• Title/Summary/Keyword: Hydrocarbon flame

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A Study of Supersonic Combustion using Various Liquid Hydrocarbon Fuels

  • Hashimoto, Susumu;Hiramoto, Ayumu;Tsue, Mitsuhiro;Kono, Michikata;Ishikawa, Yuta;Suzuki, Shunsuke;Ujiie, Yasushige
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.340-345
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    • 2008
  • Liquid hydrocarbon fuels are gathering increasing attention as candidates for a scramjet engine fuel. Experimental researches on supersonic combustion of kerosene have been conducted in model scramjet combustors. Through these works, understanding of combustion characteristics of kerosene have been revealed on some level, and so we decided to work on other kinds of liquid hydrocarbon fuels in order to explore effects of fuel properties on supersonic combustion performances, especially self-ignition and flame-holding. In addition, comparing the results of new fuels with kerosene, the relationship between fuel properties and supersonic combustion characteristics was discussed.

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Numerical Study of PAH Formation Characteristics in Laminar Non-Premixed C2H4 Jet Flames (층류 비예혼합 C2H4 제트 화염장에서의 PAH 생성특성 해석)

  • Kim, Taehoon;Kim, Yongmo
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.133-134
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    • 2014
  • The full transport equation approach for laminar non-premixed flame with detailed chemistry, soot and radiation has an advantage in accuracy and describing for emission pathway, but this approach requires the excessive computational cost especially for a higher-order hydrocarbon fuel flames. On the other hand, the standard flamelet model has an efficiency and accuracy for non-premixed flame, though this model is not suitable for simulating slow processor like soot and radiation in laminar non-premixed flame situation. To overcome this limitation, modified transient flamelet model is developed which coupled with two-equation soot model involved in soot formation and evolution mechanism such as nucleation, surface growth, oxidation and agglomeration.

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The Effect of DBD Plasma on Fuel Reforming and on the Characteristics of Laminar Flames (DBD 플라즈마에 의한 연료개질 및 층류 화염 특성 변화)

  • Kim, Eungang;Park, Sunho;Song, Young-Hoon;Lee, Wonnam
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.195-198
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    • 2014
  • $Fuel/N_2$ and fuel/air mixtures were treated with non-thermal DBD plasma and the changes in characteristics of laminar diffusion flame have been observed. Flame of $Fuel/N_2$ mixture generated more soot under plasma condition while less amount of soot was formed from fuel/air mixture flame. Luminescence spectrum and gas chromatography results confirmed that plasma energy converts a fraction of fuel molecules into radicals, which then form $C_2$, $C_3$, $C_4$ and higher hydrocarbon under no oxygen condition or turn into CO, $CO_2$ and $H_2O$ when oxygen is present.

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The Influence of CH3Cl on CH4/CH3Cl/O2/N2 Premixed Flames Under the O2 Enrichment (산소부화 조건인 CH4/CH3Cl/O2/N2 예혼합 화염에서 CH3Cl의 영향)

  • Shin Sung Su;Lee Ki Yong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.2 s.233
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    • pp.255-262
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    • 2005
  • A comprehensive experimental and numerical study has been conducted to understand the influence of $CH_{3}Cl$ addition on $CH_4/O_2/N_2$ premixed flames under the oxygen enrichment. The laminar flame speeds of $CH_4/CH_{3}Cl/O_2/N_2$ premixed flames at room temperature and atmospheric pressure are experimentally measured using Bunsen nozzle flame technique, varying the amount of $CH_{3}Cl$ in the fuel, the equivalence ratio of the unburned mixture, and the level of the oxygen enrichment. The flame speeds predicted by a detailed chemical kinetic mechanism employed are found to be in excellent agreement with those deduced from experiments. Even though the molar amount of $CH_{3}Cl$ in a methane flame is increased, temperature at the postflame is not significantly varied, but the calculated heat release rate and emission index of NO are largely decreased for the oxygen enhanced flame. The function of $CH_{3}Cl$ as inhibitor on hydrocarbon flames becomes weakened as the level of the oxygen enrichment is increased from 0.21 to 0.5.

Combustion Characteristics and Soot Formation in a Jet Diffusion Flame (제트 확산화염의 연소특성과 매연생성에 관한 연구)

  • 이교우;백승욱
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.10
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    • pp.2712-2723
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    • 1994
  • Numerical simulation of an axisymmetric ethylene-air jet diffusion flame has been carried out in order to investigate flame dynamics and soot formation. The model solves the time-dependent Navier-Stokes equations and includes models for soot formation, chemical reaction, molecular diffusion, thermal conduction, and radiation. Numerically FCT(Flux Corrected Transport) and DOM(Discrete Ordinate Method) methos are used for convection and radiation trasport respectively. Simulation was conducted for a 5 cm/sec fuel jet flowing into a coflowing air stream. The maximum flame temperature was found to be approximately 2100 K, and was located at an axial position of approximately 5 cm from the base of the flame. The maximum soot volume fraction was about $7{\times}10^{-7}$, and was located within the high temperature region where the fuel mole fraction ranges from 0.01 to 0.1. The buoyancy-driven low-frequency(12~13 Hz) structures convected along the outer region of the flame were captured. In case without radiation trasport, the maximum temperature was higher by 150 K than in case with radiation. Also the maximum soot volume fraction reached about $8{\times}10^{-6}$. As the the hydrocarbon fuel forms many soot particles, the radiation transport becomes to play a more important role.

The Effect of DBD Plasma on Hydrocarbon Fuel Reforming and Change in Flammability Limits (DBD 플라즈마 개질에 의한 탄화수소계 연료 화염의 가연한계 변화)

  • Song, Mincheol;Ahn, Taekook;Nam, Younwoo;Park, Sunho
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.189-192
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    • 2015
  • An experimental study was conducted to find the effect of DBD plasma on the flammability limits of inert-gas-diluted fuel. The results showed that the concentration of diluting nitrogen at flammability limit increased when nitrogen-diluted methane and propane were reformed by plasma, while it decreased when nitrogen-diluted ethylene was reformed by plasma. Gas chromatography results suggested that the fuel type dependence of flammability limits is due to the difference in the concentrations of hydrogen and hydrocarbon species in reformed fuel.

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Hydrocarbon Speciation in Low Temperature Diesel Combustion (저온 디젤 연소에서 발생하는 탄화수소 종 분석)

  • Han, Man-Bae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.4
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    • pp.417-422
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    • 2010
  • Low temperature diesel combustion was achieved via a combination of late injection timing ($8.5^{\circ}$ CA BTDC to $0.5^{\circ}$ CA BTDC) and heavy exhaust gas recirculation (37% to 48%) with ultra low sulfur Swedish diesel fuel in a 1.7L common rail direct injection diesel engine. When injection timing is retarded at a certain exhaust gas recirculation rate, the particulate matter and nitrogen oxides decease simultaneously, while the hydrocarbon and carbon monoxide increase. Hydrocarbon speciation by gas chromatography using a flame ionization detector reveals that the ratio of partially burned hydrocarbon, i.e., mainly alkenes increase as the injection timing is retarded and exhaust gas recirculation is increased. The two most abundant hydrocarbon species are ethene which is a representative species of partially burned hydrocarbons, and n-undecane, which is a representative species of unburned hydrocarbons. They may be used as surrogate hydrocarbon species for performing a bench flow reactor test for catalyst development.

PAH and Soot Formation Characteristics of DME/Ethylene Fuel (DME/에틸렌 연료의 PAH 및 매연의 생성 특성)

  • Yoon, Seung-Suk;Lee, Sang-Min;Chung, Suk-ho
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.3
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    • pp.171-177
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    • 2005
  • In order to investigate the effect of dimethyl ether (DME) on PAH and soot formation, the fuel has been mixed to the counter-flow diffusion flames of ethylene. Laser-induced incandescence and laser-induced fluorescence techniques were employed to measure relative concentrations of soot volume fraction and polycyclic aromatic hydrocarbon (PAH) concentration, respectively. Results showed that even though pure DME flame produces the minimal amount of PAH and soot, the mixture fuel of DME and ethylene could increase PAH and soot formation, as compared to those of pure ethylene flame. This implies that even though DME has been known to be a clean fuel for soot formation, the mixture fuel of DME and the hydrocarbon fuel could produce enhanced production of soot. Numerical simulation demonstrated that methyl (CH$_{3}$) radical generated by the initial pyrolysis of DME can be contributed to the enhancement of PAH and soot formation, through the formation of propargyl (C$_{3}$H$_{3}$) radical.

Effects of Various Densities and Velocities to Gaseous Hydrocarbon Fuel on Near Nozzle Flow Field in Laminar Coflow Diffusion Flames

  • Ngorn, Thou;Jang, Sehyun;Yun, Seok Hun;Park, Seol Hyeon;Lee, Joo Hee;Choi, Jae Hyuk
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.291-293
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    • 2015
  • The experimental study on flow characteristic in various laminar coflow diffusion flame has been conducted with a particular focus on the buoyancy force exerted from gaseous hydrocarbon fuels. Methane ($CH_4$), Ethylene ($C_2H_4$) and n-Butane ($C_4H_{10}$) were used as fuels. Coflow burner and Schlieren technique were used to observe the fuel flow field near nozzle exit and flow characteristics in flames. The result showed that the vortices in n-Butane with density heavier than air were appeared near the nozzle exit with the strong negative buoyancy on the fuel stream. As Reynolds number increases by the control of velocity, the vortices were greater and the vortices tips were moved up from the nozzle exit. In addition, it can be found that the heated nozzle can affect to the flow fields of fuel stream near the nozzle exit.

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Effect of Fuel Mixing on PAH and Soot Formation in Counterflow Diffusion Flames (다양한 연료의 혼합에 따른 대향류 확산화염에서의 PAH 및 매연생성 특성)

  • Yoon, S.S.;Lee, S.M.;Chung, S.H.
    • 한국연소학회:학술대회논문집
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    • 2003.05a
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    • pp.137-142
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    • 2003
  • In order to investigate the effect of fuel mixing on PAH and soot formation, four species of methane, ethane, propane and propene have been mixed in counterlfow ethylene diffusion flame. Laser-induced incandescene and laser-induced fluorescene techniques were employed to measure soot volume fraction and polycyclic aromatic hydrocarbon (PAH) concentration, respectively. Results showed that the mixing of ethane (or propane) in ethylene diffusion flame produces more PAHs and soot than those of propene, even though the propene diffusion flame produces more PAHs and soot than that of propane and ethane. Considering that propene directly dehydrogenates to propargyl radical, this behavior implied that the enhancement of PAH and soot formation by the fuel mixing of ethylene and ethane (or propane) cannot be explained by propargyl radical directly dehydrogenated from ethane (or propane).

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