• 제목/요약/키워드: Homogeneous Solution

검색결과 561건 처리시간 0.033초

High-$I_c$ single-coat YBCO films prepared by the MOD process

  • Lee, J.W.;Shin, G.M.;Yoo, S.I.
    • 한국초전도ㆍ저온공학회논문지
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    • 제13권4호
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    • pp.22-25
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    • 2011
  • A single-coat $YBa_2Cu_3O_{7-{\delta}}$ (YBCO) film of high critical currents ($I_c$) could be successfully fabricated by optimizing the viscosity of the coating solution in the metal-organic deposition (MOD) process. From a Ba-deficient coating solution (Y: Ba: Cu = 1: 1.5: 3) having the viscosity of 212 $mPa{\cdot}sec$, 0.9 ${\mu}m$-thick single coat YBCO film with the $I_c$ value of 289 A/cm-width ($J_c$ = 3.2 MA/$cm^2$) at 77 K was achievable on the $SrTiO_3$ (STO) substrate, which was superior to that of our previous report for 0.8 ${\mu}m$-thick single coat YBCO film from a stoichiometric coating solution (Y: Ba: Cu = 1: 2: 3) on the $LaAlO_3$ (LAO) substrate. This result might be attributed to denser and more homogeneous microstrcuture in the case of the YBCO film from the Ba-deficient coating solution.

이온빔 조사된 용액 공정 기반 LaZnO 박막 위 액정 분자의 수평 배향 특성 (Homogeneous Alignment Characteristics of Liquid Crystal Molecules on Solution-Derived Lanthanum Zinc Oxide Film with Ion-Beam Irradiation)

  • 오병윤
    • 한국전기전자재료학회논문지
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    • 제32권5호
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    • pp.382-386
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    • 2019
  • The alignment characteristics of liquid crystal (LC) molecules on a solution-derived lanthanum zinc oxide (LZO) film under ion-beam irradiation were demonstrated. Using the solution process, an LZO film was fabricated on the glass substrate and cured at $100^{\circ}C$. Afterwards, ion-beam irradiation was performed following the LC alignment method. Using this film, an LC cell was fabricated and the characteristics of the LC alignment were verified. Cross polarizing microscopy and the crystal rotation method were used to investigate the alignment state of the LC molecules on the LZO films. Furthermore, field emission scanning electron microscopy and X-ray photoelectron spectroscopy were used to explore the effect of the ion-beam irradiation on the LZO film. Through these, it was confirmed that the ion-beam irradiation induced surface modification, which demonstrated anisotropic physical and chemical surface characteristics. Due to this, uniform LC alignment was achieved. Finally, the residual DC and anchoring energy of the LC cell based on the LZO films were measured using a capacitance-voltage curve.

Instability of (Heterogeneous) Euler beam: Deterministic vs. stochastic reduced model approach

  • Ibrahimbegovic, Adnan;Mejia-Nava, Rosa Adela;Hajdo, Emina;Limnios, Nikolaos
    • Coupled systems mechanics
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    • 제11권2호
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    • pp.167-198
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    • 2022
  • In this paper we deal with classical instability problems of heterogeneous Euler beam under conservative loading. It is chosen as the model problem to systematically present several possible solution methods from simplest deterministic to more complex stochastic approach, both of which that can handle more complex engineering problems. We first present classical analytic solution along with rigorous definition of the classical Euler buckling problem starting from homogeneous beam with either simplified linearized theory or the most general geometrically exact beam theory. We then present the numerical solution to this problem by using reduced model constructed by discrete approximation based upon the weak form of the instability problem featuring von Karman (virtual) strain combined with the finite element method. We explain how such numerical approach can easily be adapted to solving instability problems much more complex than classical Euler's beam and in particular for heterogeneous beam, where analytic solution is not readily available. We finally present the stochastic approach making use of the Duffing oscillator, as the corresponding reduced model for heterogeneous Euler's beam within the dynamics framework. We show that such an approach allows computing probability density function quantifying all possible solutions to this instability problem. We conclude that increased computational cost of the stochastic framework is more than compensated by its ability to take into account beam material heterogeneities described in terms of fast oscillating stochastic process, which is typical of time evolution of internal variables describing plasticity and damage.

분무열분해공정에 의한 인듐 산화물 나노 분말 제조에 미치는 반응인자들의 영향 (Effect of Reaction Factors on the Fabrication of Nano-Sized Indium Oxide Powder by Spray Pyrolysis Process)

  • 유재근
    • 한국분말재료학회지
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    • 제11권6호
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    • pp.493-502
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    • 2004
  • In this study, nano-sized indium oxide powder with the average particle size below 100 nm is fab-ricated from the indium chloride solution by the spray pyrolysis process. The effects of the reaction temperature, the concentration of raw material solution and the inlet speed of solution on the properties of powder were studied. As the reaction temperature increased from 850 to $1000^{\circ}C$, the average particle size of produced powder increased from 30 to 100 nm, and microstructure became more solid, the particle size distribution was more irregular, the intensity of a XRD peak increased and specific surface area decreased. As the indium concentration of the raw material solution increased from 40 to 350 g/l, the average particle size of the powder gradually increased from 20 to 60 nm, yet the particle size distribution appeared more irregular, the intensity of a XRD peak increased and spe-cific surface area decreased. As the inlet speed of solution increased from 2 to 5 cc/min., the average particle size of the powder decreased and the particle size distribution became more homogeneous. In case of the inlet speed of 10 cc/min, the average particle size was larger and the particle size distribution was much irregular compared with the inlet speed of 5 cc/min. As the inlet speed of solution was 50 cc/min, the average particle size was smaller and microstructure of the powder was less solid compared with the inlet speed of 10 cc/min. The intensity of a XRD peak and the variation of specific area of the powder had the same tendency with the variation of the average par-ticle size.

다관능 아크릴레이트계 자외선 경화형 코팅액의 제조 및 이를 이용한 PET 필름 도막의 광학 특성 연구 (Preparation of UV curable coating solution from multi functional acrylates and characterization of optical properties of coated layer on PET film)

  • 이수;진석환
    • 한국응용과학기술학회지
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    • 제26권4호
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    • pp.467-472
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    • 2009
  • Ultraviolet curable coating solution was prepared with poly(ethylene glycol) acrylate oligomer and various mono and multi-functional acrylate monomers. The optical properties of UV cured coating layer on PET film with acrylate coating solution containing metal oxides, such as fumed silica and alumina, were also investigated to reduce light reflection on films. Poly(ethylene glycol) diacrylate which has 575 of average molecular weight was used as oligomer acrylate, and pentaerythritol triacrylate and dipentaerythritolpenta-/hexa acrylate were used as multi-functional acrylate monomers. Also, butyl acrylate was used to improve the adhesion as well as to reduce glass transition temperature to give a better flexability. 1-hydroxy cyclohexyl phenyl ketone was used as photoinitiator. We found out the metal oxides in acrylate coating solution showed a homogeneous dispersion from energy dispersive spectroscopy data. Transmittance and light reflection of coated PET film was measured with UV/vis spectrometer and gloss meter, respectively. When 1.00 g of both metal oxides was added into coating solution, the transmittance and the glossiness were reduced from 90% to 30% and from 190 GU to 35 GU, respectively. However, adding up to 1.00 g of the metal oxide into coating solution did not affect on the hardness of coating layer and adhesion between coated layer and PET film. Conclusively, we can control transmittance and light reflection of coated film by adjusting the amounts of metal oxide in coating solution.

A NOTE ON A FINITE ELEMENT METHOD DEALING WITH CORNER SINGULARITIES

  • Kim, Seok-Chan;Woo, Gyung-Soo;Park, Tae-Hoon
    • Journal of applied mathematics & informatics
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    • 제7권2호
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    • pp.493-506
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    • 2000
  • Recently the first author and his coworker report a new finite element method for the Poisson equations with homogeneous Dirichlet boundary conditions on a polygonal domain with one re-entrant angle [7], They use the well-known fact that the solution of such problem has a singular representation, deduced a well-posed new variational problem for a regular part of solution and an extraction formula for the so-called stress intensity factor using tow cut-off functions. They use Fredholm alternative an Garding's inequality to establish the well-posedness of the variational problem and finite element approximation, so there is a maximum bound for mesh h theoretically. although the numerical experiments shows the convergence for every reasonable h with reasonable size y imposing a restriction to the support of the extra cut-off function without using Garding's inequality. We also give error analysis with similar results.

Preparation and Characterization of Chemically Stable PVDF-HFP Asymmetric Microfiltration (MF) Membranes

  • Lee, Yeon-Ee;JeGal, Jong-Geon
    • 멤브레인
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    • 제22권2호
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    • pp.104-112
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    • 2012
  • Chemically stable Polyvinylidene fluoride-hexa-fluoropropane (PVDF-HFP) copolymer asymmetric membranes were prepared by the conventional phase inversion process, using Dimethyacetamide (DMAc) as a solvent and water as a non-solvent. To control the pore size and porosity of the PVDF-HFP membranes, tetra-ethoxysilane (TEOS) was used as a pore-forming agent. The prepared membranes were characterized, using several analytical methods such as Fourier Transform Infrared spectroscopy (FTIR), Thermo-gravimetric analyzer (TGA), Field Emission Scanning Electronic Microscopy (FESEM). TEOS turned out to increase porosity and make homogeneous pores on the membranes. Depending on the composition of the dope solutions, the pore size was ranged from 0.1 to 1.0 ${\mu}m$. The flux of the PVDF-HFP membranes prepared by using TEOS as a pore forming agent was increased substantially without much decrease in the rejection. When 15 wt% PVDF-HFP solution was blended with 13 wt% TEOS solution at composition ratio of 70/30 in wt%, the water flux at 2 bars was about 2 $m^3/m^2day$.

물과 에탄을 이성분 혼합용매 계에서 부피 및 온도 변화에 관한 연구 (A Study on the Change of Volume and Temperature in Aqueous Binary Solvent with Ethanol)

  • 김용권;임귀택
    • 한국초등과학교육학회지:초등과학교육
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    • 제20권1호
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    • pp.139-147
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    • 2001
  • This paper is to study on the change of volume and temperature of the solution which mixed water with ethanol. And its main purpose is to examine closely how the volume changes, and to find the method to maximize the change of the volume. The summaries for results of the study are; First, we were known that water and ethanol are homogeneously mixed. But two solvents does not mix homogeneously by different specific gravity at early stages. Second, we could see that the volume changed large at homogeneous mixed water with ethanol by stirrer, the change of volume is the largest value when water mixed with ethanol in the ratio of one to one. Third, when water mixed with ethanol in the ratio of one to one, the change of temperature is very large by activated hydrogen bond. We conclude that it is the best result when ratio of water and ethanol is one to one and the solution is well mixed.

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Elastodynamic Response of a Crack Perpendicular to the Graded Interfacial Zone in Bonded Dissimilar Materials Under Antiplane Shear Impact

  • Kim, Sung-Ho;Choi, Hyung-Jip
    • Journal of Mechanical Science and Technology
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    • 제18권8호
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    • pp.1375-1387
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    • 2004
  • A solution is given for the elastodynamic problem of a crack perpendicular to the graded interfacial zone in bonded materials under the action of anti plane shear impact. The interfacial zone is modeled as a nonhomogeneous interlayer with the power-law variations of its shear modulus and mass density between the two dissimilar, homogeneous half-planes. Laplace and Fourier integral transforms are employed to reduce the transient problem to the solution of a Cauchy-type singular integral equation in the Laplace transform domain. Via the numerical inversion of the Laplace transforms, the values of the dynamic stress intensity factors are obtained as a function of time. As a result, the influences of material and geometric parameters of the bonded media on the overshoot characteristics of the dynamic stress intensities are discussed. A comparison is also made with the corresponding elastostatic solutions, addressing the inertia effect on the dynamic load transfer to the crack tips for various combinations of the physical properties.

열하중을 받는 이종재 V-노치 균열의 응력강도계수 해석

  • 문창호;조상봉;김진광;노홍래
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2003년도 추계학술대회 논문요약집
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    • pp.240-240
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    • 2003
  • V-노치 균열에서 열하중이 작용하는 경우는 비제차형 경계조건의 문제가 되고, 이 조건에 대한 방정식의 일반해를 구하기 위해서 재차형 연립방정식에 대한 일반해(Homogeneous solution)와 비제차형 연립방정식에 대한 특수해(Particular solution)의 두 가지 해를 구할 수 있다. 이들 해는 V-노치 균열에 대한 고유치가 되고 이 고유치가 중복근을 가지게 되는 경우에는 로그항(1n[r])이 나타나게 되고 이 항에 의해서 응력을 무한대로 발산시키므로 이를 대수응력특이성이라 한다. 열하중이 작용할 때 대수응력특이성을 나타내는 로그항의 계수가 영(0)이 되어 대수응력특이성이 사라지게 되므로 V-노치 선단에서의 응력특이성은 고유치와 그에 대한 고유벡터에 의해 결정된다. 본 논문에서는 비정상상태 열하중이 가해지는 등방성 이종재료 내의 V-노치 균열문제에서 패기 각도와 이종재료의 기계적 성질에 의해 결정되는 응력특이성지수를 구하고 이에 대한 응력강도계수를 유한요소해석 프로그램인 ANSYS와 상반일 경로 적분법(RWCIM)을 이용하여 구하였다.

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