• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.7 s.250
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• pp.692-699
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• 2006

In this work, $TiO_2$ nanoparticles were synthesized using $N_2-diluted$ and Oxygen-enriched co-flow hydrogen diffusion flames. The effect of flame temperature on the crystalline structure of the formed $TiO_2$ nanoparticles was investigated. The measured maximum centerline temperature of the flame ranged from 2,103k for oxygen-enriched flame to 1,339K for $N_2-diluted$ flame. The visible flame length and the height of the main reaction zone were characterized by direct photographs. The crystalline structures of $TiO_2$ nanoparticles were analyzed by XRD. From the XRD analysis, it was evident that the crystalline structures of the formed nanoparticles were divided into two sorts. In the higher temperature region, over the 1,700K, the fraction of formed $TiO_2$ nanoparticles having anatase-phase crystalline structure increased with increasing the flame temperature. On the contrary, in the lower temperature region, below the 1,600K, the fraction of anatase-phase nanoparticles increased with decreasing the flame temperature.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.8
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• pp.997-1009
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• 1999

Silica particle formation and growth process including chemical reaction, coagulation and sintering was studied in a counterflow diffusion flame burner. The counterflow geometry provides a one dimensional flow field, along the stagnation point streamline, which greatly simplifies interpretation of the particle growth characteristics. $SiCl_4$ has been used as the source of silicon in hydrogen/oxygen/argon flames. The temperature profiles obtained by calculation showed a good agreement with experiment data. Using one and two dimensional sectional method, aerosol dynamics equation in a flame was solved, and these two results were compared. The two dimensional section method can consider sintering effect and growth of primary particle during synthesis, thus it showed evolution of morphology of non-spherical particles (aggregates) using surface fractal dimension. The effects of flame temperature and chemical loading on particle dynamics were studied. Geometric mean diameter based on surface area and total number concentration followed the trend of experiment results, especially, the change of diameters showed the sintering effect in high temperature environment.

• Journal of the Korean Society of Visualization
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• v.3 no.2
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• pp.51-56
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• 2005

Acoustic excitations were imposed to coaxial air jet of non-premixed jet flame with hydrogen gaseous injected axially in the center of the flow. The frequencies of excitation were three dominant resonant frequencies at 1L, 2L, 3L. modes including specially 514 Hz (2L-mode) which was estimated theoretically as longitudinal mode of combustor characteristics. The mixing enhancement by acoustic forcing has been investigated quantitatively using PLIF and PIV. The effect of acoustic excitation on combustion process was significant to enhance mixing rate that coincides with specific resonant frequencies. And the behavior of vortex-interaction on flame structure was a good evidence to investigate the phenomenon of shear/mixing layer of fuel-air jet structure. The results obtained in this study concludes that generated streamwise vortex by acoustic excitation has a potential to enhance the mixing rate and abating NOx emissions.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.4
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• pp.504-511
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• 2000

PIV(Particle Image Velocimetry) is a recently developed technique for visualizing the fluid velocity fields. Because it has several advantages over the LDV(Laser Doppler Velocimetry), it became one of the most popular diagnostic tools in spite of its short history. However, its application to combustion is restricted by some problems such as flame illumination, scattered light refraction, particle density variation due to heat release, the combined effect of abrupt change in particle density and fluid velocity on flame contour, and thermophoresis which is particle lagging due to temperature gradient. These problems are expected to be originated from the non-continuous characteristics of flames and the limitations of particle dynamics. In the present study, these problems were considered for the visualization of the instantaneous coaxial hydrogen diffusion flame. And the instantaneous flame contour was detected using particle density difference. The visualized diffusion flame velocity field shows its turbulent and meandering nature. It was also observed that the flame is located inside the outer shear layer and flame geometry is largely influenced by the vorticity.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.32 no.3
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• pp.224-230
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• 2008

In this article, $TiO_2$ nanoparticles were synthesized by using $O_2$-enriched coflow, hydrogen, diffusion flames. We investigated the thermal stability of the flame-synthesized $TiO_2$ nanoparticles by examining the crystalline structures of the nanoparticles. Also, the results were compared with those of commercial P-25 nanoparticles. $TiO_2$ nanoparticles, which were spherical with diameters approximately ranging from 30 to 60nm, were synthesized. From the XRD analyses, about 96wt% of the synthesized nanoparticles were anatase-phase. After the heat-treatment at $800^{\circ}C$ for 30 minutes, the synthesized $TiO_2$ nanoparticles showed no significant changes of their shapes and crystalline phases. On the other hand, most of the commercial particles sintered with each other and changed to the rutile-phase. Based on the result of XRD analysis it is believed that the flame-synthesized $TiO_2$ nanoparticles have higher thermal stability at $800^{\circ}C$ than the commercial particles.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.5
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• pp.509-515
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• 2012

In this study, ${\gamma}-Al_2O_3$ nanoparticles were synthesized by using coflow hydrogen diffusion flames. The synthesis conditions were varied with using several oxygen concentrations in the oxidizing air. The particle characteristics of the flame-synthesized $Al_2O_3$ nanoparticles were determined by examining the crystalline structure, shape, and specific surface area of the nanoparticles. The measured maximum centerline temperature of the flames ranged from 1507.8 K to 1998.7 K. The morphology and crystal structure of the $Al_2O_3$ nanoparticles were determined from SEM images and XRD analyses, respectively. The particle sizes were calculated from measured BET specific surface areas and ranged from 25 nm to 52 nm. From XRD analyses, it was inferred that a large number of the synthesized nanoparticles were ${\gamma}-Al_2O_3$ nanoparticles including ${\theta}-Al_2O_3$ nanoparticles.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.9
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• pp.829-836
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• 2013

The combustion characteristics with variations in synthetic natural gas (SNG) compositions were studied in a lab-scale combustor. The objective of the current study is to investigate the flame stabilization, flame structure, and spectrometry in a non-premixed SNG flame with varying fuel compositions. For the analysis of light emission in SNG flames, we used a spectrometer. As experimental conditions, the fuel jet velocity at the nozzle exit $u_F$ was varied from 5 to 40 m/s and the coaxial air velocity $u_A$ was varies from 0 to 0.43 m/s. The experiments showed that the flame stability increased with the hydrogen component in SNG.

• Journal of the Korean Society of Marine Environment & Safety
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• v.18 no.5
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• pp.468-474
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• 2012

In this study, experimental studies were performed for the carbon nanomaterial(CNM) which is catching on as a material for eco-ship. The opposed-flow methane flame was used as a heat source for synthesis of CNM. Ferrocene was used as a catalyst for the synthesis of CNM. These major parameters were $H_2$ mixing rate and sampling positions that synthesize CNMs in opposed-flow diffusion flames. The propensities of CNMs were experimentally determined using SEM and TEM images. The experimental result showed that the amount of CNTs was increased with increasing $H_2$ concentration. It can also be found that the optimal temperature in opposed-flow methane flame for synthesis of CNT was about 1500 K.