• Journal of the Korea Concrete Institute
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• v.27 no.3
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• pp.237-244
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• 2015

Entering the 20th century since the industrial revolution, the cement has been widely used in the field of construction and civil engineering due to the remarkable development of construction industry. However, result from that development, each kind of industrial by-products and waste and the carbon dioxide generated in the process of cement production cause air pollution and environmental damage so earth is getting sick now slowly. Therefore, we have to recognize importance about this. It means that the time taking specific and long-term measures have come. In this research paper, as substitution of the cement generating environmental pollution, we investigate the hydration reaction of non-Sintered Cement mortar mixed with GBFS, active stimulant of alkaline and sulphate series by using SEM and XRD, mechanical and chemical properties according to the curing method. As a result of this experiment, NSC realized outstanding strength for water curing and steam curing. It means that it has a good possibility as substitution of cement. From now on, it can be used for structure satisfying specific standard. We expect to find a substitution of outstanding cement by progressing continuous research making the best use of pros and cons according to the curing method.

• Journal of the Korea Concrete Institute
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• v.28 no.3
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• pp.299-308
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• 2016

This paper presents an investigation of the mechanical and microstructural properties on hardened samples that were synthesized using blended binder(fly ash(FA) and blast furnace slag cement(BFSC)), alkali activator and sea water or distilled water. Binders were prepared by mixing the FA and BFSC in different blend weight ratios of 6:4, 7:3 and 8:2. Sodium hydroxide and sodium silicate were used 5 wt% of binder, respectively, as an alkaline activator. The compressive strength and absorption were measured at the age of 3, 7 and 28 days, and the XRD, TGA and MIP tests were performed at the age of 28 days. An increase in the content of BFSC leads to an increase in the quantities of ettringite and C-S-H formed, regardless of the type of mixing water. And it also shows higher strength due to the reduction of pores larger than ~50 nm. All hardened samples in this study have common hydration products of C-S-H, $Ca(OH)_2$ and calcite. Hydrocalumite of all reaction products formed was only present in hardened sample mixed with sea water. For each FA/BFSC mixing ratio, the compressive strength of hardened sample mixed with sea water was similar to that mixed with distilled water. It is proposed that the slight increase of strength of samples mixed with sea water is mainly due to the presence of hydrocalumite phase containing chlorine ion, contributing to the change of total porosity and pore size distribution in samples.

• Journal of the Korean Chemical Society
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• v.45 no.2
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• pp.116-120
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• 2001

In order to know the physicochemical properties of magnetized water, the experimental methods of column assay, crystalization of saltsand gypsom have been explored to elucidate the effects of magnetized water on the solubility speed of salts, crystal pattern from salt squeous solutions, and gypsom crystal pattern, respectively. In the column assay for salt solubility the magnetized water showed the decreased initial solubility speed of NaCl and slightly increased initial solubility spped of KCI, however, the maximum solugilities of NaCl and KCI in the magnetized aster were almost same in the double distilled water, respectively. The column assay also indicated that the magnetized water showed the decreased initial solubility speed of urea (CH$_4$N$_2$O), sodium citrate (HOC(CO$_2$Na)-(CH$_2$CO$_2$Na)$_2$-2H$_2$O) and (NH$_4$)$_2$compared to the double distilled water, while slightly increased solubility speed of glycine (NH$_2$CH$_2$COOH), boric acid (H$_3$BO$_3$), MgSO$_4$. Crystalization of 1% or 5% salt aqueous solutions by rapid evaporation disclosed that the magnetized water produced more condensed and bigger crystal structure than the control water. The pattern of gypsom crystal formation also indicated that the magntized water enhanced the crystal formation in the hydration reaction of gypsom plaster compared to the double distilled water. Taken together, it was presumed that the magnetized water showed the different physicochemical properties in the interaction with various salts, especially showed the contrast results between NaCl and KCI.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.36 no.6
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• pp.1117-1123
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• 2016

Roller-Compacted Concrete Pavement (RCCP) is a type of pavement that shares conventional concrete pavement material characteristics and asphalt pavement construction characteristics. Even though RCCP is compacted in the same way and have similar aggregate gradation to asphalt pavements, its materials and structural performance properties are similar to those of conventional concrete pavement. With cement hydration and aggregate interlock, Roller-Compacted Concrete or RCC can provide strength properties equal to those of conventional concrete with low cement content. Therefore, compaction ratio of RCC can highly influence on its strength. In general, 95% of compaction ratio is required for proper strength development. RCC strength can be highly influenced by compaction energy which depends on compaction equipment and compaction method. Therefore, it is necessary to analyze the relationship between compressive strength and compaction ratio of RCC. RCCP specimens were produced at different compaction ratio by using different compaction methods and energies. The compaction ratio was defined by the ratio of the specimen's dry density and its maximum dry density. The maximum dry density was obtained from Modified Proctor test. 28 days compressive strength corresponding to each compaction ratio case was tested. Finally, the relationship between compressive strength and compaction ratio can be analyzed. For application of roller-compacted concrete in domestic construction site, the relationship is important for field compaction management.

• Asian-Australasian Journal of Animal Sciences
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• v.33 no.12
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• pp.1965-1974
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• 2020

Objective: This study consisted of two stages; the first was to determine the effect of extrusion and sieving treatments on the chemical properties of palm kernel cake (PKC), and accordingly, a follow-up experiment (second stage) was conducted to determine and compare the apparent metabolizable energy (AME), and protein and amino acid digestibility of extruded and sieved PKC. Methods: Two physical treatments, namely extrusion (using temperature profiles of 90℃/100℃/100℃, 90℃/100℃/110℃, and 90℃/100℃/120℃) and sieving (to 8 particles sizes ranging from >8.00 to 0.15 mm) were carried out to determine their effects on chemical properties, primarily crude protein (CP) and fiber contents of PKC. Based on the results from the above study, PKC that extruded with temperature profile 90/100/110℃ and of sieved size between 1.5 to 0.15 mm (which made up of near 60% of total samples) were used to determine treatments effect on AME and CP and amino acid digestibility. The second stage experiment was conducted using 64 male Cobb 500 chickens randomly assigned to 16 cages (4 cages [or replicates] per treatment) to the following four dietary groups: i) basal (control) diet, ii) basal diet containing 20% untreated PKC, iii) basal diet containing 20% extruded PKC (EPKC), and iv) basal diet containing 20% sieved PKC (SPKC). Results: Extrusion and sieving had no effect on CP and ash contents of PKC, however, both treatments reduced (p<0.05) crude fiber by 21% and 19%, respectively. Overall, extrusion and sieving reduced content of most of the amino acids except for aspartate, glutamate, alanine and lysine which increased, while serine, cysteine and tryptophan remained unchanged. Extrusion resulted in 6% increase (p<0.05) in AME and enhanced CP digestibility (p<0.05) by 32%, as compared to the untreated PKC while sieving had no effect on AME but improved CP digestibility by 39% which was not significantly different from that by extrusion. Conclusion: Extrusion is more effective than sieving and serves as a practical method to enhance AME and digestibility of CP and several amino acids in broiler chickens.

• Journal of the Korea Institute of Building Construction
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• v.18 no.5
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• pp.439-446
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• 2018

The PHC pile has been increasingly used due to its implementation of the top-base method, which is advantageous in high penetration rate and bearing capacity reinforcement. Typically, when a PHC pile is manufactured, high-strength mixed materials are mainly used to enhance the compressive strength. However, recent studies have been conducted to utilize ground granulated blast-furnace slag (GGBS) in terms of economic efficiency. For this reason, this study manufactured PHC pile considering the replacement ratio and curing conditions of GGBS instead of high-strength mixed materials, and further investigated the engineering properties of the PHC pile. According to the experimental results, the compressive strength of GGBS-replaced PHC pile increased by steam curing, and particularly, PHC pile with 20% replacement of GGBS under $80^{\circ}C$ steam curing condition showed a compressive strength of approximately 84MPa. Furthermore, the experimental results confirmed that more hydration products were generated under the $80^{\circ}C$ steam curing condition than that under the $20^{\circ}C$ steam curing condition, which would affect the higher density of the PHC pile as well as the increase in the compressive strength.

• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.6
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• pp.163-170
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• 2012

With the advantage of a rapid exothermic reaction property, jet set concrete may be used as a cold weather concrete because it can reach the required strength before being damaged by cold weathers. And it can be hardened more quickly if the field temperature is properly compensated by heating. Because ordinary concrete cannot be hardened well under sub-zero temperatures, anti-freeze agents are typically added to prevent the frost damage and to ensure the proper hardening of concrete. While the addition of a large amount of anti-freeze agent is effective to prevent concrete from freezing and accelerates cement hydration resulting in shortening the setting time and enhancing the initial strength, it induces problems in long-term strength growth. Also, it is not economically feasible because most anti-freeze agents are mainly composed of chlorides. Recent studies reported that magnesia-phosphate composites can be hardened very quickly and hydrated even in low temperatures, which can be used as an alternative of cold weather concrete for cold weathers and very cold places. As a preliminary study, to obtain the material properties, mortar specimens with different mixture proportions of magnesia-phosphate composites were manufactured and series of experiments were conducted varying the curing temperature. From the experimental results, an appropriate mixture design for cold weathers and very cold places is suggested.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.35 no.3
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• pp.533-544
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• 2015

Unlike the concrete structure built on land, that exposed to the marine environment is greatly degraded in durability due to the exposure to not only the physical action caused by sea wind, tide, and wave, but also the harsh conditions, including the chemical erosion and freeze-thaw which result from $SO_4{^{2-}}$, $Cl^-$ and $Mg^{2+}$ ions in seawater. In the process of the large scaled construction of submerged concrete structures, of course environmental hazardous substance, such as alkaline (pH) and heavy metals, may be leached. Thus, this issue needs to be adequately reviewed and studied. Therefore, this study attempted to develop a CSA (Calcium Sulfo Aluminate) activator using electric arc furnace reducing slags, as well as the eco-friendly concrete for artificial reefs using electric arc furnace oxidizing slag as aggregate for concrete. The strength properties of the eco-friendly concrete exposed to the marine environment were lower than those of the normal concrete by curing 28 days. This suggest that additional studies are needed to improve the early strength of the eco-friendly concrete. With respect to seawater resistance of the eco-friendly concrete, the average strength loss against 1 year of curing days reached 8-9%. the eco-friendly concrete using high volume of ground granulated blast furnace slags and high specific gravity of electronic arc furnace oxidizing slag demonstrated the sufficient usability as a freeze-thaw resistant material. With respect to heavy metal leaching properties of the eco-friendly concrete, heavy metal substances were immobilized by chemical bonding in the curing process through the hydration of concrete. Thus, heavy metal substances were neither identified at or below environmental hazard criteria nor detected, suggesting that the eco-friendly concrete is safe in terms of leaching of hazardous substances.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.6
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• pp.132-139
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• 2017

A huge amount of de-icing agent is sprayed during winter to promote traffic safety in cold regions, and the quantity of de-icing agent sprayed has increased each year. The main ingredients in commonly used de-icing agents are chlorides, such as calcium chloride($CaCl_2$) and sodium chloride(NaCl). While calcium chloride is mostly used in Korea and sodium chloride is usually used in the U.S. and Japan, all de-icing agents include chloride ions. The chlorides included in sprayed calcium chloride-based de-icing agents have severe adverse effects, including the corrosion of reinforcing steels through salt damage by infiltrating into road structures, reduced structural performance of pavement or damage to bridge structures, and surface scaling, in combination with freezing damage in winter, as well as water pollution. In addition, the deterioration of paved concrete road surface that occurs after the use of calcium chloride-based de-icing agent accelerates the development of visual problems with traffic structures. Therefore, the present study was performed to prepare an environment-friendly liquid de-icing agent through a reaction between waste organic acids and calcium-based by-products, which are industrial by-products, and to analyze the properties of the de-icing agent in order to evaluate its applicability to road facilities.

• Journal of the Korea Concrete Institute
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• v.23 no.3
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• pp.347-352
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• 2011

When concrete is worked in cold weather, the methods of using hot air, water and aggregate heating, accelerators are used to prevent early frosting and to improve early strength. But these methods raise problems such as implementation difficulty, high cost, and energy losses. Among the available cold weathering methods, accelerator method is the most economical but with the drawbacks of rapid setting and insufficient workability in the initial hydration stage. Therefore, the tablet method usually used for pharmaceutical field was applied to the accelerator method to compare the controlled reaction time of the new and old accelerator method. Based on the test results, physical and mechanical properties of concrete were tested and the possibility of delaying initial reactions to increase the total reaction time was evaluated. The results showed that when both accelerators and tablet were used, setting-time decreased. Physical properties of concrete were optimal for tablet 0.5% and 1.0%. Also, accelerator 0.5%, tablet 0.5% and 1.0% showed good early strengths.