• Journal of Electrochemical Science and Technology
• /
• 제10권3호
• /
• pp.302-312
• /
• 2019

The voltage produced from the salinity gradient in reverse electrodialysis (RED) increases proportionally with the number of cell pairs of alternating cation and anion exchange membranes. Large-scale RED systems consisting of hundreds of cell pairs exhibit high voltage of more than 10 V, which is sufficient to utilize water electrolysis as the electrode reaction even though there is no specific strategy for minimizing the overpotential of water electrolysis. Moreover, hydrogen gas can be simultaneously obtained as surplus energy from the electrochemical reduction of water at the cathode if the RED system is equipped with proper venting and collecting facilities. Therefore, RED-driven water electrolysis system can be a promising solution not only for sustainable electric power but also for eco-friendly hydrogen production with high purity without $CO_2$ emission. The RED system in this study includes a high membrane voltage from more than 50 cells, neutral-pH water as the electrolyte, and an artificial NaCl solution as the feed water, which are more universal, economical, and eco-friendly conditions than previous studies on RED with hydrogen production. We measure the amount of hydrogen produced at maximum power of the RED system using a batch-type electrode chamber with a gas bag and evaluate the interrelation between the electric power and hydrogen energy with varied cell pairs. A hydrogen production rate of $1.1{\times}10^{-4}mol\;cm^{-2}h^{-1}$ is obtained, which is larger than previously reported values for RED system with simultaneous hydrogen production.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2004년도 하계학술대회 논문집 B
• /
• pp.1495-1497
• /
• 2004

This paper presents an effective modeling scheme of SPE cell system for hydrogen production. As oxygen and hydrogen produced by water electrolysis using SPE are high purity, we can use oxygen in biomedical and hydrogen could be used in many ways. Recently, it is under the eye as a surplus power storage system. PSCAD/EMTDC model of SPE cell system for hydrogen production to efficiently utilize Solar cell energy which produces effectively hydrogen energy is showed in this paper. The simulated results are then verified by comparing them with the actual values obtained from the data acquisition system. Authors are sure that it is a useful method to the researchers who study SPE cell system for hydrogen production.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2005년도 춘계학술대회 논문집 전기기기 및 에너지변환시스템부문
• /
• pp.274-276
• /
• 2005

This paper present an effective modeling scheme of SPE cell system for hydrogen production. As oxygen and hydrogen produced by water electrolysis using SPE are high purity, we can use oxygen in biomedical and hydrogen could be used in many ways. Recently, it is under the eye as a surplus power storage system. PSCAD/EMTDC model of SPE cell system for hydrogen production to efficiently utilize solar cell energy is showed in this paper. The simulated results are then verified by comparing them with the actual values obtained from the data acquisition system. Authors are sure that it is a useful method to the researchers who study SPE cell system for hydrogen production.

• 전기학회논문지P
• /
• 제67권2호
• /
• pp.94-99
• /
• 2018

Depending on how the energy storage system(ESS) is used in a system that can construct a microgrid by using an independent power source such as campus, surplus power can be generated that can not be charged to the ESS. For example, assuming that heat is supplied by a fuel cell in the case of a system in which thermal self-sustaining is prioritized, the fuel cell capacity required differs depending on the heat load. The amount of surplus power that can not be stored in the ESS will appear differently depending on the load operation of the fuel cell for each cycle. This power is hydrogenated through a water electrolytic device to present the amount of hydrogen energy that can be operated for each cycle. Therefore, this paper propose the possibility of utilizing University campus as a hydrogen station.