• 제목/요약/키워드: Hydration experiment

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고강도 콘크리트의 수화열 저감에 미치는 혼화재 종류 및 대체율의 영향에 관한 연구 (A Study on the Effect of Admixture Types and Replacement Ratio on Hydration Heat Reduction of High-Strength Concrete)

  • 김무한;최세진;오시덕;김용로;이종호
    • 한국건축시공학회지
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    • 제2권2호
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    • pp.145-150
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    • 2002
  • The hydration of cement paste occurs when the cement is miked with water. During the hydration, hydration heat causes the thermal stress depending on the site of concrete and the cement content. Especially in the high-strength concrete, we must give care to the concrete due to its large cement content. In this study conduction calorimeter and concrete insulation hydration heat meter were used to investigation the hydration heat characteristics of cement and concrete. To reduce hydration heat of high-strength concrete, several types of replacement of fly-ash and blast-furnace slag powder were used in this experiment. As a result of this study, it was found that hydration heat of high-strength concrete was reduced by replacement of fly-ash and blast-furnace slag powder. In case of high-strength concrete using blast-furnace slag powder, the max-heat arrival time was delayed but an effect of heat reduction was lower than a case of high-strength concrete using fly-ash, because it was considered that the heat-dependence property of blast-furnace slag powder was higher than that of fly-ash.

매입형 히트파이프를 이용한 매스콘크리트 수화열 분산 효과 (Dispersion Effect of Hydration Heat in Mass Concrete Using Embedded Heat Pipe)

  • 김명식;염치선;백동일
    • 한국해양공학회지
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    • 제23권4호
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    • pp.85-90
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    • 2009
  • Although most of existing hydration heat control methods show a certain degree of hydration heat control, generally, there are many problems as mentioned above. Therefore, our laboratory previously developed a hydration heat control method using an exposed heat pipe, which solves most of these problems and simultaneously displays excellent hydration heat control. Unfortunately, even this method had some problems such as the processing, transport, and assembly of heat pipes, and the surface treatment of a cut plane after pouring, and hardening concrete. Therefore, in this study, a hydration heat control method using an embedded pipe has been developed with the expectation that this method solves those problems in hydration heat control using an exposed heat pipe. As a result of the experiment, the peak temperature of ECHP and ICHP specimen about $4.5{\sim}6.5^{\circ}C$ than the OPC specimen and the probability of thermal cracked generated in ECHP and ICHP specimen decreased up to $13{\sim}20%$. Finally, it was confirmed in this study that the hydration heat control method using an embedded heat pipe is significantly more superior and cost effective than the existing method of an exposed one.

순환골재 용출수를 활용한 고로슬래그 미분말 혼입 모르터의 강도특성 (A Study on the Hydration Property of Mortar with Balst Furnace Slag using Water Eluted from Recycled Coarse Aggregates)

  • 신상엽;정의창;김영수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2012년도 추계 학술논문 발표대회
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    • pp.81-82
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    • 2012
  • The purpose of this study is the hydration properties of motar using Blast-Furnace Slag(BFS) with water elured from recycled coarse aggregate. The results of the experiment show that the water eluted from recycled coarse aggregate mixed with blast furnace slag has comparatively higher hydration activity than the mortar not mixed with one in early-age mortar causing the calcium hydroxide in the recycled coarse aggregate to work on as a stimulus to the hydration of ground granulated blast furnace slag. BFS mixed with the eluting water the hydration reaction was a promotion.

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제지(製紙) Sludge-Cement Board의 제조가능성(製造可能性)에 관(關)한 연구(硏究)(I) -수화반응(水和反應)에 의(依)한 경화장해지수측정(硬化障害指數測定)- (Studies on Manufacturing Possibility of Paper Sludge- Cement Board (I) -Measurement of Inhibitory Index by Hydration Reaction-)

  • 김은익;오정수
    • Journal of the Korean Wood Science and Technology
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    • 제21권3호
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    • pp.74-81
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    • 1993
  • This experiment was carried out to investigate the reaction of hydration of paper sludge during the setting of portland cement in a paper sludge, wood-cement-water mixturte. The percentage of paper sludge per cement is 7.5%, 15%, 30% respectively. The result indicated that the sludge of 7.5% had the most effect on reaction of hydration, and the sludge of 15% had moderately inhibitory effect but there is still possibility to make sludge-cement board. Paper sludge of 30%, Pinus koraiensis Sieb. et Zucc and Populus euramericana Guinier were proved to have the worst inhibitory effect on cement hydration, so pretreatment will be needed before making board with paper sludge-cement mixture.

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pH 변화에 따른 고로수쇄 BFS의 초기 수화 특성 (Early Hydration Properties of BFS by a Change of pH)

  • 강현주;이웅걸;송명신;강승민;김경남
    • 한국세라믹학회지
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    • 제49권5호
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    • pp.442-447
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    • 2012
  • This study investigated on the early hydration and physical characteristics of BFS by pH variation. NaOH solution was used as a pH activator. In the range from pH 12 to pH 14, Experiment was compared the hydration propertied of OPC(Ordinary Portland Cement) and BFS(Blast Furnace BFS) and BFS containing 2 wt% of gypsum. It was found that CAH(Calcium Aluminate Hydrates) phases and CSH(Calcium Silicate Hydrates) phases were formed during the early hydration of BFS, and that CAH phases, CSH phases and ettringites were formed during the early hydration of BFS containing 2 wt% of gypsum. Furthermore, early hydration of BFS and BFS containing 2 wt% of gypsum were faster then OPC at pH 14, and the 1 day compressive strength of BFS increased by approximately 30% compared to OPC, and BFS containing 2 wt% of gypsum also increased by approximately 40% compared to OPC.

에트링가이트-석회 복합계 팽창재의 수화반응 모델화 (Hydration Model of Ettringite-Gypsum Type Expansive Additive)

  • 박선규;야구귀문;송하원;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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    • pp.683-686
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    • 2004
  • In recent years, some attention was particularly given to cracking sensitivity of high performance concrete. It has been argued and demonstrated experimentally that such concrete undergoes autogenous shrinkage due to self-desiccation at early age, and, as a result, internal tensile stress may develop, leading to micro cracking and macro cracking. One possible method to reduce cracking due to autogenous shrinkage is the addition of expansive additive. Tests conducted by many researches have shown the beneficial effects of addition of expansive additive for reducing the risk of shrinkage-introduced cracking. However, the research on hydration model of expansion additive has been hardly researched up to now. This paper presents a study of the hydration model of Ettringite-Gypsum type expansive additive. Result of comparing forecast values with experiment value, proposed model is shown to expressible of hydration of expansive additive.

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콘크리트 수화발열 및 자기수축 특성의 정량적 분석을 위한 통계적 방법 (The statistical method for quantitative analysis of hydration heat and autogenous shrinkage of concrete)

  • 이의배;이형준;구경모;나철성;김규용;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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    • pp.645-648
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    • 2008
  • 본 연구에서는 초기재령 고강도 콘크리트의 수화발열 특성 및 자기수축 특성의 직접적인 상관관계를 분석하기 위한 기초연구로서, 우선 초기재령 콘크리트의 수화온도와 자기수축의 발현 특성을 정량적으로 표현할 수 있는 통계적 방법에 대해 고찰하였다. 우선 수화발열 특성 및 자기수축 특성을 표현할 수 있는 정량적인 계수로서 수화온도와 자기수축이 급격하게 증가하는 구간의 기울기인 수화발열상승속도와 자기수축증가속도를 설정하였으며, 이 두 계수는 통계적 수법을 활용하여 일정범위의 결정계수를 갖는 회귀계수로 산정하는 것으로 제안하였다. 또한 설정된 통계적 분석방법의 유효성을 검증하기 위해 실제 측정된 수화온도 및 자기수축 데이터를 분석하였으며, 그 결과 초기재령 고강도 콘크리트의 수화발열 특성 및 자기수축 특성을 보다 정량적으로 분석할 수 있었으며, 두 가지 특성의 상관관계를 정량적인 수치로 비교 분석하는 것이 가능하였다.

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하이볼륨 플라이애시 시멘트의 수화도 및 역학적 특성 (The Degree of Hydration and Mechanical Properties of High Volume Fly Ash Cement)

  • 차수원;최영철
    • 한국구조물진단유지관리공학회 논문집
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    • 제26권5호
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    • pp.95-102
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    • 2022
  • 최근, 전세계적으로 온실 가스의 저감에 관심이 높아지면서 건설 산업에서도 FA를 대량 치환하는 HVFAC의 사용을 위한 연구가 수행되고 있다. 시멘트의 수화도와 FA 반응도의 정량적인 측정은 HVFAC의 강도발현 메커니즘을 명확히 이해할 수 있게 한다. FA가 포함된 시멘트 페이스트의 수화 및 포졸란 반응은 매우 복잡하고 수화 생성물의 조성을 정확하게 결정할 수 없으므로 간단한 방법으로 반응도를 설명하는 것은 매우 어렵다. 따라서, 이 연구는 재령에 따른 하이볼륨 FA 시멘트의 수화 특성을 조사하였다. 시멘트의 수화도와 FA의 반응도는 재령에 따른 선택용해법과 페이스트의 비증발 수량을 통해 평가하였다. 또한 HVFA 모르타르 시편을 이용하여 연령에 따른 압축강도를 측정하였다. 실험결과 FA의 치환율이 증가할수록 시멘트의 수화도는 증가하나 FA의 반응성은 감소하는 것으로 나타났다.

화학 활성화제에 의한 플라이애쉬-생석회계의 수화반응 (hydration of the Fly Ash-CaO System in the Presence of Various Chemical Activators)

  • 송종택;김재영;류동우;고상렬;한경섭
    • 한국세라믹학회지
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    • 제35권2호
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    • pp.185-195
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    • 1998
  • This experiment carried out in order to investigate the effect of the chemical activators for acceleration of hydration the system of Fly ash-Cao The paste was consisted of 80wt% Fly ash and 20wt% CaO with 1. 3. 5wt% of 4 activators(N{{{{ alpha _2 }}S{{{{ OMICRON _4 }}, CaC{{{{ {l }_{2 } }}, NaOH, Ca(N{{{{ OMICRON _3 {)}_{2 } }} and W/S ratio of 0.42 After curing for 1, 3, 7, 14, 28 days the paste hydration was characterized by the measurement of compressive strength XRD analysis SEM observation the combined water and the reaction amount of Ca(OH)2 determination. As a result of this ex-periment all of the system which involved Na2SO4 or NaOH had a god compressive strength. In the case of 7 days curing a system which added CaCl2 showed the highest compressive strength among all especially NaOH system showed a high increase in strength as a dosage of it increased. Hydration products were different according to activatores added. Only C-S-H was observed in NaOH system. As the reaction amount of Ca(OH)2 and combined water were increased the compressive strength increased. There were few differences in the comparision of strength between ignited loss 3.1% and loss 9.3% of fly ash.

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조분 시멘트와 고로슬래그를 조합 사용한 콘크리트의 수화발열 특성 (Generation of Hydration Heat of the Concrete Combined Coarse Particle Cement and Blast Furnace Slag)

  • 노상균;백대현;장덕배;김영필;차완호;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2008년도 춘계 학술논문 발표대회
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    • pp.61-65
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    • 2008
  • This study, having combined and displaced blast furnace slag("BS" hereinafter) known as admixture material that delays hydration reaction with coarse particle cement("CC" hereinafter) collected in particle classification method during ordinary portland cement("OPC" hereinafter), reviewed the hydration heat characteristics affecting the concrete. To reduce hydration heat, the study plain-mixed which used 100% OPC for W/B 50% level 1, displaced CC at level 3 of 25%, 50% and 75% for OPC, and by displacing BS with admixture material at level 5 of 0%, 20%, 40%, 60% and 80% for cement(OPC+CC), experimented totally 16 batches. As a result of experiment, in the case of flow, the more CC displacement rate increased, the more it tended to decrease, and the more BS displacement rate increased, the more it decreased. Also, as for simple adiabatic temperature rise by the CC and BS displacement rates, it decreased as displacement rate increased, and particularly in the case of displaced BS of 80%, It showed temperature reduction effect of about 63% companing with plain. Compressive strength decreased in proportion to displacement rate, however strength reduction increment was shown to decrease with age progress.

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