• Title/Summary/Keyword: Hybrid polymer

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Comparison of Micro Trench Machining Characteristics with Nonferrous Metal and Polymer using Single Diamond Cutting Tool (단결정 다이아몬드 공구에 의한 비철금속과 폴리머 소재의 마이크로 트렌치 가공특성 비교)

  • Choi, Hwan-Jin;Jeon, Eun-Chae;Choi, Doo-Sun;Je, Tae-Jin;Kang, Myung-Chang
    • Journal of Powder Materials
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    • v.20 no.5
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    • pp.355-358
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    • 2013
  • Micro trench structures are applied in gratings, security films, wave guides, and micro fluidics. These micro trench structures have commonly been fabricated by micro electro mechanical system (MEMS) process. However, if the micro trench structures are machined using a diamond tool on large area plate, the resulting process is the most effective manufacturing method for products with high quality surfaces and outstanding optical characteristics. A nonferrous metal has been used as a workpiece; recently, and hybrid materials, including polymer materials, have been applied to mold for display fields. Thus, the machining characteristics of polymer materials should be analyzed. In this study, machining characteristics were compared between nonferrous metals and polymer materials using single crystal diamond (SCD) tools; the use of such materials is increasing in machining applications. The experiment was conducted using a square type diamond tool and a shaper machine tool with cutting depths of 2, 4, 6 and 10 ${\mu}m$ and a cutting speed of 200 mm/s. The machined surfaces, chip, and cutting force were compared through the experiment.

Ultra High Molecular Weight Polyethylene Nanocomposite Films : Thermomechanical Property, Morphology, and Gas Permeability (초고분자량 폴리에틸렌 나노복합체 필름 : 열적-기계적 성질, 모폴로지 및 기체 투과도)

  • Jung, Min-Hye;Kim, Jeong-Cheol;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.31 no.5
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    • pp.428-435
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    • 2007
  • The thermomechanical property, morphology, and gas permeability of nanocomposites of ultra high molecular weight polyethylene (UHMWPE) with two different organoclays are compared. Hexamethylene benzimidazole-mica ($C_{16}BIMD-Mica$) and Cloisite 25A were used as reinforcing fillers in the formation of UHMWPE hybrid films. Dispersions of organoclays with UHMWPE were carried out by using the solution intercalation method at different organoclay contents to produce nano-scale composites. Transmission electron microscopy (TEM) micrographs show that some of the clay layers are dispersed homogeneously within the polymer matrix on the nano-scale, although some clay particles are agglomerated. We also found that the addition of only a small amount of organoclay is enough to improve the thermomechanical property and gas barrier of the UHMWPE hybrid films. In general, Cloisite 25A is more effective than $C_{16}BIMD-Mica$ in increasing both the thermomechanical property and the gas barrier in a UHMWPE matrix.

Bond Strength and Corrosion Resistance of Coated Reinforcing Bar Using Hybrid-Type Polymer Cement Slurry (Hybrid형 폴리머 시멘트 슬러리로 도장한 철근의 부착강도와 부식저항성)

  • Jo, Young-Kug
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.3
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    • pp.93-99
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    • 2008
  • The purpose of this study is to evaluate the bond strength and corrosion resistance of coated reinforcing bar using hybrid-type polymer cement slurry(PCS). PCS coated steels, which is made from two types of polymer dispersions such as St/BA and EVA are prepared, and tested for bond strength and various corrosion resistances such as autoclaved cure, carbonation and H2SO4 solution. From the test results, the bond strength of PCS coated reinforcing bar using ordinary portland cement at 1-5, 2-1 and 4-5 of mixes is higher than that of uncoated regular steel. However, bond strength of almost PCS coated reinforcing bars using ultra rapid high strength cement is higher than that of epoxy coated bar, is also in ranges of 102% to 123% compared to that of uncoated regular steel. In autoclaved accelerating test, the ratio of corrosion of uncoated regular steel is increased with the increase in NaCl content, but the corrosion of PCS coated steel was very small. In the acceleration test for carbonation, increasing the amount of NaCl the corrosion of coated steel did not produce. The corrosion of uncoated regular steel is increased with the increase in the amount of NaCl. It can be seen that the NaCl following the acceleration test for carbonation can lower the corrosion resistance of concrete. As a result, the corrosion of steel largely is affected by the acceleration curing, chloride ion penetration and carbonation and shown more severe corrosion by applying complex factors. These corrosions of steel can be suppressed by the coating of PCS.

Synthesis and Characterization of Hybrid Nanocomposites of Pd Nanoparticles Containing POSS(Pd-POSS) and Poly(acrylic acid) via Ionic Interactions (실세스키옥세인을 포함한 팔라듐 나노입자와 폴리아크릴산과의 이온결합에 의한 나노복합체 제조 및 특성평가)

  • Jeon, Jong-Hwan;Lim, Jung-Hyurk;Chujo, Yoshiki;Kim, Kyung-Min
    • Polymer(Korea)
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    • v.33 no.6
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    • pp.615-619
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    • 2009
  • Pd-POSS nanoparticles were produced from the reaction of palladium (II) acetate and octa(3-aminopropyl)octasilsesquioxane octahydrochloride (POSS-${NH_3}^+$) in methanol at room temperature. Pd-POSS nanoparticles with a mean diameter of 60-80 nm were the highly ordered spherical aggregates. In contrast, Pd nanoparticles with a size of 4.0 nm were obtained when POSS-${NH_3}^+$ was not introduced. Pd-POSS/PAA nanocomposites of Pd-POSS nanoparticles and poly(acrylic acid) (PAA) were fabricated by utilizing ionic interactions between positively charged Pd-POSS nanoparticles and negatively charged carboxylate groups of PAA. PAA was used as a cross-linker for the preparation of hybrid nanocomposites with the controlled organized structures of Pd-POSS nanoparticles. That is, the self-organization of Pd-POSS nanoparticles was formed into the shape of continuous lines by using PAA as a cross-linker. The composition, structure, surface morphology, and thermal stability of the Pd-POSS/PAA nanocomposites were studied by FE-SEM, AFM, TEM, FT-IR, and TGA.

Preparation of Core/Shell Nanoparticles Using Poly(3,4-ethylenedioxythiophene) and Multi-Walled Carbon Nanotube Nanocomposites via an Atom Transfer Radical Polymerization (Poly(3,4-ethylenedioxythiophene)을 이용한 Core/shell 나노입자와 원자이동 라디칼중합 공정에 의한 다중벽 탄소나노튜브 나노복합체 제조)

  • Joo, Young-Tae;Jin, Seon-Mi;Kim, Yang-Soo
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.452-457
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    • 2009
  • Hybrid nanomaterials consisting of multi-walled carbon nanotube(MWNT) and/or PEDOT of conductive polymer were prepared in this study. In the presence of catalyst and ligand, the MWNT-Br compound prepared by the successive surface treatment reaction was mixed with MMA to initiate the atom transfer radical polymerization process. PMMA was covalently linked to the surface of MWNT for the formation of MWNT/PMMA nanocomposites. The EDOT and oxidant were added in the aqueous emulsion of PS produced via a miniemulsion polymerization process and then it proceeded to carry out the oxidative chemical polymerization of EDOT for the preparation of PEDOT/PS nanoparticles with the core-shell structure. The aqueous dispersion of PEDOT:poly(styrene sulfonate) (PSS) was mixed with the silica particles treated with a silane compound and thus PEDOT:PSS-clad silica nanoparticles were prepared by the surface chemistry reaction. The hybrid nanomaterials were analyzed by using TEM, FE-SEM, TGA, EDX, UV, and FT-IR.