• Title/Summary/Keyword: Hydrated-Lime

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Neutralization Processes of Acid Mine Drainage (AMD) from the Abandoned Donghae Coal Mine (동해 폐탄광 일대 산성 광산폐수의 중화처리)

  • 김정엽;전효택;오대균
    • Journal of the Korean Society of Groundwater Environment
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    • v.2 no.1
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    • pp.38-47
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    • 1995
  • This study was carried out in order to provide basic information on neutralization processes of acid mine drainage (AMD) from the abandoned Donghae coal mine in the Samchuk coalfield. The contents of potentially toxic elements in stream water increase and the level of pH decreases during dry season. Hydrated lime is turned out to be the best neutralizer of the acid mine water from a technical and economic viewpoint. From the results of equilibrium calculation, Fe and Al could be precipitated as FeOOH, and Al(OH)$_3$, respectively, in the neutralization process. The sites of holding basins necessary to equalize quantity and quality of AMD are recommended by GIS analysis, and the capacities of holding basins are determined by hydrological calculation.

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CuO/3Al$_2$O$_3$ㆍ2SiO$_2$, 촉매담지 세라믹 캔들필터를 이용한 먼지/NOx/SOx/HCl 제거기술

  • 문수호;홍민선;이재춘;이동섭
    • Journal of Energy Engineering
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    • v.13 no.2
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    • pp.133-143
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    • 2004
  • Simultaneous removal technology of particulate/NOx/SOx/HCl using CuO/3Al$_2$O$_3$ㆍ2SiO$_2$catalyst impregnated ceramic candle filters is an advanced air pollution process and provides significantly to reduce hazardous gases emitted from coal-fired power plant. This process uses a high-temperature catalytic filter for integrating SOx and HCl reduction through injection an alkali sorbent (such as hydrated lime or sodium bicarbonate), NOx removal through ammonia injection and selective catalytic reduction (SCR), and particulate collection on the catalytic filter surface. The advantages of the process include : compact integration of the emission control technologies into a single component; easy handling of dry sorbent and by-product; and improved SCR catalytic life due to lowered SOx, HCl and particulate levels. CuO/3Al$_2$O$_3$ㆍ2SiO$_2$ catalyst impregnated ceramic candle filters showed a possibility of simultaneous treatment from results which have ascertained high removal efficiency at various combined gases conditions, and in pilot plant test for 3 months, NO conversion was showed 90% over.

Effect of pH of Casing Soil and Calcium on Mycelial Growth and Yield of Agaricus bisporus (Lge.) Sing (복토의 pH 및 칼슘이 양송이의 균사생장 및 수량에 미치는 영향)

  • Park Won Mok;Kim Dong Soo;Park Yong Hwan;Kwack Beyoung Hwa
    • Korean journal of applied entomology
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    • v.10 no.1
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    • pp.59-62
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    • 1971
  • The highest fresh weight of Agaricus bisporus was obtained at pH 7.5 of casing soil. Above or below this pH level, the yields were significantly reduced. Stimulatory effect of calcium on the mycelial growth depended upon pH of casing soil, In neutral or slightly alkaline soil, the stimulatory effect was increased. The effects of supplementing calcium carbonate or hydrated lime to casing soil were assumed not only the influence of pH of casing soil, but also stimulatory effect of calcium ion on mycelial growth of A. bisporus.

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Production Process of Foamed Glass by Compressive Shaping (가압성형 방법에 의한 발포유리의 제조공정)

  • Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.239-246
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    • 2013
  • Principle of foamed glass manufacturing process first starts with putting vitreous material powder into a mold. After the foaming calcination, foamed body should be annealed after separation from the mold. For this reason, existing manufacturing process could not be a continuous type process. In this study, in order to develop a continuous production process of foamed glass, the possibility of new foam glass manufacturing process was investigated by foaming calcination of the compact body obtained from compression-molding of vitreous raw materials in stead of using a mold. Through the experimental results of the foaming calcination of the compact body with adding various foaming agents such as $Na_2CO_3$, $CaCO_3$ and petroleum coke, into hydrated soda-lime vitreous raw materials, it was shown that developing a continuous process without using any molds for manufacturing foamed glass would be possible.

Evaluation of Moisture Susceptibility of Asphalt Mixtures Using Boiling Water Test (보일링 시험을 통한 아스팔트 혼합물의 수분민감성 평가)

  • Kim, Jun;Park, Dae-Wook;Vo, Viet Hai;Kim, Hyeok-Jung;Park, Jun-Sang
    • International Journal of Highway Engineering
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    • v.17 no.1
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    • pp.77-82
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    • 2015
  • PURPOSES : The purpose of this paper is to evaluate the moisture susceptibility of asphalt mixtures containing developed liquid anti-stripping agents using the boiling water test as a screening test. METHODS : The boiling water test was used to evaluate the moisture susceptibility of asphalt mixtures containing different anti-stripping agents. The tensile strength ratio was calculated to compare the moisture susceptibility of the asphalt mixtures after indirect strength tests were performed. Additionally, image analysis techniques were used to calculate and analyze the quantity of stripped area in the asphalt mixtures. RESULTS : In general, the asphalt mixtures containing anti-stripping agents showed a higher resistance of anti-stripping based on the boiling water test and tensile strength ratio. CONCLUSIONS : The boiling water test can be used to differentiate the resistance of moisture susceptibility of asphalt mixtures, except for asphalt mixtures containing hydrated lime. The boiling water test can be used as a screening test for asphalt mixtures before conducting time consuming and expensive indirect tensile strength tests.

Strength Properties of Recycled Concrete Containing Water-redispersible Copolymer Powder (재유화형분말수지를 혼입한 재생콘크리트의 강도 특성)

  • Kim, In-Su;Sung, Chan-Yong
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.128-134
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    • 2005
  • This study was performed to evaluate the strength and durability properties of recycled concrete containing water - redispersible copolymer powder(WRP) and blast furnace slag powder(BSP) [RCWS]. Material used were cemente, recycled coarse aggregare, natural fine aggregate, water-redispersible copolymer powder, blast-furnace slag powder. Especially, Water-redispersible powder was used for blending with Inorganic binders such as cemente, gypsum and hydrated lime etc. First of all, Mixed ratio method of RCWS made Two Type. One was called type-1 which used to BSP content 5% and WRP(Water-redispersible powder) content 0%, 1%, 2%, 3%, 4%, 5%, 6%. respectively. Another was called Type-2 which used to BSP(blast furnace slag powder)content 10% and WRP(Water-redispersible powder) content 0%, 1%, 2%, 3%, 4%, 5%, 6%. respectively. According to the experimental results of (RCWS), Incase Type-2 at curing age 28days, Compressive strength, pulse velocity and dynamic modulous of elasticity were shown higher than Type-1 and The more WRP content increasing($0%{\sim}6%$) was the lower Compressive strength, Pulse velocity and Dynamic modulous of elasticity. Water absorption ratio was in the range of $3.85%\;{\sim}\;3.23%$, it was almost equal to Type-1, 2 but Increasing the WRP content($0%{\sim}6%$), The water absorption ratio is decreased.

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Effect of Cassava Hay and Rice Bran Oil Supplementation on Rumen Fermentation, Milk Yield and Milk Composition in Lactating Dairy Cows

  • Lunsin, R.;Wanapat, Metha;Rowlinson, P.
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.10
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    • pp.1364-1373
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    • 2012
  • Four crossbred (75% Holstein Friesian) lactating dairy cows, with an average live weight of $418{\pm}5$ kg and $36{\pm}10$ d in milk were randomly assigned according to a $2{\times}2$ factorial arrangement in a $4{\times}4$ Latin square design to evaluate the effects of cassava hay (CH) and rice bran oil (RBO) on feed intake, nutrient digestibility, ruminal fermentation, milk yield, and milk composition. Factor A was non-supplementation or supplementation with CH in the concentrate. Factor B was supplementation with RBO at 0% or 4% in the concentrate mixture. The four dietary treatments were (T1) control (Concentrate with non-CH plus 0% RBO; C), (T2) Concentrate with CH plus 0% RBO (CH), (T3) Concentrate with non-CH plus 4% RBO (RBO), and (T4) Concentrate with CH plus 4% RBO (CHRBO). The cows were offered concentrate, at a ratio of concentrate to milk production of 1:2, and urea-lime treated rice straw was fed ad libitum. Urea-lime treated rice straw involved 2.5 g urea and 2.5 g $Ca(OH)_2$ (purchased as hydrated lime) in 100 ml water, the relevant volume of solution was sprayed onto a 100 g air-dry (91% DM) straw, and then covering the stack with a plastic sheet for a minimum of 10 d before feeding directly to animals. The CH based concentrate resulted in significantly higher roughage intake and total DM intake expressed as a percentage of BW (p<0.05). Ruminal pH, $NH_3$-N, BUN and total VFA did not differ among treatments, while RBO supplementation increased propionate, but decreased acetate concentration (p<0.05). Furthermore, the population of total ruminal bacteria was significantly lower on the RBO diet (p<0.05). In contrast, the total ruminal bacteria and cellulolytic bacteria on the CH diet were higher than on the other treatments. Supplementation with CH increased (p<0.05) F. succinogens and R. flavefaciens populations, whereas the populations of B. fibrisolvens and M. elsdenii were increased on the RBO diet. In addition, supplementation with CH and RBO had no effect on milk production and composition in dairy cows, while fatty acid composition of milk was influenced by RBO supplementation, and resulted in significantly lower (p<0.05) concentrations of both short-chain and medium-chain FA, and increased (p<0.05) the proportion of long-chain FA in milk fat, as well as significantly increased cis-9, trans-11 CLA and total CLA. In conclusion, RBO or CH exhibited specific effects on DMI, rumen fermentation, microbial population, milk yield and composition in lactating dairy cows, which were not interactions between CH and RBO in the diets. Feeding lactating dairy cows with RBO could improve fatty acid in milk fat by increasing cis-9, trans-11 CLA.

Evaluation of Moisture Susceptibility on Asphalt Mixtures mixing Anti-Stripping Agent (박리방지제의 첨가에 따른 아스팔트 혼합물의 수분민감성 평가)

  • Yang, Sung-Lin;Hwang, Sung-Do;Kim, Yeong-Min;Jeong, Kyu-Dong
    • International Journal of Highway Engineering
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    • v.10 no.4
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    • pp.41-52
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    • 2008
  • This study is to evaluate the property for the moisture susceptibility of asphalt mixtures using anti-stripping agent. Asphalt mixtures using lime, hydrated lime and liquid anti-stripping agent are evaluated through the three types of modified moisture conditioning($H_c$, V_s$, F-T). Indirect Tensile Test, that is recommended by AASHTO TP-9, which includes creep test, resilient modulus test and strength test is used to estimate moisture susceptibility. Analysis method through Energy Ratio(ER) that is proposed by Roque at University of Florida is used to evaluate moisture susceptibility and moisture resistance effects of asphalt mixtures using anti-stripping agent. As a test result, material property of asphalt mixtures was changed by moisture conditioning methods and the types of anti-stripping agent. Also, cracking resistance of accumulated moisture damage was changed by moisture conditioning methods and the types of anti-stripping agent. Based on test result, it was found that cracking resistance using Energy Ratio was differed from 10% to 30%.

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Hybrid neutralization and membrane process for fluoride removal from an industrial effluent

  • Meftah, Nouha;Ezzeddine, Abdessalem;Bedoui, Ahmed;Hannachi, Ahmed
    • Membrane and Water Treatment
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    • v.11 no.4
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    • pp.303-312
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    • 2020
  • This study aims to investigate at a laboratory scale fluorides removal from an industrial wastewater having excessive F- concentration through a hybrid process combining neutralization and membrane separation. For the membrane separation operation, both Reverse Osmosis (RO) and Nanofiltration (NF) were investigated and confronted. The optimized neutralization step with hydrated lime allowed reaching fluoride removal rates of 99.1± 0.4 %. To simulate continuous process, consecutive batch treatments with full recirculation of membrane process brines were conducted. Despite the relatively high super saturations with respect to CaF2, no membrane cloaking was observed. The RO polishing treatment allowed decreasing the permeate fluoride concentration to 0.9± 0.3 mg/L with a fluoride rejection rate of 93± 2% at the optimal transmembrane pressure of around 100 psi. When NF membrane was used to treat neutralization filtrate, the permeate fluoride concentration dropped to 1.1± 0.4 mg/L with a fluoride rejection rate of 88± 5% at the optimal pressure of around 80 psi. Thus, with respect to RO, NF allowed roughly 20% decrease of the driving pressure at the expense of only 5% drop of rejection rate. Both NF and RO permeates at optimal operating transmembrane pressures respect environmental regulations for reject streams discharge into the environment.

Enhancement of the Characteristics of Cement Matrix by the Accelerated Carbonation Reaction of Portlandite with Supercritical Carbon Dioxide

  • Kim, In-Tae;Kim, Hwan-Young;Park, Geun-Il;Yoo, Jae-Hyung;Kim, Joon-Hyung;Seo, Yong-Chil
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.586-591
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    • 2001
  • This research investigated the feasibility of the accelerated carbonation of cement waste forms with carbon dioxide in a supercritical state. Hydraulic cement has been used as a main solidification matrix for the immobilization of radioactive and/or hazardous wastes. As a result of the hydration reaction for major compounds of portland cement, portlandite (Ca(OH)$_2$) is present in the hydrated cement waste form. The chemical durability of a cement form is expected to increase by converting portlandite to the less soluble calcite (CaCO$_3$). For a faster reaction of portlandite with carbon dioxide, SCCD (supercritical carbon dioxide) rather than gaseous $CO_2$, in ambient pressure is used. The cement forms fabricated with an addition of slated lime or Na-bentonite were cured under ambient conditions for 28days and then treated with SCCD in an autoclave maintained at 34$^{\circ}C$ and 80atm. After SCCD treatment, the physicochemical properties of cement matrices were analyzed to evaluate the effectiveness of accelerated carbonation reaction. Conversion of parts of portlandite to calcite by the carbonation reaction with SCCD was verified by XRD (X-ray diffraction) analysis and the composition of portlandite and calcite was estimated using thermogravimetric (TG) data. After SCCD treatment, tile cement density slightly increased by about 1.5% regardless of the SCCD treatment time. The leaching behavior of cement, tested in accordance with an ISO leach test method at 7$0^{\circ}C$ for over 300 days, showed a proportional relationship to the square root of the leaching time, so the major leaching mechanism of cement matrix was diffusion controlled. The cumulative fraction leached (CFL) of calcium decreased by more than 50% after SCCD treatment. It might be concluded that the enhancement of the characteristics of a cement matrix by an accelerated carbonation reaction with SCCD is possible to some extent.

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