• 한국세라믹학회지
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• 제48권6호
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• pp.504-509
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• 2011

In this study, the effect of superplasticizers on the dispersibility and hydration properties of cement with silica fume were investigated. Superplasticizers are used Naphthalene type, Ligno-sulfate type and polycarboxylate type. Compared with plastic viscosity of cement paste without superplasticizers(Plain), plastic viscosity of cement paste with superplasticizers are reduced and yield stress of cement pastes with each superplasticizer is increased rather than Plain. And then, plastic viscosity of cement paste with Naphthalene type superplasticizer was the least of all types. Compared with other two types, setting and hydration of cement paste with Polycarboxylate type(PC) superplasticizer is very fast. At compressive strength after 3-day, PC is higher than other two types, But, compressive strength of after 7-day and 28-day, PC is smaller than other two types.

• 한국세라믹학회지
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• 제48권6호
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• pp.510-515
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• 2011

In this study, as a material used to replace silica fumes for high strength concrete, nano-silica compound with organic functional group for dispersion and with inorganic silica group that can cause a pozzolan reaction is synthesized, These nano silica compound is divided into IC, which is nano size $SiO_2$ with irregularly combined hydroxyl group and carboxyl group, and RC, which is nano size $SiO_2$ with regularly combined hydroxyl group and carboxyl group. The effects of these nano silica compound on the hydration of cement are reviewed. As a result, all of synthesized nano-silica compounds have excellent dispersion on the cement flow, we think that dispersion property is the effect of air entraining by synthesized nano-silica compounds. The result of the microstructure observation showed that the particle size of the synthesized nano-silica is smaller than silica fume and spread evenly among the cement particles. In initial The phenomenon of strength decreasing occurred due to delayed hydration reaction by the synthesized nano-silica with carboxyl(-COOH) and hydroxyl(-OH) functional group.

• 한국산학기술학회논문지
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• 제6권3호
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• pp.223-230
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• 2005

최근 들어 매스콘크리트 구조물의 해석에 대한 연구가 증가 추세에 있다. 대형 콘크리트 구조물은 일괄 타설하지 않고 분할하여 타설하기 때문에 서로 다른 발열특성 및 시간의존적 특성을 지닌 콘크리트로 구성된 구조물이 됩니다 따라서 실제 구조물과 근접한 수화열해석 모델을 만들기 위해서는 시공단계를 고려한 모델이 필요합니다. 본 연구에서는 교각 기초의 온도균열을 방지하기 위하여 열응력 검토를 실시하였으며, 이때 기초는 보통 콘크리트를 사용하고 $12m\times14m$의 면적과 3m 높이를 가지는 것을 모델로 하였다. 2단계로 분할하여 타설된 기초구조물에 대해서 별 해석을 수행하고 그 결과를 분석합니다.

• 한국구조물진단유지관리공학회 논문집
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• 제15권5호
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• pp.218-226
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• 2011

본 연구에서는 스트론튬계 잠열재를 사용한 저발열 콘크리트를 레미콘 배처플랜트에서 시험생산한 후 생산된 콘크리트의 기초성능 및 모의부재에 의한 수화온도 특성을 평가하였으며, 그 결과 스트론튬계 잠열재를 사용한 저발열 콘크리트의 현장적용 가능성을 확인하였다. 이후 스트론튬계 잠열재를 사용한 콘크리트를 실제 교각 건설현장에 적용하였으며, 적용부재에 대한 수화열 해석 및 타설 콘크리트의 성능평가 결과 수화열 및 온도균열 저감효과가 우수한 것으로 나타나, 향후 대형 매스콘크리트의 수화열 및 온도균열 저감대책으로서 활용이 기대된다.

• 한국세라믹학회지
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• 제39권7호
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• pp.617-621
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• 2002

Calcium aluminosulfate (3CaO.3Al$_2$O$_3$.CaSO$_4$or $C_4$A$_3$S) was prepared by chemical synthesis from the nitrate salts and aluminum sulfate. $C_4$A$_3$S was the main phase after calcination at 110$0^{\circ}C$. The specific surface areas after calcination at 110$0^{\circ}C$ and 130$0^{\circ}C$ were about 2.5 and 1.0 $m^2$/g, respectively. Hydration was investigated by XRD, DSC, SEM, EDS, conduction calorimetry and analysis of the liquid phase. Calorimetry showed that the induction period was longer than that of a sample prepared by conventional solid state sintering and this was attributed to the formation of amorphous coatings in abundance of $Al_2$O$_3$ and SO$_3$. Crystalline hydration products, principally calcium monosulfoaluminate hydrate and Al(OH)$_3$, appeared subsequently.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.429-432
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• 2008

Large area members such as foundation concrete of underground structures in power plants have an effect on structural stability and durability of the structure due to danger of crack occurrence and shrinkage crack that occur owing to the difference of temperature by heat of hydration between inside and outside of the members at initial age. And a construction for waterproofness is performed additionally to protect marine structures from osmosis of seawater because the structures adjoin below the surface of sea. So, if a rise of the heat of hydration, crack, and corrosion of bars are controled effectively using a composite such as fluosilicate salt in concrete production process of a initial construction, expenses are cut down and construction hours are reduced by securing durability through improvement of watertightness. The property tests of adiabatic temperature by hydration are carried out at initial age about standard concrete and test concrete using a fluosilicate salt composite to evaluate an effect on improvement of watertightness for concrete structures in this study. And the experiments such as a permeability test of hardened concrete, a water absorption test, a compression strength test and a elongation test are carried out and the results from these are described.

• Computers and Concrete
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• 제29권4호
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• pp.237-246
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• 2022

The concrete quality relies on general factors like preparation technique, uniformity of the compaction, amount and appropriateness of the additives. The current article investigates the impact of a well knows amino acid, L-arginine as an additive on water requirements, setting durations and characterization of various cement samples. Compressive strength tests of reference and L-arginine added cements at age of 2, 7 and 28 days were carried out according to TS-EN 196-1. Samples were blended by incorporating various amounts of L-arginine (25 ppm, 50 ppm and 75 ppm) in the cement water mixture which were tested with Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermo-gravimetric analysis (TG), scanning electron microscopy (SEM) and the energy-dispersive X-ray spectroscopy (EDS) on the 28th day. Results revealed that L-arginine does not affect the setting time, volume expansion of cement and water demands negatively; rather it imparts enhanced sustainability to the samples. It was determined that the highest value belonged to the 75L mortar with an increase of 2.6% compared to the reference sample when the compressive strengths of all mortars were compared on the 28th day. Besides, it has been observed that the development of calcium silicate hydrate or C-S-H gel, calcium hydroxide or CH and other hydrated products are associated with each other. L-arginine definitely has a contribution in the consumption of CH formed in the hydration process.

• 대한토목학회논문집
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• 제26권5A호
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• pp.909-915
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• 2006

콘크리트의 자기수축을 예측하기 위해 기존 수화도와 자기수축의 진행 속도 차이를 불포화공극 생성 속도로 가정하고 시멘트 페이스트의 자기수축 실험을 통하여 물-결합재비에 반비례하는 불포화공극 보정계수를 산정할 수 있었다. 이를 자기수축 기여 성분과 미기여 성분이 고려된 변형 Pickket 모델을 이용하여 콘크리트의 자기수축을 예측하였으며, 실험값 및 기존 Tazawa 모델과 일치하는 경향을 나타내어 불포화공극 보정계수에 의한 자기수축 예측이 타당함을 알 수 있었다. 그러나 강도의 함수로 설정된 기존 CEB-FIP 자기수축 예측 모델의 경우 최종 자기수축률과 자기수축 발현 시간함수에 대하여 다소의 수정이 필요할 것으로 판단된다.

• Bulletin of the Korean Chemical Society
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• 제29권6호
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• pp.1233-1242
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• 2008

The hydration effect on the intrinsic magnetism of natural salmon double-strand DNA was explored using electron magnetic resonance (EMR) spectroscopy and superconducting quantum interference device (SQUID) magnetic measurements. We learned from this study that the magnetic properties of DNA are roughly classified into two distinct groups depending on their water content: One group is of higher water content in the range of 2.6-24 water molecules per nucleotide (wpn), where all the EMR parameters and SQUID susceptibilities are dominated by spin species experiencing quasi one-dimensional diffusive motion and are independent of the water content. The other group is of lower water content in the range of 1.4-0.5 wpn. In this group, the magnetic properties are most probably dominated by cyclotron motion of spin species along the helical π -way, which is possible when the momentum scattering time (${\tau}_k$) is long enough not only to satisfy the cyclotron resonance condition (${\omega}_c{\tau}_k$ > 1) but also to induce a constructive interference between the neighboring double helices. The same effect is reflected in the S-shaped magnetization-magnetic field strength (M-H) curves superimposed with the linear background obtained by SQUID measurements, which leads to larger susceptibilities at 1000 G when compared with the values at 10,000 G. In particular, we propose that the spin-orbital coupling and Faraday's mutual inductive effect can be utilized to interpret the dimensional crossover of spin motions from quasi 1D in the hydrate state to 3D in the dry state of dsDNA.

• 한국건설순환자원학회논문집
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• 제8권1호
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• pp.39-48
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• 2020

본 연구에서는 철과 니켈의 합금강 제조공정에서 발생하는 산업부산물인 페로니켈슬래그를 혼입하여 기존 결합재와의 화학반응 및 성능을 확인하였다. 고로슬래그 미분말과 페로니켈슬래그를 활용하여 시멘트 대비 치환률 50%까지 삼성분계 치환하여 실험을 통해 기초 물성 및 특징을 평가하였다. 실험 결과에 따르면 페로니켈슬래그를 혼입할 시 포졸란 반응이 기여하여 밀실한 내부 공극 및 수화물이 형성되었고, 수화열과 건조 수축 감소 효과도 나타났다. 압축강도는 초기 재령에는 다소 저조한 강도발현을 나타냈으나, 28일 장기재령으로 갈수록 강도 증가가 나타났다. 추후 최적 배합을 도출하여 용도에 맞게 활용할 경우 시멘트 결합재로서의 활용 가능성이 기대된다.