• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.05a
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• pp.24-25
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• 2017

Ambient temperature has a direct impact on the hydraulic process. Though -any experiments have been processed in order to investigate the hydration properties under the various ambient temperature of OPC, there are not reported about aluminate-based composite. This presentation is composed of contents on the experimental investigation of the hydration heat of pulverized rapid cooling ladle furnace slag based composite. Based on the experimental outcomes, gypsum can decrease the hydration heat dramatically and lower ambient temperature has a negative effect on accelerated the hydraulic process.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.701-704
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• 2006

Recently, the attention is paid to the problem of thermal crack by hydration heat according to the increase of high strength and mass concrete structures. At this point, various research has been carried out for the control of hydration heat in high strength and mass concrete. As a part of the research, the application of Low Heat Technology (LHT) for the control of thermal crack by hydration heat was investigated in this study. To investigate the application, it was selected LHT which can reduce hydration heat of concrete with effect in series I and II. Also, it was investigated the characteristics of hydration heat generation of low heat concrete using LHT with binder types in seriesIII.

• Bulletin of the Korean Chemical Society
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• v.2 no.1
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• pp.24-28
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• 1981

Theoretical studies of the sodium cation binding and the isotope hydration effects on the static model compound B-DNA have been qualitatively elucidated by using empirical potential energy functions. In the first place, the sodium cations bound to phosphate anions and their hydration scheme have been optimized and have given a reasonable agreement with other theoretical results and experimental studies. In the second stage, the isotope effect on the hydration through the substitution of $D_2O\;for\;H_2O$ has been carried out by the same procedure. The stabilization of B-DNA has been explained and compared in terms of the sodium cation binding to phosphate anions and its hydration in both cases of $H_2O\;and\;D_2O$.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.35 no.6
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• pp.627-632
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• 2002

This study was investigated the changes of gel properties about pH, color and water holding capacity at various hydration time and temperature of food-grade additives (BPP: bovine plasma protein, DEW: dried egg white, SPI: soy protein isolate). The changes of rheological properties were checked about hydration time and temperature. Hydration time and temperature affected pH value, hydration decreased pH of SPI and DEW. The BPP was not influenced at hydration time and temperature. Some Hydration condition increased jelly strength of food-grade additive, but SPI did not form a gel at all hydration condition. Hydration increased lightness of food-protein.

• Journal of the Korean Ceramic Society
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• v.15 no.4
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• pp.205-212
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• 1978

The hydration reaction of the slag-gypsum system was studied by X-ray diffraction, differential thermal analysis, optical icroscopic observation, and measurement of heat liberation of hydration. 1. Domestic granulated slag was almost noncrystalized state, and its mineral compositions calculated were 46.53% of gehlenite, 28.14% of akermanite, and 19.04% of wollastonite. 2. The slag quenched with water at relatively high temperature had better reactivity. 3. The production of ettringite, CSH gel and AH3 gel were stimulated by effect of $Ca(OH)_2$, $Mg(OH)_2$ and calcined dolomite as activators, and the strength of hardened body would be developed by forming compacted microstructure.

• Journal of the Korean Ceramic Society
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• v.19 no.2
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• pp.133-138
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• 1982

Two kinds of clinker liquid melts, one containing 2.0% of $K_2O$ and the other without $K_2O$, were prepared with the similar composition as those developed during the firing of portland cement clinker. One portion of melt was quenched and found to consist of glass together with traces of proto-$C_3A$, and the other portion was allowed to cool spontaneously to crystallize $C_3A$ and calciumferrite well. The product obtained by crystallization of the melt without $K_2O$showed cubic $C_3A$, while orthorhombic $C_3A$ was formed from the crystallized product containing $K_2O$. Studies on the hydration behavior of the samples made from the melts with 30% of gypsum were carried out for 24 hours by observation at regular intervals ettringite, monosulphate hydrates and gypsum which were formed or consumed during hydration. The samples without $K_2O$ in the melts were hydrated wth addition of proper amount of $K_2SO_4$ in the water for hydration. Hydration behavior of glassified $C_3A$ showed that it has low reactivity relative to crystallized $C_3A$, and also hydration reactivity of orthorhombic $C_3A$ was much lower than that of cubic $C_3A$ in 60 minutes. Potassium sulphate in the solution reduced the hydration reactivity of $C_3A$ . Evolution peaks of hydration heat examined by twin-type conduction micro-calorimeter showed that glassified $C_3A$ without $K_2O$ had secondary peak after 9 hours and $C_3A$ containing $K_2O$ after 12 hours. When crystallized $C_3A$ was hydrated, initial peaks of hydration heat were considerably high and there was no secondary peak for cubic $C_3A$ but the secondary peak of orthorhombic $C_3A$ appeared after 4 hours.

• Resources Recycling
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• v.24 no.1
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• pp.12-20
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• 2015

In this study, change of hydration property with contents and type of gypsum in ternary natural hydraulic lime containing blast furnace slag and gypsum was investigated. Anhydrite, hemihydrate and dihydrate were added 3 % and 10 %, respectively in natural hydraulic lime adding blast furnace slag 20 %. Hydration and physical behavior due to solubility and reactivity of different types of gypsum were analyzed in early hydration. As a result of analysis of hydration properties, in all samples, hydrates such as ettringite and C-S-H were produced in early hydration, and amount of hydrates with increase of hydration time was increased. In the case of compressive strength, when contents of gypsum are 3 %, it was higher compressive strength than other specimens. At hydration 28 days, for addition of anhydrite and hemihydrate, compressive strength was more than adding dihydrate.

• International Journal of Concrete Structures and Materials
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• v.9 no.1
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• pp.55-60
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• 2015

In this study, influence of different stone powders (SP), including limestone powders (LP), quartzite powders (QP), and granitic powders (GP), on the hydration behaviors of portland cement, for example, setting time, hydration heat, and hydration products, were discussed. The initial and the final setting time both shorten when the content of LP is 5 %, however, they are slightly delayed by the other two SPs. The LP has no obvious influence on the arrival time of the first peak in the exothermal curves, and it makes the peak value decrease; the other two SPs postpone the appearance of the first peak, and they also make the peak value decrease. For the second peak, LP shifts the peak position to the left, QP has no effect on this peak position, and GP makes the appearance of this peak delayed by 143 min. Similarly, three kinds of SPs have different influence on the hydration products of portland cement. The LP precipitates the formation of hydrated calcium carbo aluminate, the QP the formation of hydrated garnet, and the GP makes the amount of Tobermorite increase.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.501-504
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• 2004

This paper proposes degree of hydration based shrinkage prediction model of 40MPa HPC. This model shows degree of hydration which is defined as the ratio between the hydrated cement mass and the initial mass of cement is very closely related to shrinkage deformation. In this study, degree of hydration was determined by CEMHYD-3D program of NIST. Verification of the predicted degree of hydration is performed by comparison between test results of compressive strength and estimated one by CEMHYD-3D. Proposed model is determined by statistical nonlinear analysis using the program Origin of Origin Lab. Co. To get coefficients of the model, drying shrinkage tests of four specimen series were followed with basic material tests. Testes were performed in constant temperature /humidity chamber, with difference moisture curing ages to know initial curing time effect. Verification with another specimen, collected construction field of FCM bridge, was given in the same condition as pre-tested specimens. Finally, all test results were compared to propose degree of hydration based model and other code models; AASHTO, ACI, CEB-FIP, JSCE, etc.

• Journal of the Korean Ceramic Society
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• v.47 no.5
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• pp.394-400
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• 2010

This study examined the effects of particle size on characteristics of cement by controlling the particle size of commercial cement. Through a size adjustment, the cement has increasing more of particles that are less than $10{\mu}m$ in size so the initial reaction time has been shortened as a result of improvement in the early hydration reaction. Additionally, it showed a great characteristics of strength from the early age and the initial hydration heat has been increased as well. In the upper and middle parts cements, the initial hydration reaction rate contribution is high with the $10{\mu}m$ compared to original cement. So the initial hydration reaction rate is improved and as a result, it also showed relatively high hydration heat as well. Additionally, adiabatic temperature also showed an increase rate in the results.