• Journal of the korean academy of Pediatric Dentistry
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• v.29 no.3
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• pp.455-462
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• 2002

Currently, the ages of the patients visiting dental hospital for dental care are becoming younger and the interest in the treatment for the handicapped and incapable of cooperation children increases. As a method for treatment of these patients, the sedation treatment is considered. A dental sedation using chloral hydrate and hydroxyzine of them were used widely and for a long time. In this study, the samples were consisted of incapable of cooperation or very young children required treatment of restoration under local anesthesia. Then, the vital signs were accessed in pediatric dental sedation using the combination of chloral hydrate and hydroxyzine. As a result of this study, the vital signs were little different in pediatric dental sedation using the combination of chloral hydrate and hydroxyzine. Simply, the respiration rate and pulse rate decreased according to sleeping of patients. Therefore, the sedation using the combination of chloral hydrate and hydroxyzine induced to appropriate sedation in incapable of cooperation or very young children with little effects of vital signs.

• Journal of computational fluids engineering
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• v.13 no.4
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• pp.50-57
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• 2008

The prediction of hydrate pellet decomposition characteristics is required to design the regasification process of GTS (gas to solid) technology, which is considered as an economic alternative for LNG technology to transport natural gas produced from small and stranded gas wells. Mathematical model based on the conservation principles, the phase equilibrium relation, equation of gas state and phase change kinetics was set up and numerical solution procedure employing volume averaged fixed grid formulation and extended enthalpy method are implemented. Initially, porous methane hydrate pellet is at uniform temperature and pressure within hydrate stable region. The pressure starts to decrease with a fixed rate down to the final pressure and is kept constant afterwards while the bounding surface of pellet is heated by convection. The predicted convective heat and mass transfer accompanied by the decomposed gas flow through hydrate/ice solid matrix is reported focused on the comparison of spherical and cylindrical pellets having the same effective radius.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.107-110
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• 2008

The price of natural gas import continues to rise, as well as its domestic consumption rate. This research examined the economic feasibility of domestically developing and producing gas hydrate to substitute imported natural gas. Today, the technology to commercially produce gas hydrate is still lacking; however, if the gas hydrate is able to be commercially produced domestically and replace imported natural gas, the annual economic benefit for the Republic of Korea would be 211 - 833 USD/ton. From the industry's point of view, gas hydrate is a high value investment since one can expect an annual profit of over 150USD/ton. The commercial value of gas hydrate development will increase as long as the natural gas market continues to expand and as the increase of natural gas consumption remains steady. With further development of technology, one can anticipate an even higher expected return on the investment.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.703-704
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• 2009

Natural gas Hydrate is an ice-like crystal containing natural gas it. Natural gas hydrate is studied as a new energy resource and a factor for seafloor slope stability and global warming. The unique pressure and temperature stability conditions of natural gas hydrate have challenged the research efforts. In this study, a new tool to study hydrate-bearing sediments and the preliminary results are introduced. The device can sustain 20MPa of the fluid pressure and apply 5MPa of the vertical effective stress under the temperature control. Cell can be scanned by X-ray CT scanner and also has the capability of multi-sensor data acquisition. Preliminary results suggests various application of the cell to hydrate-bearing research.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.531-533
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• 2007

We report and discuss molecular and isotopic properties of hydrate-bound gases from 55 samples and void gases from 494 samples collected during Ocean Drilling Program (ODP) Leg 204 at Hydrate Ridge offshore Oregon. Gas hydrates appear to crystallize in sediments from two end-member gas sources (deep allochthonous and in situ) as mixtures of different proportions. In an area of high gas flux at the Southern Summit of the ridge (Sites 1248-1250), shallow (0-40 meters below the seafloor (mbsf)) gas hydrates are composed of mainly allochthonous mixed microbial and thermogenic methane and a small portion of thermogenic C2+ gases, which migrated vertically and laterally from as deep as 2-2.5 km depths. In contrast, deep (50-105 mbsf) gas hydrates at the Southern Summit (Sites 1248 and 1250) and on the flanks of the ridge (Sites 1244-1247) crystallize mainly from microbial methane and ethane generated dominantly in situ. A small contribution of allochthonous gas may also be present at sites where geologic and tectonic settings favor vertical gas migration from greater depth (e.g., Site 1244).

• YAKHAK HOEJI
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• v.22 no.1
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• pp.8-14
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• 1978

The method that changes sodium cloxacillin from amorphous form to hydrate form was investigated. Using organic solvents of which dielectric constants are greater than 9, the amorphous sodium cloxacillin could be changed to hydrate form. The difference of water content of sodium cloxacillin hydrate caused the differences of ir spectrum at $3,350~3,360cm_{-1}$, and owing to the decrease of water content, hydrate form was changed to the morphous form, which could be identified by x-ray diffraction pattern. Regarding the stability of sodium cloxacillin in activity, the hydrate form was stable but the amorphous form was very unstable. Moreover, the stable hydrate form was scarcely hygroscopic, while the other form was hygroscopic, becoming a fused state ar $50^{\circ}$. and R.H. 50%.

• 한국전산유체공학회:학술대회논문집
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• 2008.03a
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• pp.268-275
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• 2008

The prediction of hydrate pellet decomposition characteristics is required to design the regasification process of GTS (gas to solid) technology, which is considered as an economic alternative for LNG technology to transport natural gas produced from small and stranded gas wells. Mathematical model based on the conservation principles, the phase equilibrium relation, equation of gas state and phase change kinetics was set up and numerical solution procedure employing volume averaged fixed grid formulation and extended enthalpy method are implemented. Initially, porous methane hydrate pellet is at uniform temperature and pressure within hydrate stable region. The pressure starts to decrease with a fixed rate down to the final pressure and is kept constant afterwards while the bounding surface of pellet is heated by convection. The predicted convective heat and mass transfer accompanied by the decomposed gas flow through hydrate/ice solid matrix is reported focused on the comparison of spherical and cylindrical pellets having the same effective radius.

• 한국전산유체공학회:학술대회논문집
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• 2008.10a
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• pp.268-275
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• 2008

The prediction of hydrate pellet decomposition characteristics is required to design the regasification process of GTS (gas to solid) technology, which is considered as an economic alternative for LNG technology to transport natural gas produced from small and stranded gas wells. Mathematical model based on the conservation principles, the phase equilibrium relation, equation of gas state and phase change kinetics was set up and numerical solution procedure employing volume averaged fixed grid formulation and extended enthalpy method are implemented. Initially, porous methane hydrate pellet is at uniform temperature and pressure within hydrate stable region. The pressure starts to decrease with a fixed rate down to the final pressure and is kept constant afterwards while the bounding surface of pellet is heated by convection. The predicted convective heat and mass transfer accompanied by the decomposed gas flow through hydrate/ice solid matrix is reported focused on the comparison of spherical and cylindrical pellets having the same effective radius.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.676-679
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• 2009

The bottom-simulating reflector (BSR) is the most commonly observed seismic indicator of gas hydrate in the Ulleung Basin, East Sea. We processed ten representative seismic reflection profiles, selected from a large data set, for amplitude variation with offset (AVO) analysis of the BSR to estimate gas-hydrate concentrations. First, BSRs were divided into five groups based on their seismic amplitudes and associated sediment types: (1) very high-amplitude BSRs in turbidite/hemipelagic sediments, (2) high-amplitude BSRs in debris-flow deposits, (3) moderate-amplitude BSRs in turbidite/hemipelagic sediments, (4) very low-amplitude BSRs in debris-flow deposits, and (5) very low-amplitude BSRs in seismic chimneys. The AVO responses of the group 1 and 3 BSRs are characterized by a rapid decrease and a relatively slow decrease in magnitude with offset, respectively. The AVO response of the group 2 BSR is characterized by a relatively slow increase in magnitude with offset. The AVO responses of the groups 4 and 5 BSRs are characterized by a flat AVO with very small zero-offset amplitude. Theoretical AVO curves, based on the three-phase Biot theory, suggest that the group 1 and 3 BSRs may be related to high (> 40%) concentrations of gas hydrate whereas the group 2 BSRs may indicate low (< 20%) concentrations of gas hydrate. The AVO responses of the group 4 and 5 BSRs cannot be compared with the theoretical models because of their very small zero-offset amplitudes. The comparison of the AVO response of the BSR at the UBGH-04 well with theoretical models suggests about 10% gas-hydrate concentration above the gas-hydrate stability zone.

• Korean Chemical Engineering Research
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• v.58 no.4
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• pp.635-641
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• 2020

In this study, phase equilibria and formation behaviors of methane hydrate containing mono-ethylene glycol (MEG) and salts (sodium chloride, NaCl; sodium bromide, NaBr; sodium iodide, NaI) are investigated. Equilibrium conditions of methane hydrate containing MEG and salts are measured in a temperature range 272~283 K and a pressure range 3.5~11 MPa. Hydrate inhibition performance in the presence of additives can be summarized as follows: methane hydrate containing (5 wt% NaCl + 10 wt% MEG) > (5 wt% NaBr + 10 wt% MEG) > (5 wt% NaI + 10 wt% MEG). Formation behaviors of methane hydrate with MEG and salts are investigated for analyzing the induction time, gas consumption amount and growth rate of methane hydrates. There are no significant changes in the induction time during methane hydrate formation, but the addition of MEG and salts solution during hydrate formation can affect the gas consumption amount and growth rate.