic stars. Discovery of Raman scattered He II in young planetary nebulae (NGC 7027, NGC 6302, IC 5117) allow one to expect that Raman scattering can be an extremely useful tool to look into the mass loss processes in these objects. Because hydrogen is a single electron atom, their wavefunctions are known in closed form, so that exact calculations of cross sections are feasible. In this paper, I review some basic properties of Raman scattered features and present detailed and explicit matrix elements for computation of the scattering cross section of radiation with atomic hydrogen. Some astrophysical objects for which Raman scattering may be observationally pertinent are briefly mentioned.

• Nuclear Engineering and Technology
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• 제54권8호
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• pp.3130-3139
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• 2022

Direct containment heating (DCH) is one of the potential factors leading to early containment failure. DCH is closely related to safety analysis and containment performance evaluation of nuclear power plants. In this study, a DCH prediction program was developed to analyze the DCH loads of containment vessel. The phenomenological model of debris dispersal, metal oxidation reaction, debris-atmospheric heat transfer and hydrogen jet burn was established. Code assessment was performed by comparing with several separate effect tests and integral effect tests. The comparison between the predicted results and experimental data shows that the program can predict the key parameters such as peak pressure, temperature, and hydrogen production in containment well, and for most comparisons the relative errors can be maintained within 20%. Among them, the prediction uncertainty of hydrogen production is slightly larger. The analysis shows that the main sources of the error are the difference of time scale and the oxidation of cavity debris.

• Bulletin of the Korean Chemical Society
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• 제20권9호
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• pp.1067-1072
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• 1999

Structures of unprotonated [(NH3)n+(n = 1-6)] and protonated [NH4+(NH3)n-1(n = 1-6)] ammonia cluster cations have been optimized with ab initio Hartree-Fock (HF) and second-order MФller-Plesset (MP2)/6-31+G ** levels and the harmonic vibrational frequencies have also been evaluated. In unprotonated cluster cations, NH3+ forms as a central core of the first ammonia solvation shell. In protonated cluster cations, NH4+ forms as a central core. In unprotonated dimer and trimer cations, there are two types of isomers (hydrogen-bonded and head-to-head interactions). In both cluster cations, the hydrogen-bonded isomers are more stable. In the hydrogen-bonded dimer cation, the proton transfer reaction takes place from (NH3-HN+H2) to (NH4+-NH2). But in the other unprotonated cluster cations, the proton transfer does not take place. In unprotonated pentamer and hexamer, a NH3+ core has both interactions in a complex. On the other hand, in unprotonated tetramer a core has only the hydrogen-bonded type combined with neutral ammonia molecules. With increasing cluster cation size, the bond lengths [R(NN)] between two nitrogen atoms and the distances [R(N ...H)] of the hydrogen-bond increase reg-ularly. In the calculated infra-red absorption bands for ammonia cluster cations, the characteristic peaks of the bridged NH vibration of the hydrogen-bonded clusters appear near 2500 cm-1 . With increasing size, the peaks shift from 2306 cm-1 to 2780 cm-1 .

• Nuclear Engineering and Technology
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• 제51권7호
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• pp.1749-1757
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• 2019

Predicting lower flammability limits (LFL) of hydrogen has become an ever-important task for safety of nuclear industry. While numerous experimental studies have been conducted, LFL results applicable for the harsh environment are still lack of information. Our aim is to develop a calculated non-adiabatic flame temperature (CNAFT) model to better predict LFL of hydrogen mixtures in nuclear power plant. The developed model is unique for incorporating radiative heat loss during flame propagation using the CNAFT coefficient derived through previous studies of flame propagation. Our new model is more consistent with the experimental results for various mixtures compared to the previous model, which relied on calculated adiabatic flame temperature (CAFT) to predict the LFL without any consideration of heat loss. Limitation of the previous model could be explained clearly based on the CNAFT coefficient magnitude. The prediction accuracy for hydrogen mixtures at elevated initial temperatures and high helium content was improved substantially. The model reliability was confirmed for $H_2-air$ mixtures up to $300^{\circ}C$ and $H_2-air-He$ mixtures up to 50 vol % helium concentration. Therefore, the CNAFT model developed based on radiation heat loss is expected as the practical method for predicting LFL in hydrogen risk analysis.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2271-2278
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• 2007

Electron transfer of a redox protein at a bare gold electrode is too slow to observe the redox peaks. A novel Nafion-riboflavin functional membrane was constructed during this study and electron transfer of cytochrome c, superoxide dismutase, and hemoglobin were carried out on the functional membrane-modified gold electrode with good stability and repeatability. The immobilized protein-modified electrodes showed quasireversible electrochemical redox behaviors with formal potentials of 0.150, 0.175, and 0.202 V versus Ag/AgCl for the cytochrome c, superoxide dismutase and hemoglobin, respectively. Whole experiment was carried out in the 50 mM MOPS buffer solution with pH 6.0 at 25 oC. For the immobilized protein, the cathodic transfer coefficients were 0.67, 0.68 and 0.67 and electron transfer-rate constants were evaluated to be 2.25, 2.23 and 2.5 s?1, respectively. Hydrogen peroxide concentration was measured by the peroxidase activity of hemoglobin and our experiment revealed that the enzyme was fully functional while immobilized on the Nafion-riboflavin membrane.