• Title/Summary/Keyword: Hydrated-Lime

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Production of Foamed Glass by Using Hydrolysis of Waste Glass (II) - Foaming Process of Hydrated Glass - (폐유리의 가수분해 반응에 의한 발포유리의 제조(II) - 가수분해된 유리의 발포 -)

  • Lee, Chul-Tae;Lee, Hong Gil;Um, Eui-Heum
    • Applied Chemistry for Engineering
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    • v.16 no.6
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    • pp.760-767
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    • 2005
  • The goal of this study was to find an application method of the waste soda-lime glass as the feed material for foamed glass by foaming of hydrated waste glass. The proper conditions for the foaming of hydrated waste glass were found to be: temperature of $92.5^{\circ}C$; reaction time of 10~20 min; particle size of -325 mesh as the unhydrated glass starting materials; and graphite weight to the hydrated glass ratio of 0.003 as the foaming agent. The resulting formed glass made from hydrated mixed waste glass under above mentioned conditions had the characteristics of density less than $0.2g/cm^3$ and thermal conductivity of $0.05kcal/mh^{\circ}C$.

The Synthesis and Hydraulic properties of Calcium Sulfo Aluminate(CSA) derived from Secondary Refining Slag. (제강 2차 정련 슬래그를 재활용한 칼슘설포알루미네이트(CSA) 합성 및 수화 특성)

  • Seo, Chang Woo;Kim, Seon-Hyo;Ko, Sang Jin;Kim, Sang Hyun;Jo, Kyu Young
    • Korean Journal of Metals and Materials
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    • v.46 no.7
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    • pp.437-442
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    • 2008
  • The synthesis and hydration of Calcium Sulfo Aluminate[$3CaO{\cdot}3Al_2O_3{\cdot}CaSO_4(C_4A_3{\overline{S}})$, CSA cement utilizing secondary steelmaking refining slags is studied for recycling the discarded steel plant wastes to meet the environmental requrations imposed on the steel industry. Raw materials of secondary refining slag, lime sludge, gypsum and bauxite were prepared to be sintered at $1,250^{\circ}C$. The sintered samples were hydrated for 1, 3 and 7 days to evaluate the mineralogical and physico-mechanical properties. The hydration products evaluated with the aid of SEM and XRD analyses confirmed the formation and the continuing growth of ettringite phase with the further hydration times, which plays a role in developing the early strength and the expansion properties of cements. The physico-mechanical properties of hydrated CSA products employing the recycled steelmaking refining slags determined in terms of compressive strength and linear expansion of hydrated products are found to be superior to those of the Ordinary Portland Cement(OPC) or the other commercial CSA cements.

Influence of Sulfate on the Early Hydration in the Solidification of Lime-tailings (소석회-광물찌꺼기 고형화의 초기 수화에 미치는 황산염의 영향)

  • Lee, Hyun-Cheol;Min, Kyoung-Won;Yoo, Hwan-Geun
    • Economic and Environmental Geology
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    • v.46 no.6
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    • pp.535-544
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    • 2013
  • Influence of sulfate on the early hydration in the solidification treatment of abandoned mine tailings was characterized. Solidified specimens using hydrated lime as a binder were prepared with various amounts of added $Na_2SO_4$ and different curing days. Unconfined compressive strength measurement, heavy metal leaching test, XRD analysis were performed after 7-, 14- and 28-days curing. According to curing days strength of solidified specimens using only distilled water increased but those with addition of $Na_2SO_4$ decreased. External cracks of specimens developed definitely with increasing $Na_2SO_4$ concentration and curing days. Concentrations of Cu, Cd, Zn, and As in the leached solutions from solidified specimens decreased significantly but Pb was leached readily in cases of hydrated lime dosage more than 10 wt%. Gypsum and $MgSO_4$ were identified in the cracked solidified specimens by XRD analysis, and pillar-shaped crystals of SEM image were identified as gypsum in reference with EDS analysis. Crystallization of sulfate in the process of lime-tailing solidification caused cracking, which should be supplemented for solidification treatment of highly sulfur-contained tailing.

Preparation and Characterization of Porous Filters from Ca(OH)2 and CaCO3 for SO2 Removal in Dry-FGD Process (건식 FGD 공정에서 SO2 제거를 위한 Ca(OH)2 및 CaCO3 원료의 다공성 필터 제조 및 특성)

  • Han, Yo-Seop;Kim, Hyun-Jung;Park, Young-Goo;Park, Jai-Koo
    • Applied Chemistry for Engineering
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    • v.16 no.6
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    • pp.772-777
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    • 2005
  • Porous hydrated lime and limestone filters were prepared by foaming and gelcasting method, and their physical properties were evaluated. Through these analyses, it has been found that with the increased porosity and pore size of the filters, majority of pores in the filters were inter-connected by windows. Also, $SO_2$ removal efficiency for the filters was investigated. As the porosity and the reaction temperature increased, $SO_2$ removal efficiency also increased. Especially, unlike the variation of entrance concentration, the entrance flow rate had great influence on the removal efficiency. In case of the filters with an equal porosity, the hydrated lime filter had superior removal efficiency compared to the limestone filter. From these results, it was shown that the high conversion ratio to CaO from the hydrated lime filter was a result of facilitated formation of $CaSO_4$ by $SO_2$.

Lime addition chemical stabilization of expansive soil at Al-Kawamil city, Sohag region, Egypt

  • Farghaly, Ahmed Abdelraheem;El-Shater, A.;Naiem, Mostafa Abdou Abdel;Hamdy, Fatma
    • Advances in Computational Design
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    • v.5 no.1
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    • pp.1-11
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    • 2020
  • Soil is the fundamental element in the construction process. Soil problems affect the safety of the structures, even so the high quality of the structures and so, bad soil found the structures will affect the lifetime or even destroy the structures built on it. Therefore, the study of soil is an important step in the construction process and the investigation of the most effective characteristics of a special kind of soil (shale soil), i.e. Atterberg limits, swelling pressure, swelling potential and unconfined compression strength, are the most effective soil properties. A big projects will be constructed in new urban extension areas with expansive shale soils, like at Al-Kawamil and new Akhmim shale soils which associated with soil problems, treatment system should be used to ensure the stability of the soil under the structures foundations one of the most effective methods is by adding lime solution to the soil by specific quantities, which affect on the properties of the shale soil by decreasing the swelling and increasing the compressive strength of the treatment soils. Experimenting with the soil added to the lime, it was found that the addition of lime solution 6% improve c j the properties of the soil. The results of the tests showed the high effectiveness of using lime in the treatment of Al-Kawamil soil

Microstructural properties of hardened cement paste blended with coal fly ash, sugar mill lime sludge and rice hull ash

  • Opiso, Einstine M.;Sato, Tsutomu;Otake, Tsubasa
    • Advances in concrete construction
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    • v.5 no.3
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    • pp.289-301
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    • 2017
  • The synergistic interactions of supplementary cementitious materials (SCMs) with ordinary portland cement (OPC) in multi-blended systems could enhance the mechanical and durability properties of concrete and increase the amount of cement that can be replaced. In this study, the characteristics of the hydration products as well as paste microstructure of blended cement containing 20% coal fly ash, 10% rice hull ash and 10% sugar mill lime sludge in quaternary blended system was investigated. Portlandite content, hydration products, compressive strength, pore size distribution and microstructural architecture of hydrated blended cement pastes were examined. The quaternary blended cement paste showed lower compressive strength, reduced amount of Portlandite phases, and higher porosity compared to plain hardened cement paste. The interaction of SCMs with OPC influenced the hydration products, resulting to the formation of ettringite and monocarboaluminate phases. The blended cement paste also showed extensive calcium silicate hydrates and calcium aluminate silicate hydrates but unrefined compared to plain cement paste. In overall, the expected synergistic reaction was significantly hindered due to the low quality of supplementary cementitious materials used. Hence, pre-treatments of SCMs must be considered to enhance their reactivity as good quality SCMs can become limited in the future.

Reuse of dredged sediments as pavement materials by cement kiln dust and lime treatment

  • Yoobanpot, Naphol;Jamsawang, Pitthaya;Krairan, Krissakorn;Jongpradist, Pornkasem;Horpibulsuk, Suksun
    • Geomechanics and Engineering
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    • v.15 no.4
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    • pp.1005-1016
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    • 2018
  • This paper presents an investigation on the properties of two types of cement kiln dust (CKD)-stabilized dredged sediments, silt and clay with a comparison to hydrated lime stabilization. Unconfined compressive strength (UCS) and California bearing ratio (CBR) tests were conducted to examine the optimal stabilizer content and classify the type of highway material. A strength development model of treated dredged sediments was performed. The influences of various stabilizer types and sediment types on UCS were interpreted with the aid of microstructural observations, including X-ray diffraction and scanning electron microscopy analysis. The results of the tests revealed that 6% of lime by dry weight can be suggested as optimal content for the improvement of clay and silt as selected materials. For CKD-stabilized sediment as soil cement subbase material, the use of 8% CKD was suggested as optimal content for clay, whereas 6% CKD was recommended for silt; the overall CBR value agreed with the UCS test. The reaction products calcium silicate hydrate and ettringite are the controlling mechanisms for the mechanical performance of CKD-stabilized sediments, whereas calcium aluminate hydrate is the control for lime-stabilized sediments. These results will contribute to the use of CKD as a sustainable and novel stabilizer for lime in highway material applications.

Characteristics of Asphalt Concrete using Waste Foundry Sand (주물고사 첨가 아스팔트 콘크리트의 특성에 관한 연구)

  • Kim, Kwang-Woo;Ko, Dong-Hyuk;Choi, Dong-Chon;Kim, Sung-Won;Kim, Joong-Yul
    • International Journal of Highway Engineering
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    • v.3 no.4 s.10
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    • pp.105-116
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    • 2001
  • This study was performed to evaluate the characteristics of waste foundry sand (WFS) and the asphalt mixture made of a foundry waste sand. To estimate the applicability of WFS, chemical and physical properties were measured by XRF(X-ray fluorescent), and SEM(Scanning electronic microfilm). To improve the stripping resistance of WFS asphalt mixture, anti-stripping agents (a hydrated lime and a liquid anti-stripping agent) were used. To improve tensile properties and durability of WFS asphalt concrete mixture, LDPE(low-density polyethylene) was used as an asphalt modifier Marshall mix design, indirect tensile strength, tensile strength ratio(TSR) after freezing and thawing, moisture susceptibility and wheel tracking tests were carried out to evaluate performance of WFS asphalt concrete. Comparing with conventional asphalt concrete, WFS asphalt concretes showed similar or the better qualify in mechanical properties, and satisfied all specification limits. Therefore, it Is concluded that waste foundry sand can be recycled as an asphalt pavement material.

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The effect of anti-stripping on asphalt mixtures depending on the types of anti-stripping agents (박리방지제에 따른 아스팔트 혼합물의 박리방지 특성 연구)

  • Kim, Won Jae;Tran Van, Phuc;Do Thanh, Chung;Park, Chang Kyu;Lee, Hyun Jong
    • International Journal of Highway Engineering
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    • v.19 no.2
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    • pp.127-135
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    • 2017
  • PURPOSES: The objective of this study is to evaluate the effect of anti-stripping on asphalt mixtures constituting anti-stripping agents. METHODS : Based on the literature review, asphalt mixture added with anti-stripping agents was prepared, and these asphalt mixtures were evaluated for anti-stripping properties for each anti-stripping agent through various lab tests, namely, tensile strength ratio (TSR), dynamic immersion test, uniaxial compression test, and indirect tensile strength test (IDT). The liquid anti-stripping agents used in the lab test were premixed with each asphalt binder (PG 64-22, PG 76-22) before being mixed with the aggregate. RESULTS :The result of the TSR test revealed that the effect of anti-stripping was highest when hydrated lime and liquid anti-stripping agent W were added. The correlation coefficient $R^2$ between the TSR result and cohesion ratio is 0.99, which indicates that the sensitivity of the TSR to moisture damage is reliable from the mechanical point of view. The covering ratio of the asphalt binder to the liquid anti-stripping agent W was determined to be higher than that to the other liquid anti-stripping agents. CONCLUSIONS :It is considered that the improved moisture resistance of asphalt mixture as a result of the use of anti-stripping agents can reduce the incidence of various pavement damages such as portholes caused by stripping, and the performance life of the asphalt road pavement can be prolonged.

Study of Lime Finishing Layer(intonaco) in Koguryo Tomb Murals (고구려 고분벽화의 석회마감층에 관한 연구)

  • Lee, Hwa-Soo;Han, Kyeong-Soon
    • Journal of Conservation Science
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    • v.19
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    • pp.43-56
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    • 2006
  • We checked the conditions and material properties after producing the lime finishing layers with a mortar mix of processed lime. In addition, we reproduced the lime finishing layers of the Koguryo Tomb Murals, colored the layers with a few different techniques and identified the characteristics for each painting technique. As a result of the experiment, we could infer the producing techniques as well as teaming the conditions and properties of the lime finishing layers of the Koguryo tomb murals, and examined the maintenance of the lime finishing layers. Of those samples produced under various conditions, the layers of slaked lime, which were obtained after being hydrated underground for a long time, showed quite a good condition. Thus the slaked lime mixes produced through particular hydration methods are judged to increase the maintenance of the lime finishing layers of the Koguryo Tomb Murals. Mostly, the paints of Koguryo Tomb Murals indicated that they have similar conditions with the samples produced with a secco method. In addition, Considering the compositional forms of the painting layers and the boundary layers which formed between the painting layers and the finishing layers, we can verify that, in some cases, the conditions of the painting layers of the Koguryo tomb murals are similar to those which were produced with a combination of fresco and secco.

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