• Title/Summary/Keyword: Hybrid Materials

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Fabrication of Organic-Inorganic Hybrid Thin Film by Molecular Layer Deposition

  • Han, Gyu-Seok;Kim, Su-Hwan;Han, Gi-Bok;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.251-251
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    • 2010
  • Organic-inorganic hybrid materials have attracted because of its combined properties, such as flexibility and high electrical performance. In addition, the hybrid materials are expected to have synergic effect which are not shown in just one component. Here, we fabricated organic-inorganic hybrid thin film. Organic-inorganic hybrid thin film have been deposited from diethyl zinc and 1, 2, 4-trihydroxybenzene (THB) by molecular layer deposition (MLD). UV-VIS, Using Infrared spectrum and X-ray photoelectron spectroscopy confirm that Zinc and THB hybrid film (ZnTHB) consist of Zn-O and THB - oxide units and the micro structure and composition of hybrid film. hat the sequential surface reactions of diethyl zinc and ethylene glycol are sufficiently self-limiting and saturating to enable well-controlled MLD growth. Transmission electron microscopy image shows lamination growth of ZnTHB film according to cycle.

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Tensile Properties of Carbon-Glass/Epoxy Hybrid Laminates Produced by VARTM (VARTM 법으로 제작한 탄소-유리/에폭시 하이브리드 적층재의 인장 특성)

  • Kim, Yonjig
    • Korean Journal of Metals and Materials
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    • v.49 no.10
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    • pp.760-765
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    • 2011
  • This paper presents a study of the tensile behavior of carbon and glass fiber reinforced epoxy hybrid laminates manufactured by vacuum assisted resin transfer molding (VARTM). The objective of this study was to develop and characterize carbon fiber reinforced plastic hybrid composite material that is low cost and light-weight and that possesses adequate strength and stiffness. The effect of position and content of the glass fabric layer on the tensile properties of the hybrid laminates was examined. The strength and stiffness of the hybrid laminates showed a steady decrease with an increase of the glass fabric content this decrease was almost linear. Fracture strain of these laminates showed a slight increasing trend when glass fabric content was increased up to 3 layers, but at a glass fabric content > 3 layers the strain was almost constant. When glass fabric layers were at both outer surfaces, the hybrid laminate exhibited a slightly higher tensile strength and elastic modulus due to the small amount of glass yarn pull-out.

A review on the recovery of the lithium carbonate powders from lithium-containing substances (리튬 함유 물질로부터 탄산리튬 회수에 대한 고찰)

  • Kim, Dae-Weon;Park, Jae Ryang;Ahn, Nak-Kyoon;Choi, Gwang-Mook;Jin, Yun-Ho;Yang, Jae-Kyo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.3
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    • pp.91-106
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    • 2019
  • The demand for lithium has increased sharply due to the explosive increase in lithium secondary batteries for environment-friendly vehicles (EV: Electric Vehicle, HEV: Hybrid Electric Vehicle, PHEV: Plug-in Hybrid Electric Vehicle). Traditionally, lithium has been produced mainly from lithium-containing minerals and brine, and recently it also has been recovered along with other valuable metals by recycling cathode materials of lithium secondary batteries. In this study, we comprehensively reviewed various recovering precesses of lithium from lithium-containing substances.

Study on the Thermal Performance of a Solar Assisted Heat Pump System with a Hybrid Collector (태양열/공기열 복합 집열기를 가지는 하이브리드 히트펌프 시스템의 열성능에 관한 연구)

  • DO, KYU HYUNG;CHOI, BYUNG-IL;HAN, YONG-SHIK;KIM, MYUNGBAE;KIM, TAEHOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.2
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    • pp.182-191
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    • 2016
  • In the present work, a solar assisted heat pump (SAHP) system with a hybrid collector was analyzed. For this, a simplified thermodynamic model was developed. Based on the proposed model, the heat transfer rate, COP, and the annual operating hour of the SAHP system were estimated. The effect of the variation of system design parameters on the performance of the system was also examined. From the results, the performance was improved with increasing the effectiveness of heat exchangers and decreasing the difference between the evaporation temperature and the outlet brine temperature of the hybrid collector loop. Finally, the performance of SAHP system with a hybrid collector was compared with that of conventional serial and parallel SAHP systems. The SAHP system with a hybrid collector was substantially better than a series system and slightly worse than a parallel system for both the yearly averaged heat transfer rate and COP. However, the annual operating hour of the SAHP system with a hybrid collector was much better than that of a parallel system.

Fabrication of a Hybrid Superhydrophobic/superhydrophilic Surface for Water Collection: Gravure Offset Printing & Colloidal Lithography (수분수집을 위한 초발수/초친수 복합 표면 제작: 그라비아 옵셋 프린팅과 콜로이달 리소그래피 공정)

  • Ji, Seung-Muk;Kim, In-Young;Kim, Eun-Hee;Jung, Jie-Un;Kim, Wan-Doo;Lim, Hyun-Eui
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.1
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    • pp.19-24
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    • 2012
  • We demonstrate the desert beetle back mimicking hybrid superhydrophilic/superhydrophobic patterned surface by using the combination method of colloidal lithography and gravure offset printing for nano and micro patterning, respectively. The two methods are cost-effective and industrially available techniques compared to the other nano/micro patterning methods. To verify the water collecting function of the hybrid surface, the water condensation behavior is investigated on the chilled surface in ambient temperature and high humidity. Due to the synergetic effect of drop and film wise condensation, the hybrid superhydrophobic/superhydrophilic surface shows the higher efficiency than one of single wettability surfaces. The work is underway to get the good patterns of hybrid surfaces for water collecting from the dew or fog.

Electrical and Optical Properties of Transparent Conducting Films having GZO/Metal/GZO Hybrid-structure; Effects of Metal Layer(Ag, Cu, Al, Zn) (GZO/Metal/GZO 하이브리드 구조 투명 전도막의 전기적, 광학적 특성; Ag, Cu, Al, Zn 금속 삽입층의 효과)

  • Kim, Hyeon-Beom;Kim, Dong-Ho;Lee, Gun-Hwan;Kim, Kang-Ho
    • Journal of the Korean institute of surface engineering
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    • v.43 no.3
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    • pp.148-153
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    • 2010
  • Transparent conducting films having a hybrid structure of GZO/Metal/GZO were prepared on glass substrates by sequential deposition using DC magnetron sputtering. Silver, copper, aluminum and zinc thin films were used as the intermediate metal layers in the hybrid structure. The electrical and optical properties of hybrid transparent conducting films were investigated with varying the thickness of metal layer or GZO layers. With increasing the metal thickness, hybrid films showed a noticeable improvement of the electrical conductivity, which is mainly dependent on the electrical property of the metal layer. GZO(40 nm)/Ag(10 nm)/GZO(40 nm) film exhibits a resistivity of $5.2{\times}10^{-5}{\Omega}{\cdot}cm$ with an optical transmittance of 82.8%. For the films with Zn interlayer, only marginal reduction in the resistivity was observed. Furthermore, unlike other metals, hybrid films with Zn interlayer showed a decrease in the resistivity with increasing the GZO thickness. The optimal thickness of GZO layer for anti-reflection effect at a given thickness of metal (10 nm) was found to be critically dependent on the refractive index of the metal. In addition, x-ray diffraction analysis showed that the insertion of Ag layer resulted in the improvement of crystallinity of GZO films, which is beneficial for the electrical and optical properties of hybrid-type transparent conducting films.

Ontogenetic Behavior and Phototactic Properties of Interspecific Hybrid Prolarvae Produced by Crossing Female Siberian Sturgeon Acipenser baerii and Male Russian Sturgeon Acipenser gueldenstaedtii (시베리아 철갑상어(Acipenser baerii) 암컷과 러시아 철갑상어(Acipenser gueldenstaedtii) 수컷간 유도된 잡종 자어의 행동 발달 및 주광성 특징)

  • Nam, Yoon Kwon;Kim, Eun Jeong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.52 no.3
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    • pp.274-282
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    • 2019
  • Female Siberian sturgeon Acipenser baerii were crossed with male Russian sturgeon A. gueldenstaedtii and the development, ontogenetic behavior, and phototactic characteristics of the resultant hybrid prolarvae were examined. The fertilization rate of the hybrid group was similar to that of Siberian sturgeon (the maternal species), and the overall developmental characteristics of hybrid embryos were not significantly different from those of either parental species. The time window from first hatch to the completion of hatching was wider in Russian sturgeon than in Siberian and hybrid sturgeon groups. The prolarval viability of the hybrid group was similar to that of the maternal species, and significantly higher than that of the paternal species. Hybrid prolarvae displayed ontogenetic behavioral patterns that were quite similar to those of Siberian sturgeon. In an illumination preference test, hybrid prolarvae displayed significant positive phototaxis, similar to the maternal species, and clearly distinct from the negative phototactic character of the paternal species. Taken together, our data indicate that the prolarval traits of hybrid sturgeon from this cross more closely resemble those of the maternal than the paternal species.

Self-healing Engineering Materials: I. Organic Materials (자기치유 공학재료: I. 유기 재료)

  • Choi, Eun-Ji;Wang, Jing;Yoon, Ji-Hwan;Shim, Sang-Eun;Yun, Ju-Ho;Kim, Il
    • Clean Technology
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    • v.17 no.1
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    • pp.1-12
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    • 2011
  • Scientists and engineers have altered the properties of materials such as metals, alloys, polymers, ceramics, and so on, to suit the ever changing needs of our society. Man-made engineering materials generally demonstrate excellent mechanical properties, which often tar exceed those of natural materials. However, all such engineering materials lack the ability of self-healing, i.e. the ability to remove or neutralize microcracks without intentional human interaction. The damage management paradigm observed in nature can be reproduced successfully in man-made engineering materials, provided the intrinsic character of the various types of engineering materials is taken into account. Various self-healing ptotocols that can be applied for the organic materials such as polymers, ionomers and composites can be developed by utilizing suitable chemical reactions and physical intermolecular interactions.

High performance Organic-Inorganic Hybrid Materials for Application in OLED Barrier Coating

  • Jung, Kyung-Ho;Yun, Chang-Hun;Bae, Jun-Young;Yoo, Seung-Hyup;Bae, Byeong-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.806-809
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    • 2009
  • Epoxy functionalized organic-inorganic hybrid materials (hybrimers) were synthesized by sol-gel reaction for application in OLED barrier coating. By using the calcium degradation method, the oxygen transition rate (OTR) and water vapor transition rate (WVTR) measured so far is $10^{-2}cc/m^2$-day for oxygen and $10^{-1}g/m^2$-day for water molecules with single hybrimer coating film, respectively. Encapsulated OLED devices have life time of 14hrs of a single hybrimer barrier coating and 29hrs of hybrimer/inorganic double barrier coatings at $25^{\circ}C$ and 60% relative humidity.

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