• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 봄 학술논문 발표대회
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• pp.151-152
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• 2023

This study investigates the effect of nano-silica and nano-calcite on the hydration properties and mechanical performance of limestone calcined clay cement (LC³) paste. The pastes were synthesized by replacing limestone with nano-silica and nano-calcite in order to enhance the mechanical properties in both early and late stages of hydration. The nano-calcite enhanced the strength of LC³ pastes at 1 day of hydration, however, the strength decreased compared to the ordinary LC³ pastes afterwards due to excessive amount of carboaluminate produced in the pastes. On the other hand, nano-silica improved the mechanical properties of LC³ pastes at all ages of hydration. This is mainly due to the nucleation effect and pozzolanic reaction of nano-silica, affecting the early age and late ages of hydration, respectively. The nucleation effect of both nanomaterials were confirmed by the analysis of hydration heat, supporting the enhanced early age strength of nanomaterial incorporated LC³ pastes. Furthermore, the dense matrix was shown in the pore size distribution, and the increased C-S-H due to the pozzolanic reaction evidence the improved compressive and splitting tensile strength of nano-silica incorporated LC³ pastes.

• 콘크리트학회논문집
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• 제21권4호
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• pp.481-488
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• 2009

시멘트페이스트, 모르타르 및 콘크리트의 자기수축의 크기 및 발현율은 초기재령 내부온도의 이력과 크기에 의해 영향을 받는다고 보고된 바 있으나, 초기재령 수화열과 자기수축에 대한 구체적인 관계분석은 아직 미흡한 실정 이다. 이 연구에서는 초기재령 수화온도 및 자기수축의 이력특성에 대한 분석방법을 제시한 선행연구를 기초로, 시험체 크기 및 수화지연 효과에 따른 고강도콘크리트의 초기재령 수화열과 자기수축의 거동특성 및 상관관계를 분석하였다. 또한 자기수축에 의한 균열평가시 유효자기수축의 기준이 되는 응결시간과 수화온도 및 자기수축의 이력과의 관계도 검토하였다. 그 결과, 시험체가 매스화될수록 초기재령 수화발열 상승구간의 수화온도 상승량 및 수화발열 상승속도, 자 기수축 증가구간의 자기수축 증가량 및 자기수축 속도는 증가하는 것으로 나타났으며, 지연제를 사용할 경우 그 값은 감소하는 것으로 나타났다. 초기재령 콘크리트의 수화발열 상승속도가 증가하면 자기수축 속도는 증가하며, 이와 더불 어 재령 91일 자기수축도 증가하는 것으로 나타나, 종국 자기수축은 초기재령 수화발열상승 속도에 의해 영향을 받을 수 있을 것으로 사료된다. 한편, 콘크리트 균열평가시 유효자기수축의 기준이 되는 응결시간과 변곡점 및 수화온도 상 승시점은 시멘트의 수화반응 과정에 있어 서로 밀접한 관계가 있음을 확인할 수 있었다.

• 한국세라믹학회지
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• 제27권3호
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• pp.383-388
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• 1990

Hydraulic properties of CA2-based clinker synthesized by Hydration-Burning Method was studied by calorimetry, analysis of suspension, thermogravimetry, scanning electron microscopy and X-ray diffractometry. Hydraulic properties of the clinker was so activated that heat of hydration of the clinker evolved faster than that of CA synthesized by conventional method. In suspension of W/C=33, dissolution of the clinker began at nearly same time as that of CA, but precipitation of AH3 and rise of [OH-] occurred fairly faster in the suspension of the clinker than that of CA. From the beginning of hydration, AH3 was produced and became a main phase of the hydrate with minor phase of CAH10 and C2AH8, but C3AH6 was not produced at ambient temperature.

• 한국농공학회논문집
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• 제50권2호
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• pp.27-34
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• 2008

Recently, owing to the development of industry and improvement of building techniques, concrete structures are becoming larger and higher. This study was performed to analyze hydration reation properties of concrete with binders and admixtures, such as OPC, low heat cement, belite rich cement, slag powder, lime powder and fly ash. To investigate effects of PC type superplasticizer on the hydration, experiments involving FT-IR, XRD, DSC, SEM were analyzed at the curing age 1day, 3days and 28days. The hydration reaction rate of OPC concrete slightly delayed at the curing age 1day, blast furnace slag powder and fly ash were more effective. BRC and LHC concretes can be used for concrete structures in winter season.

• 한국세라믹학회지
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• 제31권11호
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• pp.1387-1395
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• 1994

Re-hydration properties of heated and ground CaO-SiO2-H2O system were studied under hydrothermal condition in order to examine the possibility of recycling ALC waste as raw materials of ALC. Powder of calcium silicate hydrates and ALC waste without heat treatment did not show further hydration while those of heat-treated at proper temperature showed re-hydration properties under hydrothermal condition. The lath-like shape of initially synthesized tobermorite was gradually turned into small debris during heating and plate-like tobermorite was crystallized during re-hydration of the heated powders. Heated and ground ALC waste could be added to natural raw mix for ALC at the ammount up to 20% with increased compressive strength and up to 30% with slightly decreased compressive strength. The optimum heating temperature of ALC for recycling was about 50$0^{\circ}C$.

• 한국세라믹학회지
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• 제30권11호
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• pp.905-910
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• 1993

$\alpha$-tricalcium phosphate($\alpha$-TCP) powders were synthesized and their hydration properties were investigated in Tris. solution. Two kinds of $\alpha$-TCP powder samples were prepared; the one is reaction product of CaHPO4.2H2O and CaCO3, and another is that of hydroxyapatite(HAp) and $\beta$-Ca2P2O7. They were satisfied with Ca/P mole ratio 1.5 and were heated at 150$0^{\circ}C$ for 5 hours. In the hydration of $\alpha$-TCP samples the powder which was synthesized from HAp and $\beta$-Ca2P2O7 was hydrated faster than that from CaHPO4.2H2O and CaCO3. The hydration reaction of $\alpha$-TCP powder transformed rapidly into HAp accompanying setting and hardening. It was realized that the hydration reaction of $\alpha$-TCP was due to the solution-precipitation mechanism and the hydrates from the reaction were Ca-deficient HAp having funtional group HPO42-.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2013년도 춘계 학술논문 발표대회
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• pp.234-235
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• 2013

In order to evaluate the properties of reduced heat of hydrationof concrete mixed with slag, in the present study, we have evaluated by experimental and analytical characteristics of heat of hydration of concrete using the latent heat material and slag.

• 한국수소및신에너지학회논문집
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• 제33권3호
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• pp.219-225
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• 2022

In this study, as one part of the studies on the mechanical properties of the polymer electrolyte membrane, a study was conducted on the change in the mechanical properties due to hydration before and after aging of the polymer electrolyte membrane. The mechanical properties of the polymer electrolyte membrane changes due to hydration were confirmed through tensile tests of hydrated and non-hydrated Nafion 117. As results of this study, non-hydrated membrane showed higher mechanical properties than hydrated thing in the elastic region and some plastic regions. But, it was confirmed that hydrated membrane exhibited higher mechanical properties than non-hydrated thing in the large plastic region. Hydrated membrane has a lower glass transition temperature than non-hydrated thing due to the role of water as a plasticizer. In addition, the number of ion aggregates decreases, but the size increases, and the hydrated Nafion 117 is thought to have different mechanical properties from that of the non-hydrated thing due to the characteristic that the internal attraction is strengthened.

• 한국세라믹학회지
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• 제36권1호
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• pp.77-81
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• 1999

분말도가 포틀랜드 시멘트의 물성에 미치는 영향을 알아보기 위하여, 서로 다른 분말도(2300, 2500, 3000, 3500, 3500, 4500 $\textrm{cm}^2$/g)를 갖는 5종의 일반 포틀랜드 시멘트를 제조하여, Ca(OH)2 분석, 수화열, 유동성 및 물성 측정을 하였다. 그 결과, 시멘트의 분말도가 낮아짐에 따라 수화속도는 늦어졌고 수화열 및 압축강도는 떨어졌으나 유동성은 개선되었다. 특히 2300$\textrm{cm}^2$/g 시멘트의 경우, 수화열은 3500$\textrm{cm}^2$/g 시멘트에 비교해서 약 15% 감소하였다.

• 대한건축학회논문집:구조계
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• 제36권1호
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• pp.155-162
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• 2020

The aim of the research is to investigate the fundamental properties and heat of hydration reducing performance of the fly ash incorporated concrete mixture when the coal gas slag (CGS) from integrated gasification combined cycle (IGCC) is used as fine aggregate. From the results of the experiment, the workability was generally increased and the air content was decreased up to one to four percent with increasing the replacing ratio of CGS to fine aggregate. The compressive strength was similar or increased within five percent to the Plain mixture when the CGS was used as a fine aggregate. When the CGS and fly ash were used same time, the heat of hydration reducing performance was improved than single using cases either CGS or fly ash. Based on the results, for the concrete mixture using CSG as a portion of the combined fine aggregate, the general properties were improved and heat of hydration was decreased approximately 16 % when the fly ash was replaced 30 % to cement and the CGS was replaced less than 50 % to fine aggregate.