• 제목/요약/키워드: Hot Wall Method

검색결과 228건 처리시간 0.026초

태양전지용 $CuGaSe_2$ 단결정 박막 성장과 열처리 효과 (The Effect of Thermal Annealing and Growth of $CuGaSe_2$ Single Crystal Thin Film for Solar Cell Application)

  • 홍광준;유상하
    • 한국태양에너지학회 논문집
    • /
    • 제23권2호
    • /
    • pp.59-70
    • /
    • 2003
  • A stoichiometric mixture of evaporating materials for $CuGaSe_2$ single crystal thin films was prepared from horizontal electric furnace. Using extrapolation method of X-ray diffraction patterns for the polycrystal $CuGaSe_2$, it was found tetragonal structure whose lattice constant $a_0$ and $c_0$ were $5.615{\AA}$ and $11.025{\AA}$, respectively. To obtain the single crystal thin films, $CuGaSe_2$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the hot wall epitaxy (HWE) system. The source and substrate temperatures were $610^{\circ}C$ and $450^{\circ}C$, respectively. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of $CuGaSe_2$ single crystal thin films measured with Hall effect by van der Pauw method are $5.01\times10^{17}cm^{-3}$ and $245cm^2/V{\cdot}s$ at 293K. respectively. The temperature dependence of the energy band gap of the $CuGaSe_2$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g$(T)=1.7998 eV-($8.7489\times10^{-4}$ eV/K)$T^2$/(T+335K). After the as-grown $CuGaSe_2$ single crystal thin films was annealed in Cu-, Se-, and Ga-atmospheres, the origin of point defects of $CuGaSe_2$ single crystal thin films has been investigated by the photoluminescence(PL) at 10 K. The native defects of $V_{CU},\;V_{Se},\;Cu_{int}$ and $Se_{int}$ obtained by PL measurements were classified as a donors or acceptors type. And we concluded that the heat-treatment in the Cu-atmosphere converted $CuGaSe_2$ single crystal thin films to an optical n-type. Also, we confirmed that Ga in $CuGaSe_2$/GaAs did not form the native defects because Ga in $CuGaSe_2$ single crystal thin films existed in the form of stable bonds.

저압 화학기상증착법을 이용한 β-SiC의 증착 및 결정 성장 방위에 따른 기계적 특성 변화 (Deposition of β-SiC by a LPCVD Method and the Effect of the Crystallographic Orientation on Mechanical Properties)

  • 김대종;이종민;김원주;윤순길;박지연
    • 한국세라믹학회지
    • /
    • 제50권1호
    • /
    • pp.43-49
    • /
    • 2013
  • ${\beta}$-SiC was deposited onto a graphite substrate by a LPCVD method and the effect of the crystallographic orientation on mechanical properties of the deposited SiC was investigated. The deposition was performed at $1300^{\circ}C$ in a cylindrical hot-wall LPCVD system by varying the deposition pressure and total flow rate. The texture and crystallographic orientation of the SiC were evaluated by XRD. The deposition rate increased linearly with the gas flow rate from 800 sccm to 1600 sccm. It also increased with the pressure but became saturated above a total pressure of 3.3 kPa. In the range of 3.3 - 10 kPa, the preferred orientation changed from the (220) and (311) planes to the (111) plane. The hardness and elastic modulus showed maximum values when the SiC had the (111) preferred orientation, though it gradually decreased upon a change to the (220) and (311) preferred orientations.

수평격판을 갖는 정사각형 밀폐공간내에서 자연대류 유동 및 열전달 (Natural Convective Flow and Heat Transfer in a Square Enclosure with a Horizontal Partition)

  • 정인기;김점수;송동주
    • 대한기계학회논문집
    • /
    • 제17권9호
    • /
    • pp.2304-2314
    • /
    • 1993
  • Natural convective flow and heat transfer in a two-dimensional square enclosure fitted with a horizontal partition are investigated numerically. The enclosure was composed of the lower hot and the upper cold horizontal walls and the adiabatic vertical walls, and a partition was situated perpendicularly at the one vertical insulated wall. The governing equations are solved by using the finite element method with Galerkin method. The computations were carried out with the variations of length, position and thermal conductivity of the partition, and Rayleigh number based on the temperature difference between two horizontal walls and the enclosure height with water(Pr=4.95). As the results, an oscillatory motion of natural convection is resulted in a sudden rise of overall heat transfer, but the increase of length of partition is significantly restrained the increase of Nusselt number. The maximum heat transfer was shown just before the transition of the direction of oscillating flow. An oscillatory motion of flow was perfectly shown the stability with the decrease of the length of partition and Rayleigh number. Also, the heat transfer was raised with the increase of the thermal conductivity in proportion to the increase of the length of partition. The stability and oscillation of flow are affected by the position of partition.

애리조나 주의 F. L. Wright 주택작품 디자인 특성 분석 (A Study on the Analysis of Design Characteristic of Works of Frank Lloyd Wright in Arizona State)

  • 황용운
    • 한국실내디자인학회논문집
    • /
    • 제27권3호
    • /
    • pp.90-99
    • /
    • 2018
  • The purpose of this study is to study how F.L. Wright reflected the climatic properties and materials of the region into creative ways of designing his architecture. The research method examined the design methods and use of materials by Wright in existing research literature and compares the space plans of housing works in Arizona. The research results will be summarized as follows : 1) For two-story houses, pilotis was used to avoid the hot air and the walls on the ground floor were often planned as thick wall. 2) In the fifties, F.L. Wright's design method changed in a circle from the vertical and horizontal lines. 3) F.L.Wright's Architectural form concepts and design concepts were extracted from local symbolic forms and natural forms. 4) F.L.Wright avoided Arizona's direct light but Indirect sunlight enters into the interior space. 5)External space was expressed as a closed space, while internal space was expressed as an open space. It's like an organic space. 6) Most of the housing materials used are stone and cement from rough deserts, and wood with low heat conductivity and thick concrete blocks to prevent the sunlight from rising above.

정사각형 밀폐공간내에서 수평격판에 의한 자연대류의 진동현상 (Oscillatory Motion of Natural Convection in a Square Enclosure with a Horizontal Partition)

  • 김점수;정인기;송동주
    • 설비공학논문집
    • /
    • 제5권4호
    • /
    • pp.285-294
    • /
    • 1993
  • An oscillatory motion of natural convection in a two-dimensional square enclosure fitted with a horizontal partition is investigated numerically. The enclosure was composed of the lower hot and the upper cold horizontal walls and the adiabatic vertical walls, and a partition was positioned perpendicularly at the mid-height of one vertical insulated wall. The governing equations are solved by using the finite element method with Galerkin method. The computations were carried out with the variations of the partition length and Rayleigh number based on the temperature difference between two horizontal walls and the enclosure height with water(Pr=4.95). As the results, an oscillatory motion of natural convection has perfectly shown the periodicity with the decrease of Rayleigh number, and the stability was reduced to a chaotic state with the increase of Rayleigh number. The period of oscillation gets shorten with the decrease of the partition length and the increase of Rayleigh number. The frequency of oscillation obtained by the variations of stream function is more similar to the experimental results than that of the average Nusselt number. The stability of oscillation grows worse with the increase of Rayleigh number. The transition Rayleigh number for the chaos is gradually decreased with the increase of the partition length.

  • PDF

초음파 분무법으로 제조한 ZnO:Al 박막의 전기 및 광학적 특성 (The electrical and optical properties of ZnO:Al films Prepared by ultrasonic spray Pyrolysis)

  • Lee, Soo-Chul;Moon, Hyun-Yeol;Lee, In-Chan;Ma, Tae-Young
    • 대한전자공학회:학술대회논문집
    • /
    • 대한전자공학회 1999년도 하계종합학술대회 논문집
    • /
    • pp.283-286
    • /
    • 1999
  • Transparent conductive aluminum-doped ZnO(AZO) films Were prepared by a ultrasonic spray pyrolysis method at the substrate temperature below 23$0^{\circ}C$. A vertical type hot wall furnace was used as a reactor in the deposition system. Zinc acetate dissolved in methanol was selected as a precursor. The substrate temperature was varied from 18$0^{\circ}C$to 24$0^{\circ}C$. Aluminum (Al) was doped into ZnO films by incorporating anhydrous aluminum chloride (AlCl$_3$) in the zinc acetate solution. The proportion of the Al in the starting solution was varied from 0 wt % to 3.0 wt %. The crystallographic properties and surface morphologies of the films were analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The resistivity of the films was measured by the Van der Pauw method, and the mobility and carrier concentration were obtained through the Hall effect measurements Transmittance was measured in the visible region. The effects of substrate temperature and aluminum content in the starling solution on the structural and electrical properties of the AZO films are discussed

  • PDF

혼합배관 내의 열 경계층 이동으로 인한 고주기 온도요동에 관한 연구 (A Study on High Cycle Temperature Fluctuation Caused by Thermal Striping in a Mixing Tee Pipe)

  • 김석범;박종호
    • 한국유체기계학회 논문집
    • /
    • 제10권5호
    • /
    • pp.9-19
    • /
    • 2007
  • Fluid temperature fluctuations in a mixing tee pipe were numerically analyzed by LES model in order to clarify internal turbulent flows and to develope an evaluation method for high-cycle thermal fatigue. Hot and cold water with an temperature difference $40^{\circ}C$ were supplied to the mixing tee. Fluid temperature fluctuations in a mixing tee pipe is analysed by using the computational fluid dynamics code, FLUENT, Temperature fluctuations of the fluid and pipe wall measured as the velocity ratio of the flow in the branch pipe to that in the main pipe was varied from 0.05 to 5.0. The power spectrum method was used to evaluate the heat transfer coefficient. The fluid temperature characteristics were dependent on the velocity ratio, rather than the absolute value of the flow velocity. Large fluid temperature fluctuations were occurred near the mixing tee, and the fluctuation temperature frequency was random. The ratios of the measured heat transfer coefficient to that evaluated by Dittus-Boelter's empirical equation were independent of the velocity ratio, The multiplier ratios were about from 4 to 6.

Water-Side Oxide Layer Thickness Measurement of the Irradiated PWR Fuel Rod by NDT Method

  • Park, Kwang-June;Park, Yoon-Kyu;Kim, Eun-Ka
    • 한국원자력학회:학술대회논문집
    • /
    • 한국원자력학회 1995년도 추계학술발표회논문집(2)
    • /
    • pp.680-686
    • /
    • 1995
  • It has been known that water-side corrosion of fuel rods in nuclear reactor is accompanied with the loss of metallic wall thickness and pickup of hydrogen. This corrosion is one of the important limiting factors ill the operating life of fuel rods. In connection with the fuel cladding corrosion, a device to measure the water-side oxide layer thickness by means of the eddy-current method without destructing the fuel rod was developed by KAERI. The device was installed on the multi-function testing bench in the nondestructive test hot-cell and its calibration was carried out successfully for the standard rod attached with plastic thin films whose thicknesses are predetermined. It shows good precision within about 10% error. And a PWR fuel rod, one of the J-44 assembly discharged from Kori nuclear power plant Unit-2, has been selected for oxide layer thickness measurements. With the result of data analysis, it appeared that the oxide layer thicknesses of Zircaloy cladding vary with the length of the fuel rod, and their thicknesses were compared with those of the destructive test results to confirm the real thicknesses.

  • PDF

원판(圓板)의 열판건조(熱板乾燥)에서 컴퓨터 시뮬레이션에 의한 내부온도(內部溫度)와 함수율(含水率) 분포모형(分布模型) (Distribution Model Based on Computer Simulation for Internal Temperature and Moisture Content in Press Drying of Tree Disks)

  • 여환명;정희석
    • Journal of the Korean Wood Science and Technology
    • /
    • 제22권2호
    • /
    • pp.61-70
    • /
    • 1994
  • This study was executed to find the applicability of press drying of tree disk by investigating the shrinkage and drying defect and to form appropriate model by comparing the actual moisture content(MC) and internal temperature in respect of drying time with calculated values based computer simulation to which was applied finite difference method. In press drying disk, heating period, constant drying rate period maintained plateau temperature at 100$^{\circ}C$ and falling drying rate period were significantly distinguished. Actual MC and internal temperature were analogous to those calculated at comparing points. Heat transfer model formed by Fourier's law using specific heat of moist wood and conduction coefficient considering fractional volume of each element of wood cell wall, bound water, free water and air showed applicability as basic data to developing heat expansion, shrinkage and drying stress during press drying. Also mass transfer model formed by Fick's diffusion law using water vapor diffusion coefficient showed applicability. Longitudinal shrinkage was developed by pressure of hot press and tangential shrinkage was restrained by hygrothermal recovery. The heart check, surface check and ring failure were occurred differently in species, but V-shaped crack didn't develop.

  • PDF

Hot Wall Epitaxy(HWE)에 의한 $AgInSe_2$단결정 박막 성장과 특성에 관한 연구 (The study of growth and characterization of $AgInSe_2$ single crystal thin film by hot wall epitaxy)

  • 홍광준
    • 한국결정성장학회지
    • /
    • 제9권2호
    • /
    • pp.197-206
    • /
    • 1999
  • 수평 전기로에서 $AgInSe_2$다결정을 합성하여 HWE(Hot Wall Epitaxy) 방법으로 $AgInSe_2$ 단결정 박막을 반절연성 GaAs(100) 위에 성장하였다. $AgInSe_2$단결정 박막은 증발원과 기판의 온도를 각각 $610^{\circ}C$, $450^{\circ}C$로 성장하였다. 이때 성장된 단결정 박막의 두께는 3.8$\mu\textrm{m}$였다. 단결정 박막의 결정성의 조사에서 20 K에서 측정한 광발광 스펙트럼은 884.1nm(1.4024eV) 근처에서 excition emission 스펙트럼이 가장 강하게 나타났으며, 또한 이중결정 X-선 회절곡선(DCXD)의 반폭치(FWHM)도 125arcsec로 매우 작은 값으로 측정되어 최적 성장 조건임을 알 수 있었다. Hall 효과는 van der Pauw 방법에 의해 측정되었으며, 온도에 의존하는 운반자 농도와 이동도는 293K에서 각각 $9.58{\times}10^{22} electron/m^3,\; 3.42{\times}10^{-2}m^2/V{\cdot}s$였다. $AgInSe_2$단결정 박막의 광전류 단파장대 봉우리들로부터 20K에서 측정된 $\Delta$Cr(Crystal field splitting)은 0.12eV, $\Delta$So(spin orbit coupling)는 0.29 eV였다. 20K에서 얻어진 광발광 봉우리들 중에서 881.1nm(1.4071 eV)와 882.4nm(1.4051 eV)는 free exciton$E_x$의 upper polariton과 lower polariton인$E_x^U$$E_x^L$를 의미하며, 884.1nm(1.4024 eV)는 donor-bound exciton emission에 의한 $I_2$봉우리를, 885.9nm(1.3995 eV)는 acceptor-bound exciton emission에 의한 $I_1$ 봉우리를 각각 나타내었다. 또한 887.5nm(1.3970 eV)에서 관측된 봉우리는 DAP(donor-acceptor pair)에 기인하는 광발광 봉우리로 해석되었다.

  • PDF