• Title/Summary/Keyword: Hybrid Materials

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Photochromic and thermal properties of poly (Vinyl alcohol)/ $H_6P_2W_{18}O_{62}$ hybrid membranes (폴리비닐알코올 $H_6P_2W_{18}O_{62}$ hybrid membranes의 광색 및 열적 특성)

  • Jian Gong;Kim, Hak-Yong;Lee, Duck-Rae;Bin Ding;Xiangdan Li
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.459-461
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    • 2002
  • A new class of materials based on organic and inorganic species combined at a molecule level has obtained more attention recently[1]. HPA(heteropolyacid) shows unmatched applied perspective in terms of synthesis chemistry, analysis chemistry, biology, medicine and materials science[2]. As a potential photochemical material, the hybrid system of HPA and polymer has been investigated. However, the design and synthesis of heteropolyacid-based hybrids, which are at the forefront of the materials chemistry research, is still in its infancy. (omitted)

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Prediction of Spring-back for GFR/CFR Unsymmetric Hybrid Composites (유리섬유/탄소섬유 강화 비대칭 하이브리드 복합재의 스프링 백 예측)

  • Jung, Woo-Kyun;Ahn, Sung-Hoon;Won, Myung-Shik
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.158-161
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    • 2005
  • The fiber-reinforced composite materials have been advanced for various applications because of its excellent mechanical and electromagnetic properties. On their manufacturing processes, however, thermo-curing inherently produces the undesired thermal deformation mainly from temperature drop from the process temperature to the room temperature, so called spring-back. The spring-back must be removed to keep the precision of designed shape. In this research, the spring-back of {glass fiber / epoxy}+{carbon fiber / epoxy} unsymmetric hybrid composites were predicted using Classical Lamination Theory (CLT), and compared with the experimental data. Additionally, using finite element analysis (ANSYS), the predicted data and experimental data were compared. The predicted values by CLT and ANSYS were well matched with experimental data.

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Manufacturing and Mechanical Properties of Sisal Fiber Reinforced Hybrid Composites

  • Hui, Zhi-Peng;Sudhakara, P.;Wang, Yi-Qi;Kim, Byung-Sun;Song, Jung-Il
    • Composites Research
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    • v.26 no.5
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    • pp.273-278
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    • 2013
  • PLA/PP polymer blends in various ratios (PLA:PP = 9:1, 4:1, 3:1, and 1:1), and their composites (PLA:PP = 1:1) with sisal fiber (10, 15 and 20 wt%) were fabricated using MAPP as compatibilizer. The aim of the work was to reduce the cost of biodegradable composites as well as to improve the impact strength of PLA using PP, a relatively cheaper thermoplastic. The developed composites were characterized for their morphological and mechanical properties. The tensile strength and modulus of the blends were decreased with increasing PP content whereas the strain at break and impact strength are increased. The tensile strength, modulus and water absorption were increased for hybrid composites with increasing fiber content.

High temperature and damping properties of squeeze cast Mg hybrid Metal Matrix Composites. (하이브리드 Mg 복합재료의 진동 감쇠능 및 고온 특성평가)

  • 장재호;김봉룡;최일동;조경목;박익민
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.143-146
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    • 2002
  • Mg alloy is the lightest material of structural materials and is noticed for lightweight automotive parts because of excellent castability, superior ductility and damping capacity than Al alloy. But Mg Alloy is poor corrosion resistance and high temperature creep properties. In this study, Mg Matrix Composites were fabricated by squeeze casting method to improve high temperature creep properties and damping capacity. Hybrid Mg composites reinforced with Alborex, graphite particle, and SiCp was improved creep properties and damping capacity compared with Mg alloy. Compared to the length ($9\mu\textrm{m}, 27\mu\textrm{m}, 45\mu\textrm{m} etc.$), Hybrid Mg composites reinforced with SiCp, one of the most superior of the length and Alborex were more superior than those reinforced with graphite particle and Alborex in mechanical properties, creep characteristics, and damping capacity, etc.

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Prediction of Drawbead Restraining Force by Hybrid Membrane/Bending Method (하이브리드 박막/굽힘 방법을 이용한 드로비드력의 예측)

  • Lee, M.G.;Chung, K.;Wagoner, R.H.;Keum, Y.T.
    • Transactions of Materials Processing
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    • v.15 no.8 s.89
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    • pp.533-538
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    • 2006
  • A simplified numerical procedure to predict drawbead restraining forces(DBRF) has been developed based on the hybrid membrane/bending method which superposes bending effects onto membrane solutions. As a semi-analytical method, the new approach is especially useful to analyze the effects of various constitutive parameters. The present model can accommodate general anisotropic yield functions along with non-linear isotropic-kinematic hardening under the plane strain condition. For the preliminary results, several sensitivity analyses for the process and material effects such as friction, drawbead depth, hardening behavior including the Bauschinger effect and yield surface shapes on the DBRF are carried out.

The Determination of Elastic Constant for Ceramic Forming Material by Hybrid Method (하이브리드 방법에 의한 세라믹 성형재료의 탄성계수 결정)

  • Park Myong Kyun;Koo Bon Sung
    • Journal of the Korea Safety Management & Science
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    • v.7 no.1
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    • pp.211-222
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    • 2005
  • The ceramic forming materials are getting more important recently since they are used widely in repairing metal structures, welded metal structures and mechanical components etc. The determination of elastic constants for ceramic coating materials takes much time and efforts in experiment due to the brittleness of ceramic material itself. The aim of this research is to determine the Young's Modulus for ceramic metal coating material. In order to achieve the goal, the hybrid method which uses impulse hammer technique for experimental method and modal analysis of finite element method for computational method was used. The results show good agreement with existing experimental data on Young's Modulus.

Organic / inorganic composite membrane for Polymer Electrolyte Membrane Fuel Cell (고분자전해질 연료전지용 유기/무기 복합 전해질)

  • Choi Seong Ho;Hong Hyeon Sil;Lee Heung Chan;Kim Yu Mi;Kim Geon
    • 한국전기화학회:학술대회논문집
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    • 2003.07a
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    • pp.169-171
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    • 2003
  • Organic/inorganic hybrid membranes have been prepared and evaluated as polymer electrolytes in a polymer electrolyte membrane fuel cell (PEMFC). Previously, partially fluorinated poly (arylenether) was synthesized and the polymer was sulfonated by fuming sulfuric acid$(30\%\;SO_3)$. Modification of these polymers with coupling agent and inorganic materials was carried out to prepare membranes. Membranes cast from these materials were investigated in relation to the proton conductivity and weight loss at the room temperature. It was found that these membranes had a higher conductivity of $10^{-2}\;Scm^{-1}$ at the room temperature. But inorganic materials have leaked out from the hybrid membrane. If this problem is resolved, organic/inorganic hybrid membranes will become satisfactory Polymer electrolytes for the PEMFC.

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Hybrid Microstructure and Mechanical Properties of HRS Processed SUS316L and Titanium Materials

  • Fujiwara, Hiroshi;Ohta, Koichi;Noro, Atsushi;Ameyama, Kei
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.540-541
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    • 2006
  • SUS316L stainless steel, commercial pure Titanium and Ti-6Al-4V alloy powders applied by Mechanical Milling (MM) process are sintered by Hot Roll Sintering (HRS) process. Microstructure and mechanical properties of those HRS materials is investigated. The microstructures of materials produced by HRS process consist of fine grains and work-hardened structure, that is, the hybrid microstructure. Tensile test of the HRS material demonstrated the good mechanical properties. These results show that the HRS process is very effective to the improvement of mechanical properties in the SUS316L stainless steel, commercial pure Titanium and Ti-6Al-4V alloy.

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An inverse determination method for strain rate and temperature dependent constitutive model of elastoplastic materials

  • Li, Xin;Zhang, Chao;Wu, Zhangming
    • Structural Engineering and Mechanics
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    • v.80 no.5
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    • pp.539-551
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    • 2021
  • With the continuous increase of computational capacity, more and more complex nonlinear elastoplastic constitutive models were developed to study the mechanical behavior of elastoplastic materials. These constitutive models generally contain a large amount of physical and phenomenological parameters, which often require a large amount of computational costs to determine. In this paper, an inverse parameter determination method is proposed to identify the constitutive parameters of elastoplastic materials, with the consideration of both strain rate effect and temperature effect. To carry out an efficient design, a hybrid optimization algorithm that combines the genetic algorithm and the Nelder-Mead simplex algorithm is proposed and developed. The proposed inverse method was employed to determine the parameters for an elasto-viscoplastic constitutive model and Johnson-cook model, which demonstrates the capability of this method in considering strain rate and temperature effect, simultaneously. This hybrid optimization algorithm shows a better accuracy and efficiency than using a single algorithm. Finally, the predictability analysis using partial experimental data is completed to further demonstrate the feasibility of the proposed method.

Highly active and trans-1,4-specific polymerization of 1,3-butadiene catalyzed by bis(benzimidazolyl)amine chromium complexes activated with methylaluminoxane (메틸알루미녹산으로 활성화시킨 고활성 bis(benzimidazolyl)amine 크롬 착물을 이용한 부타디엔 중합에 의한 트랜스 폴리부타디엔 제조)

  • Moon, Byeong Kyu;Song, Ga Young;Zhang, Lin;Shin, Jin Young;Chang, Hyuk Chul;Shim, Sang Eun;Yun, Ju Ho;Kim, Il
    • Elastomers and Composites
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    • v.48 no.1
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    • pp.61-66
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    • 2013
  • A family of Cr(III) complexes supported on tridentate dibenzimidazolyl ligands having a general formula: $[N(CH_3)(CH_2)_2(Bm-R)_2]CrCl_3$ [where Bm = benzimidazolyl, R = H (3a); -Me(3b); -Bn (3c)] have been synthesized and utilized them for the trans-1,4-specific polymerizations of 1,3-butadiene (BD), activated with methylalumoxane (MAO). The activity of BD polymerizations was sensitive to the type of ligand on the Cr metal, so that the activity decreases in the order of 3a > 3c > 3b. All the catalysts combined with MAO yielded polybutadienes with perfect trans-1,4 structure with moderate molecular weight.