• Journal of the Society of Cosmetic Scientists of Korea
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• v.25 no.1
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• pp.37-54
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• 1999

Planarized SiO$_2$ particles were prepared by two-step reduction method of making much smaller particles, micron-sized ones, to improve spreadability, adherence, and smoothness. Various pigments known as flaky extender usually have terrace layers on their surfaces, but SiO$_2$ Particles in this study exhibit a smooth surface structure. These single SiO$_2$ particles were used for core particles to prepare the composite particles coated with ultra fine TiO$_2$ particles by a homogeneous precipitation method. The thickness and the morphology of the deposited TiO$_2$ layer could be altered by adjusting the reactant concentrations, reaction time and temperature. The characteristics of SiO$_2$/TiO$_2$composite in the field of color cosmetics is to give a UV-cut effect and to enhance the chroma of human skin color, one of optical properties.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.23 no.3
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• pp.267-274
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• 2010

Unlike the structure which has a homogeneous material property, a composite structure is coupled with materials which have different properties, namely, steel and concrete. At actual modeling, the real behavior cannot be predicted without consideration of those material characteristics. Therefore, by putting the interface element between concrete and steel, a slip of steel and concrete is made predictable. Interface element can be used properly not by an ordinary constitutive relation, but by a non-linear constitutive relation considering actual adhesion and slip. A contact surface between plate-shape steel box and concrete is described by using this interface element. Furthermore, because the general 8 node conforming element is inappropriate for describing a bending buckling behavior of steel box, the EAS(Enhanced Assumed Strain) solid-shell element is used to describe a bending behavior of plate-shape steel box.

• Polymer(Korea)
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• v.37 no.4
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• pp.507-512
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• 2013

A graphene/waterborne polyurethane (WPU) nano composite was prepared by in-situ polymerization of PU and graphene having isocyanate (iGO) group in order to improve physicochemical/electrical characteristics. The properties of the graphene/WPU nanocomposite can effectively be enhanced as compared pristine WPU; up to 57% of tensile strength and $10^2$ fold of electrical conductivity with introduction of 2 wt% graphene. In addition, mechanical/electrical properties of the graphene/WPU nanocompsite were higher than those of graphene/WPU composite prepared by a simple physical blend method. It might attribute to homogeneous dispersion of iGO in the WPU matrix via covalent bonds and hydrogen bonds between WPU and iGO from the results of morphological analysis by scanning electron microscopy (SEM).

• Coupled systems mechanics
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• v.8 no.4
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• pp.299-313
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• 2019

The paper represents computer modeling of the deformed state of physically nonlinear transversally isotropic bodies with hole. In order to describe the anisotropy of the mechanical properties of transversally-isotropic materials a structurally phenomenological model has been used. This model allows representing the initial material in the form of the coupled isotropic materials: the basic material (binder) considered from the positions of continuum mechanics and the fiber material oriented along the anisotropy direction of the original material. It is assumed that the fibers perceive only the axial tensile-compression forces and are deformed together with the base material. To solve the problems of the theory of plasticity, simplified theories of small elastoplastic deformation have been used for a transversely-isotropic body, developed by B.E. Pobedrya. A simplified theory allows applying the theory of small elastoplastic deformations to solve specific applied problems, since in this case the fibrous medium is replaced by an equivalent transversely isotropic medium with effective mechanical parameters. The essence of simplification is that with simple stretching of composite in direction of the transversal isotropy axis and in direction perpendicular to it, plastic deformations do not arise. As a result, the intensity of stresses and deformations both along the principal axis of the transversal isotropy and along the perpendicular plane of isotropy is determined separately. The representation of the fibrous composite in the form of a homogeneous anisotropic material with effective mechanical parameters allows for a sufficiently accurate calculation of stresses and strains. The calculation is carried out under different loading conditions, keeping in mind that both sizes characterizing the fibrous material fiber thickness and the gap between the fibers-are several orders smaller than the radius of the hole. Based on the simplified theory and the finite element method, a computer model of nonlinear deformation of fibrous composites is constructed. For carrying out computational experiments, a specialized software package was developed. The effect of hole configuration on the distribution of deformation and stress fields in the vicinity of concentrators was investigated.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.15 no.1
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• pp.83-90
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• 2017

The pyroprocessing of spent nuclear fuel generates LiCl-KCl eutectic waste salt containing radioactive rare earth nuclides. It is necessary to develop a simple process for the treatment of LiCl-KCl eutectic waste in a hot-cell facility. In this study, capture and solidification of a rare earth nuclide (Nd) in LiCl-KCl eutectic salt using an inorganic composite with a $Li_2O-Al_2O_3-SiO_2-B_2O_3$ system was conducted to simplify the existing separation and solidification process of rare earth nuclides in LiCl-KCl eutectic waste salt from the pyroprocessing of spent nuclear fuel. More than 98wt% of Nd in LiCl-KCl eutectic salt was captured when the mass ratio of the composite was 0.67 over $NdCl_3$ in the eutectic salt. The content of $Nd_2O_3$ in the Nd captured-composite reached about 50wt%, and this composite was directly fabricated into a homogeneous and chemical resistant glass waste in a monolithic form. These results will be utilized in designing a process to simplify the existing separation and solidification process.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.30 no.3
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• pp.255-263
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• 2017

This paper presents a beam element capable of conducting material and geometric nonlinear analysis for applications requiring the ultimate behavioral analysis of structures with composite cross-sections. The element formulation is based on co-rotational kinematics to simulate geometrically nonlinear behaviors, and it uses the fiber section method to calculate the stiffness and internal forces of the element. The proposed element was implemented using an in-house numerical program in which an arc-length method was adopted to trace severe nonlinear responses(such as snap-through or snapback), as well as ductile behavior after the peak load. To verify the proposed method of element formulation and the accuracy of the program that was used to employ the element, several numerical studies were conducted and the results from these numerical models were compared with those of three-dimensional continuum models and previous studies, to demonstrate the accuracy and computational efficiency of the element. Additionally, by evaluating an example case of a frame structure with a composite member, the effects of differences between composite material properties such as the elastic modulus ratio and strength ratio were analyzed. It was found that increasing the elastic modulus of the external layer of a composite cross-section caused quasi-brittle behavior, while similar responses of the composite structure to those of homogeneous and linear materials were shown to increase the yield strength of the external layer.

• Journal of Mechanical Science and Technology
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• v.17 no.6
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• pp.836-843
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• 2003

The polymer composites contain numerous internal boundaries and its structural elements have different responses and different resistances under the same service environment. Fatigue phenomenon is much more complex in composites than homogeneous materials. An understanding of the fracture behavior of polymer composite materials subjected to constant and cyclic loading is necessary for predicting the life time of structures fabricated with polymers. There is a need to acquire a better understanding of the fatigue performance and failure mechanisms of composites under such conditions. Therefore, in this study the analyses of fiber orientation and fracture mechanism for low cycle fatigue crack have been studied by SEM and LM for observing the ultrathin sections.

• Steel and Composite Structures
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• v.18 no.1
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• pp.91-120
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• 2015

A refined higher-order shear deformation theory for bending, vibration and buckling analysis of functionally graded sandwich plates is presented in this paper. It contains only four unknowns, accounts for a hyperbolic distribution of transverse shear stress and satisfies the traction free boundary conditions. Equations of motion are derived from Hamilton's principle. The Navier-type and finite element solutions are derived for plate with simply-supported and various boundary conditions, respectively. Numerical examples are presented for functionally graded sandwich plates with homogeneous hardcore and softcore to verify the validity of the developed theory. It is observed that the present theory with four unknowns predicts the response accurately and efficiently.

• Steel and Composite Structures
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• v.21 no.5
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• pp.999-1016
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• 2016

This study presents free vibration of beam made of porous material. The mechanical properties of the beam is variable in the thickness direction and the beam is investigated in three situations: poro/nonlinear nonsymmetric distribution, poro/nonlinear symmetric distribution, and poro/monotonous distribution. First, the governing equations of porous beam are derived using principle of virtual work based on Euler-Bernoulli theory. Then, the effect of pores compressibility on natural frequencies of the beam is studied by considering clamped-clamped, clamped-free and hinged-hinged boundary conditions. Moreover, the results are compared with homogeneous beam with the same boundary conditions. Finally, the effects of poroelastic parameters such as pores compressibility, coefficients of porosity and mass on natural frequencies has been considered separately and simultaneously.

• 한국전기화학회:학술대회논문집
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• 2005.07a
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• pp.233-240
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• 2005

A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxidenanoparticles content. Their water uptake, methanol permeability and proton conductivity as a function of inoranic oxide content were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and water swelling. It is also found that increase In inorganic oxide content leads to decrease of methanol permeability. In terms of the morphology, membranes are homogeneous and exhibit a good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with the standard nafion membrane.