• 상하수도학회지
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• 제19권1호
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• pp.53-60
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• 2005

Ferrous cement hydrates made from hydrating Portland cement doped with Fe (II) were reported to reductively dechlorinate chlorinated organics and to reduce Cr (VI) to Cr (III). In this study, kinetics of nitrate removal by ferrous cement hydrates were investigated. Nitrate removal kinetics were characterized by experimental variables such as cement hydration, amount of cement addition, Fe (II) dose, pH, and byproducts. As a result, hydrated cement showed better performances than non-hydrated cement due to the formation of LDH (layered double hydroxide). Doping of Fe (II) into the cement was found to improve removal efficiency at high pHs by association with Fe (II) sorbed on cement hydrates as a reactive reductant. Reduction of nitrate produced ammonium as a major product, which accounted for 63.5% of the final products, and nitrite (0.15%) as a minor product. These results indicate that the developed media are effective as sorbent/reducing agents in the nitrate removal and the reaction mechanisms of nitrate removal are sorption and reduction.

• 한국세라믹학회지
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• 제53권1호
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• pp.7-12
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• 2016

In this paper, we have developed a simple, new and economical carbonation method to synthesize a pure form of aragonite needles using dolomite raw materials. The obtained aragonite Precipitated Calcium Carbonate (PCC) was characterized by XRD and SEM, for the measurement of morphology, particle size, and aspect ratio (ratio of length to diameter of the particles). The synthesis of aragonite PCC involves two steps. At first, after calcinated dolomite fine powder was dissolved in water for hydration, the hydrated solution was mixed with aqueous solution of magnesium chloride at $80^{\circ}C$, and then $CO_2$ was bubbled into the suspension for 3 h to produce aragonite PCC. Finally, aragonite type precipitated calcium carbonate can be synthesized from natural dolomite via a simple carbonation process, yielding product with average particle size of $30-40{\mu}m$.

• International Journal of Concrete Structures and Materials
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• 제6권3호
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• pp.155-163
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• 2012

In order to predict the neutralization of concrete which is the reaction of carbonation dioxide from the outside and cement hydration product, such as calcium hydroxide and C-S-H, it was studied the numerical analysis method considering change of the pore structure and relative humidity during the neutralization reaction. Diffusion-reaction neutralization model was developed to predict the neutralization depth of concrete with coating finishing material. In order to build numerical analysis models considering outdoor environment and finishing materials, the adaption of proposed model was shown the results of existing outdoor exposure test results and accelerated carbonation test.

• Childhood Kidney Diseases
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• 제13권1호
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• pp.21-25
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• 2009

2008년 말 발생한 멜라민 파동은 멜라민에 오염된 분유를 섭취한 영아들에서 요로계 결석이 발생한 것으로부터 비롯되었다. 멜라민 관련 요로계 결석의 위험인자는 3세 미만의 나이, 많은 멜라민 섭취량과 탈수, 요산의 요 배설량 증가 등의 일반적인 요로계 결석 위험인자의 동반이다. 멜라민 관련 결석은 주 성분이 요산이므로 수분 공급과 소변 알칼리화의 보존적인 치료로 회복되는 경우가 대부분이다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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• pp.629-634
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• 2001

Recently, to consider financial and constructive aspect, usage of Admixture, like Blast-Furnace Slag and Fly-Ash, are increased. Also the use of cold-weather-concrete is increased. Blast-furnace Slag, a by-product of steel industry, have many advantage, to reduce the heat of hydration, increase in ultimate strength and etc. But it also reduces early-age strength, so it is prevented from using of Blast-Furnace Slag at cold-weather-concrete. In this study, for the purpose of increasing usage of Blast-Furnace Slag at cold-weather-concrete, it is investigated the strength properties of concrete subjected to frost damage for the cause of early age curing. According to this study, if early curing is carried out before having frost damage, the strength of concrete, subjected to frost damage, is recovered. And that properties is not connected with the frost cause.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.143-148
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• 2002

Recently, to consider economical and constructive aspect, Usage of Admixture, like Blast-Furnace Slag and Fly-Ash, are increased. Blast-Furnace Slag, a by-product of steel industry, have many advantage, to reduce the heat of hydration, increase in ultimate strength and etc. But it also reduces early-age strength, it is prevented from using of Blast-Furnace Slag at cold-weather-concrete. In this study, for the purpose of increasing usage of Blast-Furnace Slag at cold-weather-concrete, it is investigated the strength properties of concrete subjected to time and period of frost damage for early age curing. According to this study, if early age curing is carried out before having frost damage, the strength of concrete, subjected to frost damage, is recovered. And that properties is not connected with the frost cause.

• 한국농공학회논문집
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• 제55권2호
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• pp.65-75
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• 2013

In this study, the engineering characteristics of volcanic ash-cement soil mixtures and zeolite-cement soil mixtures are investigated by using unconfined compression test, freezing-thawing test, SEM and XRD analysis. The samples were mixed with volcanic ash from Mt. Baekdusan or porous zeolite, and cement as the ratios of 3.5:1, 4.0:1, 4.5:1, 5.0:1 with and without metakaolin. It is confirmed that compressive strength degraded with increasing of the amount of volcanic ash or zeolite, and increased with addition of metakaolin as a binder. Moreover, test results suggested that the mixtures provided sufficient freezing-thawing resistance. In addition, ettringite as a product of cement hydration was detected by SEM and XRD, and that possibly contributes to the strength of the mixtures.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.687-690
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• 2005

Recently, to consider financial and constructive aspect, usage of Admixture, like Blast- Furnace Slag and Fly-Ash, are increased. These mineral admixtures, a by-product of steel industry, have many advantage, to reduce the heat of hydration, increase in ultimate strength, improve workability and etc. But it also reduces early-age strength, so it is prevented from using of Blast-Furnace Slag at cold-weather-concrete. In this study, for the purpose of increasing usage of mineral admixtures, like Blast-Furnace Slag and Fly ash, it is investigated the strength properties of concrete subjected to under low temperature According to this study, if early curing is carried out before having frost damage, the strength of concrete, subjected to frost damage, is recovered. And to consider increasing effect of strength, it is more effective to use of mineral admixtures, especially to use blast furance slag.

• 한국세라믹학회지
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• 제31권12호
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• pp.1507-1512
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• 1994

High strength cement hardened body was prepared by ordinary portland cement, silica-fume, super-plasticizer and the industrial by-product powder such as tailing, paper sludge ash and granulated slag. These raw materials were mixed and formed with w/c=0.18. The cement hardened body is cured in the autoclave at 18$0^{\circ}C$, 10atm. These admixtures made the compressive strength of all specimens develope by 170~230%. The highest compressive strength could be obtained by 236 MPa when mix composition was 14 wt% of silica-fume and 26 wt% of granulated slag. The compressive strength increased with decreasing the average pore size and the amount of the poe over the size of 50 nm by which the appearance of high compressive strength of the cement hardened body were mainly influenced. In the result, the hydration products were C-S-H, tobermorite and ettringite and it was realized that the reason why the cement hardened body became dense and revealed the higher strength was that those hydrates were formed inside of the pore and filled in it and the unhydrated materials played the role of an inner-filler.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1996년도 봄 학술발표회 논문집
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• pp.141-145
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• 1996

The primary purpose of this study is to investigate reusal techniques of by-product produced the combined heat power plant in the construction field, which may contribute to the savings of construction materials and the conservation of enviornment. This study is compared and evaluated by testing the chemical resistance, adiabatic temperature rising test, creep and drying shrinkage. As the result of the study, the following conclusions are derived : (1) hydration heat of the fly ash concrete is less than the plain concrete in adiabatic temperature rising test, (2) the fly axh concrete (FA 30%) is similar to the plain concrete in the chemical resistamce, (3) the fly ash concrete (FA 10, 30%) is similar to the plain concrete in drying shrinkage, but the fly ash concrete (FA 50%) is highly increased, (4) the fly ash concrete (FA 30%) is less than the plain concrete in creep test.