• Title/Summary/Keyword: Host materials

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Blue OLEDs Utilizing Spiro[fluorene 7,9'-benzofluorene]-type Compounds as Hosts and Dopants

  • Kim, Joo-Han;Jeon, Young-Min;Jang, Ji-Geun;Ryu, Sang-Ouk;Chang, Ho-Jung;Lee, Chil-Won;Kim, Joon-Woo;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.30 no.3
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    • pp.647-652
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    • 2009
  • A novel spiro-type host material, 5-[4-(1-naphthyl)phenyl]-spiro[fluorene-7,9'-benzofluorene] (BH-1PN) and three new dopants, namely, 5-[diphenylamino)phenyl]-spiro[fluorene-7,9'-benzofluorene] (BH-1TPA), 5-[4-(N-phenyl (m-tolyl)amino]-spiro[fluorene-7,9'-benzofluorene] (BH-1MDPA) and 5-[(N-phenyl)-2-naphthyl]amino-spiro[fluorene- 7,9'-benzofluorene] (BH-1NPA) were designed and successfully prepared using the Suzuki or amination reactions. The electroluminescence characteristics of BH-1PN as a blue host material doped with each of the blue dopants were evaluated. The structure of the device is ITO/DNTPD/NPB/BH-1PN:5% dopant/Alq3/Al-LiF. The device obtained from BH-1PN doped with diphenyl-[4-(2-[1,1;4,1]terphenyl-4-yl-vinyl)phenyl]-amine (BD-1) showed good color purity, efficiency, luminance, and current-density characteristics.

Luminescent characteristics with coupling structure of Eu for ZnO:Eu Phosphor (Zno:Eu 형광체의 Eu 결합 구조에 따른 발광 특성)

  • 박용규;한정인;조황신;주성후
    • Electrical & Electronic Materials
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    • v.10 no.8
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    • pp.763-769
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    • 1997
  • In this study we have synthesized Zno:Eu phosphors under various sintering atmospheres and temperatures. The analysis of X-ray diffractometer measurement indicates that for Zno:EuCl$_3$ phosphors sintered in air and vacuum 뗘 exists in the host lattice as Eu$_2$O$_3$and EuOCl respectively. From the photoluminescence for the phosphors sintered in vacuum Eu removes the broad-band emission of the ZnO host consequently isolating the red emission due to Eu$^{3+}$ ion and improves the color purity of red emission. The photoluminescence excitation and time resolving spectrum measurements suggest that energy-transfer process occurres from the self-activated defect center in ZnO host the Eu$^{3+}$ ion which exist in the host lattice in the form of EuOCl.

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Highly efficient deep-blue electroluminescence using doped PCVtPh with a new host material

  • Park, Jeong-Keun;Lee, Kum-Hee;Kim, Seul-Ong;Park, Jung-Sun;Seo, Ji-Hoon;Kim, Young-Kwan;Yoon, Seung-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.775-778
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    • 2009
  • Novel blue host material, 4,4'-(dinaphthalen-2-yl)-1,1'-binaphthyl (DNBN), was designed and synthesized for OLEDs. In order to test the electroluminescent properties of DNBN, DNBN was used as the host materials for a blue emitter, PCVtPh. The device exhibited deep-blue emission with the CIEx,y coordinates (x=0.15, y=0.08) at 8.0 V, a luminous efficiency of 1.66 cd/A, a power efficiency of 0.77 lm/W and an external quantum efficiency of 2.30 % at 20 mA/$cm^2$, respectively.

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Combinatorial Synthesis and Screening of the Eu-activated Phosphors in the System MO-$Al_2O_3-SiO_2$(M=Sr, Ba)

  • Yoon, Ho-Shin;Park, Jung-Kyu;Kim, Chang-Hae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.650-653
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    • 2004
  • We have synthesized some phosphors in the system MO-$Al_2O_3-SiO_2$(M=Sr, Ba) by combinatorial polymerized-complex method. Composition and synthetic temperature of phosphors in the liblary was screened from the emission intensities of individual samples under 365nm excitation. As we were screened the higher luminescent candidate composition (or candidate host lattice) at 365nm excitation, investigated whether good radiation was possible at the 405 or 465nm excitation by give the host lattice to be discovered more various change. From libraries about 2 systems, the compound to be expected in long wavelength among the compound to be screened are $Sr_4Al_{14}O_{25}$, $Sr_3Al_2O_6$, $SrAl_2Si_2O_8$, and $BaAl_2Si_2O_8$.

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Luminescence Behavior of $YNbO_4$ and $YNbO_4:Bi$

  • Chang, Hyun-Ju;Lee, Seung-Kwon;Han, Cheong-Hwa;Park, Hee-Dong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.35-36
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    • 2000
  • The luminescence behaviors of Yttrium niobate and Bi doped Yttrium niobate were investigated under UV and low voltage electron excitations and interpreted with the first-principle calculations. In the UV excitation and emission spectra of $YNbO_4$ and $YNbO_4:Bi$, we were able to separate host contribution and Bi contribution and found that the shift in emission peak to longer wavelength is mainly due to Bi contribution. Using density functional theory, the cluster calculations were carried out for both $YNbO_4$ and $YNbO_4:Bi$. From the calculated density of states, we were also able to explain the charge transfer gap in the host and the effect of Bi in the excitation and emission spectra theoretically.

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Stable efficiency roll-off in blue phosphorescent organic light-emitting diodes using a mixed host structure

  • Lee, Jong-Hee;Lee, Jeong-Ik;Lee, Jun-Yeob;Chu, Hye-Yong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.192-195
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    • 2009
  • We developed highly efficient blue PHOLEDs with reduced roll-off by using a mixed host structure. The balanced charge carrier injection and the distributed recombination zone within emissive layer resulted in a highly stable efficiency roll-off with quantum efficiencies of 20.1 and 18.1 % at a luminance of 1000 and 10000 cd/$m^2$.

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Semiconductor CdTe-Doped CdO Thin Films: Impact of Hydrogenation on the Optoelectronic Properties

  • Dakhel, Aqeel Aziz;Jaafar, Adnan
    • Korean Journal of Materials Research
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    • v.30 no.1
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    • pp.1-7
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    • 2020
  • Doping or incorporation with exotic elements are two manners to regulate the optoelectronic properties of transparent conducting (TCO) cadmium oxide (CdO). Nevertheless, the method of doping host CdO by CdTe semiconductor is of high importance. The structural, optical, and electrical properties of CdTe-doped CdO films are studied for the sake of promoting their conducting parameters (CPs), including their conductivity, carrier concentration, and carrier mobility, along with transparency in the NIR spectral region; these are then compared with the influence of doping the host CdO by pure Te ions. X-ray fluorescence (XRF), X-ray diffraction (XRD), optical absorption spectroscopy, and electrical measurements are used to characterise the deposited films prepared by thermal evaporation. Numerous results are presented and discussed in this work; among these results, the optical properties are studied through a merging of concurrent BGN (redshift) and BGW (blue shift) effects as a consequence of doping processes. The impact of hydrogenation on the characterisations of the prepared films is investigated; it has no qualitative effect on the crystalline structure. However, it is found that TCO-CPs are improved by the process of CdTe doping followed by hydrogenation. The utmost TCO-CP improvements are found with host CdO film including ~ 1 %Te, in which the resistivity decreases by ~ 750 %, carrier concentration increases by 355 %, and mobility increases by ~ 90 % due to the increase of Ncarr. The improvement of TCO-CPs by hydrogenation is attributed to the creation of O-vacancies because of H2 molecule dissociation in the presence of Te ions. These results reflect the potential of using semiconductor CdTe -doped CdO thin films in TCO applications. Nevertheless, improvements of the host CdO CPs with CdTe dopant are of a lesser degree compared with the case of doping the host CdO with pure Te ions.

A Spirobenzofluorene Type Phosphine Oxide Molecule as A Triplet Host and An Electron Transport Material for High Efficiency in Phosphorescent Organic Light-Emitting Diodes

  • Jang, Sang-Eok;Jeon, Soon-Ok;Yook, Kyoung-Soo;Joo, Chul-Woong;Son, Hyo-Suk;Lee, Jun-Yeob
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.767-770
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    • 2009
  • We synthesized a spirobenzofluorene type phosphine oxide (SPPO2) as a new triplet host and an universal electron transport material for phosphorescent organic light-emitting diodes(PHOLEDs). Red PHOLEDs with the SPPO2 host material showed a high quantum efficiency of 14.3 % with a current efficiency of 20.4 cd/A. In addition, the SPPO2 could be applied as an electron transport material which can be matched with any host material due to the lowest unoccupied molecular orbital of 2.4 eV. Electron injection from a cathode to the SPPO2 electron transport layer was better than common electron transport materials. In particular, the SPPO2 was effective as the electron transport material in blue PHOLEDs and the quantum efficiency was more than doubled and driving voltage was lowered by more than 3 V using the SPPO2 instead of common electron transport material.

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Watermarking for Digital Hologram by a Deep Neural Network and its Training Considering the Hologram Data Characteristics (딥 뉴럴 네트워크에 의한 디지털 홀로그램의 워터마킹 및 홀로그램 데이터 특성을 고려한 학습)

  • Lee, Juwon;Lee, Jae-Eun;Seo, Young-Ho;Kim, Dong-Wook
    • Journal of Broadcast Engineering
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    • v.26 no.3
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    • pp.296-307
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    • 2021
  • A digital hologram (DH) is an ultra-high value-added video content that includes 3D information in 2D data. Therefore, its intellectual property rights must be protected for its distribution. For this, this paper proposes a watermarking method of DH using a deep neural network. This method is a watermark (WM) invisibility, attack robustness, and blind watermarking method that does not use host information in WM extraction. The proposed network consists of four sub-networks: pre-processing for each of the host and WM, WM embedding watermark, and WM extracting watermark. This network expand the WM data to the host instead of shrinking host data to WM and concatenate it to the host to insert the WM by considering the characteristics of a DH having a strong high frequency component. In addition, in the training of this network, the difference in performance according to the data distribution property of DH is identified, and a method of selecting a training data set with the best performance in all types of DH is presented. The proposed method is tested for various types and strengths of attacks to show its performance. It also shows that this method has high practicality as it operates independently of the resolution of the host DH and WM data.

Thermochemical Stability and Mechanical Properties of Ceramic-Filler Added BaO-ZnO-$B_2O_3$ Based Glass for Application to Barrier Rib in Plasma Display Panels

  • Kim, Sang-Gon;Shin, Hyun-Ho;Park, Jong-Sung;Hong, Kug-Sun;Kim, Hyung-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.220-222
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    • 2004
  • Feasibility of BaO-ZnO-$B_2O_3$ (BZB) based glass system in the light of dielectric and thermal expansion properties are reported in the literature. Effects of addition of various types of ceramic fillers to the BZB-based glass on the thermochemical stability and mechanical properties were investigated in the present work. The studied filler-glass system demonstrated a capability to host various types of ceramic fillers to form thermochemically stable microcomposites at the processing temperature suitable for PDP systems. At the same time, mechanical strength of the filler-glass composites was much improved as compared to the glass itself These observations brighten the feasibility of the Pb-free BZB-based glass system as a host to employ various types of crystalline ceramic fillers so that it can be applied to barrier rib material in plasma display panels.

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