• Title/Summary/Keyword: Hopping conduction

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Small Polaron Hopping Conduction of n=3 Ruddlesden-Popper Compound La2.1Sr1.9Mn3O10 System (n=3인 Ruddlesden-Popper형 La2.1Sr1.9Mn3O10의 Small polaron Hopping 전도)

  • Jung, Woo-Hwan
    • Journal of the Korean Ceramic Society
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    • v.39 no.3
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    • pp.294-298
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    • 2002
  • Polycrystalline $La_{2.1}Sr_{1.9}Mn_3O_{10}$ with layered perovskite structure have been successfully synthesized and investigated with respect to their thermoelectric, electric and magnetic properties. The large magnetoresistance (MR) effect with $-{\Delta}{\rho}/{\rho}_0$ of ∼120% at 0.85T was observed in a wide temperature range below a cusp temperature in resistivity of about 120K, which is well below the magnetic $T_C$. At high temperature, a singnificant difference between the activation energy deduced from the electrical resistivity and thermoelectric power, a characteristic of small polaron, is observed. All of the experimental data can be well explained on the basis of the small polaron model.

Small Polaron Hopping Conduction of n=3 Ruddlesden-Popper Compound La2.1Sr1.9Mn3O10 System (II) (n=3인 Ruddlesden-Popper형 La2.1Sr1.9Mn3O10 세라믹스의 Small polaron Hopping 전도 (II))

  • Jung, Woo-Hwan;Lee, Joon-Hyung;Sohn, Jeong-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.9
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    • pp.878-883
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    • 2002
  • Electrical resistivity and thermoelectric power measurements on Mn-based $La_{2.1}Sr_{1.9}Mn_3O_{10}$ with layered perovskite structure as functions of temperature are presented. The experimental results demonstrate that the electronic transport in $La_{2.1}Sr_{1.9}Mn_3O_{10}$ is well described by the Emin-Holstein adiabatic small polaron model. The thermoelectric power data in the small polaron regime above Curie temperature is nearly equal to that predicted by nominal $Mn^{4+}$ valence arguments. This indicates that transport involves small polaron hopping.

Reconfigurable Ground-Slotted Patch Antenna Using PIN Diode Switching

  • Byun, Seung-Bok;Lee, Jeong-An;Lim, Jong-Hyuk;Yun, Tae-Yeoul
    • ETRI Journal
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    • v.29 no.6
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    • pp.832-834
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    • 2007
  • This letter presents a reconfigurable ground-slotted patch antenna using a PIN diode connection in slots to achieve dual-frequency operation. Slots in the ground plane increase the electrical length and thereby reduce antenna size by 53%. By controlling PIN diode conduction, we achieved band hopping while still satisfying the bandwidth requirements for K-PCS and WiBro bands.

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Synthesis and Characterization of Intergrowth Type Perovskite Oxide NdSr2MnCrO7

  • Singh, Devinder
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2761-2764
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    • 2011
  • A new Ruddlesden-Popper phase $NdSr_2MnCrO_7$ has been prepared by the standard ceramic method. The powder X-ray diffraction studies suggest that the phase crystallizes with tetragonal unit cell in the space group I4/mmm. The electrical transport properties show that the phase is an electrical insulator and the electrical conduction in the phase occurs by a 3D variable range hopping mechanism. The magnetic studies suggest that the ferromagnetic interactions are dominant.

Thermodynamic and Electrical Properties of Aminophenol and Anthranilic Acid Complexes with Some Transition Metals

  • M. G. Abd El Wahed;S. M. Metwally;M. M. El Gamel;S. M. Abd El Haleem
    • Bulletin of the Korean Chemical Society
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    • v.22 no.7
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    • pp.663-668
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    • 2001
  • Thermodynamic and electrical functions of aminophenol and anthranilic acid complexes with Mn(Ⅱ), Fe(Ⅱ), Co(Ⅱ), Ni(Ⅱ) and Cu(Ⅱ) were determined. ΔG°, ΔH° and ΔS° were calculated with the help of stability constant values at different temperatures. It was found that the complexing processes have an exothermic nature. The studied complexes behave like semiconductors. The conduction takes place according to hopping mechanism. To show the composition of complexes conductometric and photometric titrations, IR spectra, thermal analysis and X-ray diffraction techniques were employed.

Electrical Conductivity of Ytterbium Sesquioxide ($Yb_2O_3$) ($Yb_2O_3$의 전기 전도도)

  • 강영환;최재시;윤기현
    • Journal of the Korean Ceramic Society
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    • v.18 no.1
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    • pp.23-26
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    • 1981
  • The electrical conductivity of highly pure polycrystalline $Yb_2O_3$ has been measured from 650 to 105$0^{\circ}C$ under oxygen pressure range of $10^{-5}$ to 102 torr. The conductivity dependence of oxygen pressure in the temperature region from 750 to 105$0^{\circ}C$ is approximated by $\sigma$ $\alpha$ $Po_2^{1/5.3}$. This shows that the conduction mechanism is associated with doubly ionized metal vacancies. Fairly low activation energy and the lack of oxygen pressure dependence are found over the temperature range of 650 to 75$0^{\circ}C$. The conduction mechanism can be explaned by not metal vacancies, but hopping oxygen ions in the oxide.

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Electrical Conduction Characteristics of a Thick-film Form Multiwalled Carbon Nanotubes for Field Electron Emitter

  • Lee, Yun-Hi;Kim, Hoon;Ju, Byeong-Kwon;Yu, Jae-Eun;Oh, Myung-Hwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.53-54
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    • 2000
  • Measurements of the direct current resistivity, on multiwalled carbon nanotubes(MWNT) for field electron emitter source that had been screen printed in a thick film form were made as a function of temperature T in the range of 1.7K-390K. In this measuring temperature range, the electrical resistivity for the MWNT show that the main contribution to the conductivity comes form carries that hop directly between localized states executing variable range hopping processes. This thick-film form system for large area display showed a high bright light emission as well as very low turn-on field as like an individual MWNT system at room temperature. Furthermore, the electron emission characteristics followed well typical Fowler-Nordheim conduction under the vacuum.

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Electrical Properties of ${Ba_{0.5}}{Sr_{0.5}}{TiO_3}$Thin Film with Various Heat Treatment Conditions (다양한 열처리 조건에 따른 ${Ba_{0.5}}{Sr_{0.5}}{TiO_3}$박막의 전기적 특성)

  • 손영국
    • Journal of the Korean Ceramic Society
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    • v.38 no.5
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    • pp.492-498
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    • 2001
  • Ba$_{0.5}$Sr$_{0.5}$TiO$_3$타겟을 이용 Pt/Ti/SiO/Si 기판 위에 R.F magnetron sputtering 방법으로 BST 박막을 증착하여 다양한 열처리 조건에 따른 BST 박막의 전기적 성질(정전용량, 누설전류)에 대해 박막의 결정성과 미세구조의 연관성에 대하여 연구하였다. BST 박막의 유전상수는 grain size에 영향 받으며, 열처리 온도가 증가할수록 유전상수는 증가함을 보였고 온도에 따른 누설전류는 저전압 영역에서는 Hopping conduction, 고전압 영역에서는 Schottky conduction mechanism을 따르는 것으로 나타났다.

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Electrical Transport and Magnetic Properties in ${(LaMn) }_{1-λ }O }_{3 }$ (${(LaMn) }_{1-λ }O }_{3 }$의 전기전도 및 자기적 특성)

  • 정우환
    • Journal of the Korean Ceramic Society
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    • v.35 no.8
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    • pp.885-889
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    • 1998
  • The temperature dependence of dc conductivity and magnetic properties of cation deficient {{{{ { {(LaMn) }_{1-λ }O }_{3 } }} systems has been investigated,. Above 160K the magnetic susceptibility of all samples followed the Curie-Weiss law. The Curie temperature decreased as the cation deficiency increased. This is due to a strong Jahn-Teller effect originated from electrons of {{{{ { Mn}^{3+ } }} In the case of samples annealed in air and oxygen at-mosphere the charge carriers responsible for conduction in the ferromagnetic regime below the Curie tem-perature are believed to have both magnetic and lattice characteristics. However the conduction carriers in the paramagnetic regime above the Curie temperature are though to be formed by hopping process of small polarons which were generated by assistance of the Jahn-Teller effect.

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