• 터널과지하공간
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• 제24권2호
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• pp.143-154
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• 2014

본 연구에서는 지오메카닉스모델을 이용한 가스하이드레이트 회수 생산 과정에서의 해리 발생 및 이에 따른 주변 퇴적층의 역학적 변형을 시뮬레이션 하였다. 지오메카닉스모델은 TOUGH+Hydrate와 FLAC3D 해석 코드를 순차적으로 반복해석하는 기법으로 감압법을 이용한 가스하이드레이트 회수 생산과정에서의 온도, 압력, 포화도 변화가 생산정 주변 퇴적층 내 유효응력, 강성 및 강도 변화에 미치는 영향을 고려할 수 있는 특징이 있다. 회수생산 방식에 따른 모델해석결과 비교를 통해, 감압법과 열자극법을 병행하는 경우 초기 생산량 증대를 가져올 수 있음을 보였다. 또한, 미고결 점토질 퇴적층에서의 회수생산 시 사암층에 비해 상대적으로 변형이 크게 발생함을 보였다.

• 대한소아치과학회지
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• 제25권4호
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• pp.811-824
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• 1998

The purpose of this study was to compare the clinical sedation effect of chloral hydrate and hydroxyzine combination, midazolam, triazolam when young children were sedated for dental treatment. The uncooperative 22 children aged, 25 to 52 months of age(ASA class I) and weighting between 11 and 17kg, participated in the study. Each patient was assigned randomly to receive chloral hydrate(50mg/kg) and hydroxyzine HCl(25mg), midazolam(0.5mg/kg), and triazolam(0.25mg) oral administration : alternative regimens were administered at next appointment. According to rating scale, sleep, crying, movement, and overall behavior response were checked for evaluation of the clinical sedation effect. Pulse rate and oxygen saturation were also measured for monitoring the patients during treatment period by pulse oximeter. The results were as follows: 1. In the evaluation of sedation effect, 90.9% in chloral hydrate and hydroxyzine combination and midazolam, and 77.3% in triazolam were rated "good" or "very good". 2. Sleep was demonstrated to be statistically significant increase in chloral hydrate and hydroxyzine combination group. Despite the fact that chloral hydrate and hydroxyzine group was in a deeper state of sleep, all the children were easily aroused. 3. There were no statistically significance among the three regimens with regard to cry ing, movement, overall behavior. 4. The adverse side effect was vomiting in one patient of chloral hydrate and hydroxyzine combination. There were no clinical sign of respiratory depression.

• 공업화학
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• 제19권6호
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• pp.680-684
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• 2008

Silica sand 내에서의 메탄 하이드레이트($CH_4$ hydrate)의 형성과 분해는 $7.0^{\circ}C$의 온도에서 실험되었다. Silica sand 내에서 형성되는 메탄 하이드레이트의 형성 및 분해 특성을 연구하기 위해 새로운 반응기를 제작하였다. Silica sand bed 내에서 메탄하이드레이트의 형성과 분해되는 동안의 온도변화에 대한 연구를 위해 반응기 내의 주입한 silica sand 높이에 따라 열전대의 위치를 다르게 설치하여 실험하였다. 반응기 내에 가해지는 압력과 온도는 메탄 하이드레이트의 형성과 분해를 발생시키는 요인이다. 메탄 하이드레이트 형성을 위한 가스 흡착곡선과 분해실험을 위한 가스 발생곡선은 실험데이터로부터 결정되었다. 8 MPa의 압력에서 $7.0^{\circ}C$의 온도에서 메탄 하이드레이트 형성 실험을 수행한 결과 70%의 메탄이 하이드레이트로 전환됨을 알 수 있었다. 형성된 메탄 하이드레이트의 분해에 의한 메탄의 회수율은 82%였다.

• Journal of Advanced Marine Engineering and Technology
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• 제38권5호
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• pp.589-601
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• 2014

Natural gas hydrate (NGH) is emerging as a new eco-friendly source of energy to replace fossil fuels in the 21st century. It is well known that the Natural Gas Hydrate contains large amount of natural gas about 170 times as much as its volume and it is easy to be stored and transported safely at about $-20^{\circ}C$ under atmospheric pressure due to so called "self-preservation effect". The option of gas transport by gas hydrate pellets carrier has been investigated and developed in various industry and academy. The natural gas hydrate pellet carrier is on major link in a potential gas hydrate process chain, starting with the extraction of natural gas from the reservoir, followed by the production of hydrate pellets and the transportation to an onshore terminal for further processing or marketing. In recent years, Korean project team supported by Korean Government has been working on the development of NGH total systems including novel NGH carrier since 2011. In order to increase the knowledge on the NGH pellet carrier developed and to understand the major hazards that could have significant impact on the safety of the vessel, this paper presents and evaluates the pros and cons of cargo holds, loading and unloading systems through the analysis of current patent technology. Based on the proven and well-known technologies as well as potential measures to mitigate sintering and minimize mechanical stress on the hydrate pellet in the self-preservation state, this study presents the conceptual and basic design for NGH carrier.

• 한국가스학회지
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• 제8권3호
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• pp.24-30
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• 2004

본 연구에서는 개선된 view cell 실험 장치를 통하여 가스 하이드레이트 생성 과정을 관찰하고 이의 동특성을 고찰하였다. 순수한 물과 촉진제로 음이온계 계면활성제를 미량 첨가한 물에 천연가스를 넣어 가스 하이드레이트를 생성 과정을 관찰하였다. 본 실험에서 사용한 276.65 K, 6 MPa 조건 상태에서는 충분한 지체 지연 시간이후 물에 순간 교반을 줌으로써 형성자 생성을 쉽게 유도할 수 있었다. 가스 하이드레이트 필름의 생성은 정적상태에서 가스와 접촉된 물의 표면에 생성되었다. 이는 육안으로 구분하기 어려운 매우 얇은 막이 수초 안에 물의 표면 전체를 덮는 선행과정과 이후 다시 육안관찰이 쉬운 필름층이 재생성되었다. 순수한 물에는 짧고 굵은 섬유 다발의 형태로 끝 부분이 둥글게 말려서 결정이 형성된 모습인 반면 촉진제를 넣은 경우 작은 섬유 다발 형태로 길게 생성되었고 다른 다발과 접촉되어 엉킨 결정 상상을 보였다.

• 한국세라믹학회지
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• 제47권5호
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• pp.401-406
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• 2010

For the lower-temperature preparation of calcium monoaluminate(CA, C:CaO, A:$Al_2O_3$) clinker which is hard to synthesize purely within its melting point, an equimolar hydrate was obtained and then used as a starting raw material of clinker burning. The hydrate was prepared from a mixture of waste oyster shell and industrial aluminium hydroxide by heating to $1200^{\circ}C$, grinding and mixing with water. The hydrate was composed of amorphous aluminium hydroxide and $C_3AH_6$(H:$H_2O$) formed by resolution-precipitation mechanism of the system C-A-H. By heating the hydrate, nearly pure and porous calcium monoaluminate clinker was formed at $1400^{\circ}C$ which is fairly lower temperature than that of its melting point. The formation of calcium monoaluminate was performed mainly by the reaction between amorphous alumina and $C_{12}A_7$ caused by the decomposition of $C_3AH_6$. The immediate and earlier formation of $C_{12}A_7$ seemed to be accelerated by not only high surface area and instability of the thermally decomposed hydrate but also the catalytic effect of water decomposed from the hydrate. The final calcium monoaluminate clinker was very porous because of the influence of highly porous shape of the thermally decomposed hydrate.

• 한국가스학회지
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• 제8권4호
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• pp.23-29
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• 2004

이 연구는 가스 하이드레이트 제조시 첨가제로 아세톤, 디메틸부탄, 폴리비닐알코올, 메탄올, 에틸렌글리콜등의 다양한 화학약품을 이용하여 하이드레이트 생성 특성을 변화시키는 것이다. 아세톤, 디메틸부탄, 폴리비닐 알코올을 첨가하여 하이드레이트를 제조한 경우 가스저장능력은 순수한 물로 하이드레이트를 제조한 경우보다 증가하였다. 이중 폴리비닐알코올은 다른 첨가제보다 더 많은 가스를 저장하므로 가장 유용한 생성 촉진제로 판단된다. 사용된 첨가제중 메탄올과 에틸렌글리콜은 생성 억제제의 특성을 나타내었고 에틸렌글리콜보다 메탄올이 조금 더 낮은 가스 저장능력을 나타내어 유용한 생성 억제제로 판단된다. 그러나 생성 억제제로서의 메탄올과 에틸렌글리콜이 낮은 농도인 경우 가스 저장능력이 순수한 물보다 증가하는 생성 촉진제의 특성을 보여준다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 추계학술대회 논문집
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• pp.186-187
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• 2008

Electrical resistivity in hydrate-bearing sediments is sensitive to porosity, gas hydrate saturation, gas content, pore fluid composition, and temperature, so electrical measurements such as well logs and electromagnetic surveys have been used to explore gas hydrate-bearing formation. The high pressure tomography cell is designed considering the effect of electrode configuration and electrical shielding on tomography measurements and the safety. The evolution of electrical conductivity during $CO_2$ hydrate formation and dissociation reflects the combined effects of concurrent changes that include ionization of dissolved $CO_2$, temperature-dependent ionic mobility, changes in the degree of saturation, ion exclusion, surface conduction, and porosity changes. Measurements during hydrate formation and dissociation require careful analysis to properly interpret signatures, in particular when out-of plane conductivity anomalies prevail.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 추계학술대회 논문집
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• pp.208-212
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• 2008

Gas hydrate has been paid attention to study for because: 1) it can be considered as a new energy resources; 2) one of reasons causing the instability of sea floor slope and 3) a factor to the climate change. Bottom simulating reflector (BSR) defined as seismic boundary between the gas hydrate and free gas zone has been considered as the most common evidence in the seismic reflection data for the gas hydrate exploration. BSR has several characteristics such as parallel to the sea bottom, high amplitude, reducing interval velocity between above and below BSR and reversing phase to the sea bottom. Moreover, instantaneous attribute properties such as amplitude envelop, instantaneous frequency, phase and first derivative of amplitude of seismic data from the complex analysis could be used to analyze properties of BSR those would be added to the certain properties of BSR in order to effectively find out the existence of BSR of the gas hydrate stability zone. The output of conventional seismic data processing for gas hydrate data set in Ulleung basin in the East sea of Korea will be used for complex analyses to indicate better BSR in the seismic reflection data. This result of this analysis implies that the BSR of the analyzed seismic profile is clearly located at the two ways time (TWT) of around 3.1 seconds.

• 설비공학논문집
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• 제14권10호
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• pp.863-870
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• 2002

Fossil fuels have been depleted gradually and new energy resource which can solve this shortage is needed now. Methane hydrate, non-polluting new energy resource, satisfies this requirement and considered the precious resource prevent the global warming. Fortunately, there are abundant resources of methane hydrate distribute in the earth widely, so developing the techniques that can use these gases effectively is fully valuable. the work presented here is to develop the skill which can transport and store methane hydrate. As a first step, the equilibrium point experiment has been carried out by increasing temperatures in the cell at fixed pressures. The influence of gas consumption rates under variable degree of subcooling, stirring and water injection has been investigated formation to find out kinetic characteristics of the hydrate. The results of present investigation show that the enhancements of the hydrate formation in terms of the gas/water ratio are closely related to operational pressure, temperature, degrees of subcooling, stirring rate, and water injection.