• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2005년도 춘계학술대회
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• pp.384-387
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• 2005

Fuel cell has been well known as a clean alternative power for vehicles. Recently, an experimental technique has been developed measurement of species and distributions by using gas chromatograph. In this study, cathode channel oxygen distributions as various conditions were investigated using gas chromatograph and cell visualization. And discussed relation between flooding and oxygen concentrations. As a result of experiment, oxygen consumpt ion is affected wi th flooding. Flooding is observed in channel near hydrogen inlet, and oxygen consumption is low at that region.

• 대한화학회지
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• 제18권3호
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• pp.153-156
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• 1974

황산산성에서의 히드라진과 요오드의 반응에 대하여, 기체발생속도를 측정하였다. 이미 보고된 요오등의 소비속도의 경우와 마찬가지로, 히드라진 및 요오드의 농도에 관하여는 1차 반응이며, 반응속도는 요오드화이온의 농도에 역비례한다. 그뿐만 아니라, 요오드으이 소비속도롸 기체 발생속도가 거의 같으므로, 수명이 긴 중간물이 생기지 않는다고 결론지을 수 있다

• 한국수소및신에너지학회논문집
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• 제34권6호
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• pp.641-649
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• 2023

This study analyzes the cool-down process of liquid hydrogen storage tanks, which have advantages in terms of large-capacity transfer, storage, and utilization as hydrogen demand increases. A hydrogen liquefaction plant is selected for analysis and an efficient tank cooling method is sought by comparing the time required for the cool-down process with the gas consumption in connection with the gassing-up process required for the operation of the liquid hydrogen storage tank. The results of this study can be referred to in the operation process after the initial start-up and maintenance of the hydrogen liquefaction plant.

• 한국물환경학회지
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• 제21권6호
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• pp.630-636
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• 2005

Groundwater contamination by nitrate exceeding water quality criteria (10 mg $NO_3{^-}-N/L$) occurs frequently. Fumarate, acetate, formate, lactate, propionate, ethanol, methane and hydrogen gas were evaluated for their nitrate removal efficiencies and removal rates for in situ bioremediation of nitrate contaminated groundwater. Denitrification rate for each substrate was in the order of: fumarate > hydrogen > formate/lactate > ethanol > propionate > methanol > acetate. Microcosm studies were performed with fumarate and acetate. When fumarate was used as a substrate, nitrate was removed 100 percent with rate of 0.66 mmol/day while conversion rate from nitrate to nitrogen gas or another by-product was 87 percent. 42 mg of fumarate was needed to remove 30 mg $NO_3{^-}-N/L$. When using acetate as carbon source, 31 percent of nitrate was removed during initial adjustment period. Among removed fraction, however, 83 percent of nitrate removed by cell growth. Overall nitrate removal rate was 0.37 mmol/day. Acetate showed longer lag time in consumption compared to that of nitrate, which implying that acetate would be better carbon source compared to fumarate as more amount was utilized for nitrate removal than cell growth.

• 에너지공학
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• 제2권1호
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• pp.75-82
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• 1993

상용 모사기인 ASPEN PLUS를 이용하여 천연가스를 사용하는 50 ㎾ 인산형 연료전지시스템의 정상상태 전산모사를 실시하였다. 연료전지 본체의 모사를 위하여 USER 블럭과 FORTRAN 블럭을 작성하였다. 여러가지 조업조건에 따른 수소의 수율 변화를 살펴봄으로써 개질기의 효율을 최대로 하는 조업범위를 찾았고, 실제 경우와 근사한 결과를 얻었다. 이로부터 향후 실용화될 국내의 연료전지시스템에 대한 기본 자료와 최적조건을 제시할 수 있다. 기존의 발전효율을 얻기 위하여는 수소이용률이 50%, 이상으로 유지되어야 하며, 고온으로 조작되는 개질기와 연료전지 본체에서 발생되는 고온의 열을 효율적으로 회수하여 이용함으로써 공정의 에너지효율을 높일 수 있다.

• International Journal of Naval Architecture and Ocean Engineering
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• 제3권2호
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• pp.141-149
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• 2011

The world is facing a challenge in meeting its needs for energy. Global energy consumption in the last halfcentury has increased very rapidly and is expected to continue to grow over the next 50 years. However, it is expected to see significant differences between the last 50 years and the next. This paper aims at introducing a good solution to replace or work with conventional marine power plants. This includes the use of fuel cell power plant operated with hydrogen produced through water electrolysis or hydrogen produced from natural gas, gasoline, or diesel fuels through steam reforming processes to mitigate air pollution from ships.

• 한국안전학회지
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• 제39권2호
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• pp.75-86
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• 2024

Hydrogen has been selected as one of the key technologies for reducing CO₂ emissions to achieve carbon neutrality by 2050. However, hydrogen safety issues should be fully guaranteed before the commercial and widespread utilization of hydrogen. Here, a bow-tie risk assessment is conducted for the hydrogen fuel supply system in a gas turbine power plant, which can be a mass consumption application of hydrogen. The bow-tie program is utilized for a qualitative risk assessment, allowing the analysis of the causes and consequences according to the stages of accidents. This study proposed an advanced bow-tie method, which includes the barrier criticality matrix and visualized maps of quantitative risk reduction. It is based on evaluating the importance of numerous barriers for the extent of their impact. In addition, it emphasizes the prioritization and concentrated management of high-importance barriers. The radar chart of a bow tie allows the visual comparison of risk levels before/after the application of barriers (safety measures). The risk reduction methods are semi-quantitatively analyzed utilizing the criticality matrix and radar chart, and risk factors from multiple aspects are derived. For establishing a secure hydrogen fuel storage system, the improvements suggested by the bow-tie risk assessment results, such as 'Ergonomic equipment design to prevent human error' and 'Emergency shutdown system,' will enhance the safety level. It attempts to contribute to the development and enhancement of an efficient safety management system by suggesting a method of calculating the importance of barriers based on the bow-tie risk assessment.

• 한국자동차공학회논문집
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• 제15권3호
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• pp.174-182
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• 2007

Fuel reforming technology for the fuel cell vehicles could be applied to internal combustion engine for the reduction of engine out emissions. Since syngas which is reformed from fossil fuel has hydrogen as a major component, it has abilities to enhance the combustion characteristics with wide flammability and high speed flame propagation. In this study, syngas was added to a gasoline engine to improve combustion stability and exhaust emissions of idle state. Syngas fraction is varied to 0%, 50%, 100% with various ignition timing and excess air ratio. Combustion stability, exhaust emissions, fuel consumption and exhaust gas temperature were measured to investigate the effects of syngas addition on idle performance. Results showed that syngas has ability to widely extend lean operation limit and ignition retard range with dramatical reduction of engine out emissions.

• 멤브레인
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• 제26권2호
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• pp.152-158
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• 2016

클로알칼리(CA) 멤브레인 셀은 대표적인 염수전해 시스템으로서 가성소다와 염소를 생산하는 염수전기분해 프로세스이다. CA 멤브레인 프로세스는 타 공정에 비해 낮은 에너지 소모량을 가져 CA산업에서 가장 선호되는 공정이다. CA프로세스에 사용되는 과불소계 술폰화 이오노머막은 CA프로세스의 핵심구성 요소이며, 양이온을 선택적으로 이동시키는 역할 및 배리어적인 역할을 제공한다. 하지만, CA 구동을 위해 충족되어야 하는 요소들에 대한 정보가 제한적이기 때문에 알맞은 CA분리막 적용을 위한 제품 간의 연구가 필요하다. 본 연구에서는 실제 셀 구동을 바탕으로 하여 상용 고불소계 분리막의 이온전도경향 및 전기화학적 성능 등을 평가하였다.

• 한국수소및신에너지학회논문집
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• 제27권5호
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• pp.485-493
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• 2016

Recently submarine and unmanned underwater vehicle (UUV) are equipped with a fuel cell system as an air independent propulsion system. Methanol fuel processor can efficiently supply the hydrogen to the fuel cell system to improve the ability to dive. This study investigated the optimal conditions of the methanol fuel processor that may be used in the closed environment. For this purpose, the numerical model based on Gibbs minimization equation was established for steam reformer and three exhaust gas burners. After simulating the characteristics of steam reformer according to the steam-to-carbon ratio (SCR) and the pressure change, the SCR condition was able to narrow down to 1.1 to 1.5. Considering water consumption and the amount of heat recovered from three burners, the optimum condition of the SCR can be determined to be 1.5. Nevertheless, the additional heat supply is required to satisfy the heat balance of the methanol fuel processor in the SCR=1.5. In other to obtain additional amount of heat, the combustion of methanol is better than the increased of SCR in terms of system design.