• Journal of Korean Tunnelling and Underground Space Association
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• v.23 no.6
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• pp.439-449
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• 2021

The recent reduction in greenhouse gases, interest in environmental pollution such as low-carbon emission policies is increasing. Accordingly, the penetration rate of eco-friendly vehicles, including hydrogen battery vehicles capable of reducing carbon emission, is increasing, and thus it is required for disaster prevention and safety-related measures. In this study, the degree of risk for the concentration distribution of hydrogen when leaking hydrogen fuel vehicles according to ventilation conditions was analyzed through numerical analysis, limited to places in parking lots. As a result, when only one hydrogen tank was released, the combustible volume ratio of hydrogen in the underground parking lot was up to 8.6%, and as ventilation continued, the volume ratio of combustible hydrogen decreased to less than 1% after 150 seconds, indicating that mechanical ventilation is essential. In the case of simultaneous release or stage release of three hydrogen tanks, the final combustible volume ratio of hydrogen is similar, but the increase in the combustible volume ratio of hydrogen in the early stage of release is low, and further research is expected.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.41 no.11
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• pp.7-13
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• 2004

Experimental results are presented for the degradation of 3 nm-thick gate oxide under -2.5V $\leq$ V$_{g}$ $\leq$-4.0V stress and 10$0^{\circ}C$ conditions using P and NMOSFETs that are annealed with hydrogen or deuterium gas at high-pressure (5 atm). The degradation mechanisms are highly dependent on stress conditions. For low gate voltage, hole-trapping is found to dominate the reliability of gate oxide both in P and NMOSFETs. With increasing gate voltage to V$_{g}$ =-4.0V, the degradation becomes dominated by electron-trapping in NMOSFETs, however, the generation rate of "hot" hole was very low, because most of tunneling electrons experienced the phonon scattering before impact ionization at the Si interface. Statistical parameter variations as well as the gate leakage current depend on and are improved by high-pressure deuterium annealing, compared to corresponding hydrogen annealing. We therefore suggest that deuterium is effective in suppressing the generation of traps within the gate oxide. Our results therefore prove that hydrogen related processes are at the origin of the investigated oxide degradation.gradation.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.3
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• pp.1259-1264
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• 2014

Hydrogen is in the world limelight for future energy source, and it has been already used in various industry fields including aerospace. The extremely fine molecule of the hydrogen can be easily leaked from tiny size of the crack on the surface of transporting pipes or storage tanks, and it could bring on awfully terrible disaster. In this study, Laser-Induced Breakdown Spectroscopy (LIBS) was employed to develope a reliable detection scheme for a small quantity of hydrogen leakage. Effect of three different metal substrates (i.e. Al, Cu, SUS) on plasma generation and the intensity of the hydrogen atomic signal was investigated, and the surface damage of the substrates due to repetitive laser shots was observed using Scanning electron microscope. It was also evaluated how the surface damage could distort the atomic signal. The intensity of the atomic signal was found to be the strongest, and the signal distortion due to the surface damage was approximately $100W/m^2$ lower when Al was used for the substrate.

• Journal of Hydrogen and New Energy
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• v.35 no.3
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• pp.324-335
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• 2024

The container package type sealed water electrolysis production system installs mechanical balance of plant and electrical balance of plant as an integrated unit to enable independent operation within the package module. The auxiliary equipment required to operate the water electrolysis system must be integrated to reduce the installation area and shorten the installation time. At this time, as leak risk factors are placed in a dense space, when a hydrogen gas leak accident occurs, it can have a mutual influence on other adjacent facilities, so it contains various risk factors. In this study, when a gas leak occurs in a container packaged water electrolysis system, possible sources of leakage in the system according to the KS C IEC 60079-10-1:2015 and KGS GC101 standards were identified, and the leak rate and leak characteristics were calculated. did. The hazardous area and its range were calculated according to ventilation and dilution characteristics. In order to optimize ventilation characteristics, design of experiment was used to analyze the influence to evaluate the adequacy of ventilation, and overseas ventilation standards were analyzed and compared. In addition, the optimal ventilation structure and characteristics of the container packaged water electrolysis system were presented according to the results of the experimental design method.

• Journal of Hydrogen and New Energy
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• v.31 no.6
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• pp.605-613
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• 2020

In July and October of this year, the government announced the 'Green new deal plan within the Korean new deal policy' and 'Strategies for proliferation of future vehicles and market preoccupation'. And, in response to changes in the global climate agreement, it has decided to expand green mobility such as electric vehicles and hydrogen electric vehicles with the aim of a "net-zero" society. Accordingly, the goal is to build 310 hydrogen refueling stations along with the supply of 60,000 hydrogen vehicles in 2022, and the hydrogen infrastructure is being expanded. however, it is difficult to secure hydrogen infrastructure due to expensive construction costs and difficulty the selection of a site. In Korea, it is possible to build a mobile hydrogen station according to the safety standards covering special case of the Ministry of Industry. Since the mobile hydrogen station can be charged while moving between authorized place, it has the advantage of being able to meet a large number of demands with only one hydrogen refueling station, so it is proposed as a model suitable for the early market of hydrogen infrastructure. This study demonstrates the establishment of a hydrogen refueling station by deriving a virtual accident scenario for leakage and catastrupture for each facility for the risk factors in a mobile hydrogen station, and performing a quantitative risk assessment through the derived scenario. Through the virtual accident scenario, direction of demonstration and implications for the construction of a mobile hydrogen refueling station were derived.

• Nuclear Engineering and Technology
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• v.55 no.2
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• pp.640-647
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• 2023

Material corrosion in nuclear power plant (NPP) is not controlled only by amine injection but also by ion exchange (IX) which is the best option to remove trace Na⁺. This study was conducted to understand the Na⁺ leakage characteristics of IX beds packed with ethanolamine-form (ETAH-form) and hydrogen-form (H-form) resins in the simulated water-steam cycle in terms of intrinsic behaviors of four kinds of cation-exchange resins through ASTM test and Vanselow mass action modeling. Na⁺ was inappreciably escaped throughout the channel created in resin layer. Na⁺ leakage from IX bed was non-linearly raised because of its decreasing selectivity with increasing Na⁺ capture and with increasing the fraction of ETAH-form resin. Na⁺ did not reach the breakthrough earlier than ETAH⁺ and NH₄⁺ due to the increased selectivity of Na⁺ to the cation-exchange resin (H⁺ < ETAH⁺ < NH₄⁺ ≪ Na⁺) at the feed composition. Na⁺ leakage from the resin bed filled with small particles was decreased due to the enhanced dynamic IX processes, regardless of its low selectivity. Thus, the particle size is a predominant factor among intrinsic properties of IX resin to reduce Na⁺ leakage from the condensate polishing plant (CPP) in NPPs.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.491-494
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• 2008

The hydrogen fuel and fuel cell which have high energy efficiency and low pollutant emission are getting interest as an alternative energies due to the fossil fuel exhaust, green house effect and atmospheric pollutant problems. The hydrogen gas is very effective as an alternative energy. But, if it is leaked into the air it forms the mixed gas with the air then the danger of the explosion is risen up. So, the secure the safety is mostly important. In this research, to detect the leakage of the hydrogen rapidly, added the odorant materials which don't include the sulfur component into the hydrogen gas and researched on the effect of each odorant on the performance of the fuel cell. As the results, setting the cumulation electric power on the basis and comparing the pure hydrogen, 2,3-Butanedione 5ppm mixed gas 86.1%, 5-Ethylidene-2-Norbornene 17ppm mixed gas 88.2%, Isovaleraldehyde 10ppm mixed gas 74.8%, Ethyl Isobutyrate 2.2ppm mixed gas 93.5% of performance was shown.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2005.05a
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• pp.385-390
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• 2005

This paper provided a counter measures against the troubles and accidents that are likely to take place in the power plant using hydrogen gas as a coolant for the cooling system of the generator. Because of the extremely wide flammability limits of hydrogen in comparison to the other flammable gases, the safety measures against the hydrogen accidents is very important to ensure the normal operation of electric-power facility. This study's purpose was a presentation of standard model of safety management of hydrogen equipments in the coal firing power plant such as following items: 1) providing the technical prevention manual of the hydrogen explosions and hydrogen fires occurring in the cooling system of power generator; 2) the selection of explosion-proof equipments in terms of the risk level of operating environment; 3) the establishment of regulations and counter measures, such as the incorporation of gas leakage alarm device, for preventing the accidents from arising; 4) the establishment of safety management system to ensure the normal operation of the power plant.

• Journal of the Korean Institute of Gas
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• v.25 no.4
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• pp.43-48
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• 2021

This study was conducted using FLACS, a specialized gas accident analysis program. Hydrogen refueling stations subject of safety analysis, consist of compression facilities, storage tanks, and hydrogen piping. The safety analysis of potential risk factors was conducted after reflecting the design specifications of major facilities and components, environmental conditions around hydrogen refueling stations, etc. As of 2021, about 70 refueling stations in Korea are available, and 1,200 are scheduled to be introduced in the next 2040. To prepare for possible accidents caused by potential hazards for the safe distribution of hydrogen refueling stations, we intend to derive hydrogen leakage diffusion scenarios and review their safety.

• Journal of Hydrogen and New Energy
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• v.31 no.3
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• pp.328-336
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• 2020

In the Francis turbine, the leakage flow through the runner gaps which are between the runner and the stator structure influences the internal flow and hydraulic performance. Thus, the investigation for the flow characteristics induced by the runner gaps is important. However, the runner gaps are often disregarded by considering the time and cost of the numerical analysis. Therefore, in this study, the flow characteristics according to runner gaps of the Francis turbine model were investigated including the leakage flow of the runner cone. The three-dimensional unsteady Reynolds-averaged Navier-Stokes analyses were conducted using a scale-adaptive simulation shear stress transport as a turbulence model for observing the influence of the leakage flow on the internal flow and hydraulic performance. The efficiencies were decreased slightly with runner gaps; and the complicated flows were captured in the gaps.