• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.6
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• pp.124-133
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• 2012

Compressive strength in concrete increases with time. Regression analysis with time is conventionally performed for strength evaluation and prediction. In this study, hydrate amount is assumed as a function of hydration rate and porosity, and modeling on compressive strength is carried out considering decreasing porosity with time, which does not need the regression analysis with time. For twenty one mix proportions of HPC (High Performance Concrete), DUCOM (FE program) which can simulate the behavior in early aged concrete is utilized, and porosity from each mix proportions is obtained with time. For HPC with OPC (Ordinary Portland Cement) concrete, modeling on compressive strength is performed considering hydration rate, unit content of cement, and porosity with time. For HPC with mineral admixtures, a long-term parameter which can handle long-term strength development is additionally considered. From the comparison with the previous test results, the applicability of the proposed model is verified.

• Journal of the Korea Concrete Institute
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• v.26 no.6
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• pp.723-730
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• 2014

The usage of Ground Granulated Blast Furnance Slag (GGBFS) has been increased recently. Studies on the cement hydration model incorporating GGBFS as well as the properties of cement paste done with GGBFS such as compressive strength, hydration products and hydration heat have been the subjects of many researches. However, studies on the reaction degree of GGBFS that affect the properties of cement paste incorporating GGBFS are lacking globally and specially in Korea. Thus, in this study, the reaction degree of GGBFS using the method if selective dissolution, compressive strength, the amount of chemical bound water and $Ca(OH)_2$ were measured and analysed in accordance with water-binder ratio, replacement ratio of GGBFS, and curing temperature. The results show that the reaction degree of GGBFS, the amount of chemical bound water and $Ca(OH)_2$ in cement paste with GGBFS were higher in conditions where the replacement ratio of GGBFS was low and both water-binder ratio and curing temperature were high. Finally, the reaction degree of GGBFS was achieved at a value between 0.3~0.4.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.10a
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• pp.285-288
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• 1999

Creep is a major parameter to represent long-term behavior of concrete structures concerning serviceability and durability. The effect of creep is recently taking account into crack resistance analysis of early-age concrete concerning durability evaluation. Since existing creep prediction models were proposed to predict creep for hardened concrete, most of them cannot consider effectively the information on microstructure formation and hydration developed in the early-age concrete. In this study, creep tests for early-age concrete made of the type I cement and the type V cement are carried out respectively and creep prediction models are evaluated for the prediction of creep behavior in early-age concrete. A creep prediction model is modified for the prediction of creep in early-age concrete and also verified by comparing prediction results with results of creep tests on early-age concrete.

• Applied Biological Chemistry
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• v.41 no.8
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• pp.568-571
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• 1998

The conformations of human insulin precursors, proinsulin and preproinsulin, are described in terms of molecular dynamics simulations. Despite the presence of the C-peptide and/or the signal peptide, molecular dynamics calculations utilizing the hydration shell model over a period of 500 ps indicate that the native conformations of the A and B chains are well conserved in both cases. These results further support the NMR spectroscopy results that the C-peptide is relatively disordered and does not influence the overall conformation of the native structure. The robustness of the native structure as demonstrated by experiment and simulation will permit future protein engineering applications, whereby the expression or purification yields can be improved upon sequence modification of the C-peptide and/or the signal peptide.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.05a
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• pp.521-526
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• 2001

Box-culvert is very important structure used almost every road construction. However this is treated very simple structure in design and construction. So many crack such as nonstructural crack has been occurred. This crack is very harmful on durability of concrete. In this study, thermal crack, one of the nonstructural crack, of box-culvert controled by using rapid-strength belite cement concrete. In this process, not only heat of hydration and thermal stress but also material mechanics properties and characteristics of durability were tested. and same model box-culvert using OPC concrete is constructed in same condition for comparison.

• International Journal of Concrete Structures and Materials
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• v.4 no.1
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• pp.37-43
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• 2010

Theoretical models based on modern interpretations of the morphology and interactions of cement hydration products are developed for prediction of the mechanical properties of hydrated cement paste (hcp). The models are based on the emerging nanostructural vision of calcium silicate hydrate (C-S-H) morphology, and account for the intermolecular interactions between nano-scale calcium C-S-H particles. The models also incorporate the effects of capillary porosity and microcracking within hydrated cement paste. The intrinsic modulus of elasticity and tensile strength of hydrated cement paste are determined based on intermolecular interactions between C-S-H nano-particles. Modeling of fracture toughness indicates that frictional pull-out of the micro-scale calcium hydroxide (CH) platelets makes major contributions to the fracture energy of hcp. A tensile strength model was developed for hcp based on the linear elastic fracture mechanics theories. The predicted theoretical models are in reasonable agreements with empirical models developed based on the experimental performance of hcp.

• Journal of the Korea Concrete Institute
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• v.16 no.1 s.79
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• pp.125-129
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• 2004

Hydrating concrete pavement is typically subjected to temperature-induced stresses that drive cracking mechanisms at early concrete ages. Undesired cracking plays a key role in the long-term performance of concrete pavement systems. The loss of support beneath the concrete pavement due to curling caused by temperature changes in the pavement may induce several significant distresses such as punch out pumping, and erosion. The effect of temperature on these distress mechanisms is both significant and intricate. Because thermal conductivity dominates temperature flow in hydrating concrete over time, this material property is back-calculated by transforming governing equation of heat transfer and test data measured in laboratory. Theoretically, the back- calculated thermal conductivity simulates the heat movements in concrete very accurately. Therefore, the back- calculated thermal conductivity can be used to calibrate concrete temperature predicted by models.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2001.04a
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• pp.10-17
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• 2001

With the introduction of durability examination into design code of concrete structure, a prediction of early-age behavior of concrete and its cracking resistance becomes very important. But, the early-age behaviors such as hydration, micro-structure development, moisture transport and mechanical properties development is quite complicated and coupled each other, and thus those can not be solved independently. One way to analyze those is to model their behaviors analytically and solve those computationally within a unified framework. In this paper, we propose a finite element technique to predict the early-age behaviors of concrete within the unified framework. The technique is applied to evaluatio of cracking in a massive concrete structure and then the analysis results are discussed.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.05a
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• pp.93-95
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• 2013

Recently, with the increase in the construction of ultra-high buildings and long-span structures, there is great demand for high-strength concrete which can reduce the structural weight and thickness of member sections. While developing high-strength concrete to meet performance requirements, certain issues at the design stage must also be considered. The issues include diseconomy from a great amount of per-unit cement, spalling failure by fire at ultra-high building, autogenous shrinkage caused by increased hydration activity of binder from use of a superplasticizer. Therefore, the purpose of this study is examined the strain characteristics of Fiber-reinforced-high-strength concrete(FRHSC), which differ from those of general concrete owing to autogenous shrinkage. Based on the experimental data, we proposed an autogenous shrinkage prediction model.

• Journal of Environmental Health Sciences
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• v.26 no.2
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• pp.91-96
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• 2000

We investigated characters of transdermal therapeutic system(TTS) and the skin permeability of that with applying drug delivery system(DDS). Natural gums were selected as material of TTS. The permeation of natural gums ointment containing drug in rat skin using diffusion cell model. Permeation properties of materials were investigated for water soluble drug such as riboflavin in vitro. We used glycerin, PEG 600 and oleic acid as enhancers. Since dermis has more hydration than the stratum corneum, skin permeation rate at steady state was highly influenced when glycerin was used in riboflavin. The permeation rate of content enhancer and drug was found to be faster than that of content riboflavin only. These results showed that skin permeation rate of drug across the composite was mainly dependent on the property of ointment base and drug. All the gum ointment tested showed good safety. Proper selection of the materials which resemble and enhance properties of the delivering drug was found to be important in controlling the skin permeation rate.