• Journal of Environmental Science International
• /
• v.17 no.2
• /
• pp.211-224
• /
• 2008

Characteristics of the esterification reaction between free fatty acid in rice bran oil and methanol was investigated in the presence of catalysts, such as PTS(p-toluene sulfonic acid), Amberlyst 15 dry and SCX(silica gel based strong cation exchange resin). While reaction temperature was kept constant at $65^{\circ}C$, initial feed content of free fatty acid was varied from 100% to 1% by addition of pure free fatty acid which was previously made from rice bran oil. Also, the effect of mole ratio of methanol to fatty acid on the final conversion was examined. When esterification of pure free fatty acid was catalyzed by several acids, final conversions were increased in order of Amberlyst 15 dry, SCX and PTS. Using PTS catalyst, initially the reaction proceeded in homogeneous 2nd oder reaction mechanism. However, phase of reaction mixture changed from homogeneous to heterogeneous along the reaction time and then reaction rate was retarded by mass transfer resistance of methanol. Final conversion of free fatty acid in reaction mixture was depended on initial feed content of free fatty acid, and had maximum value at 30% of initial feed free fatty acid content for all kinds of catalysts used. And the final conversion was increased with mole ratio of methanol by the improvement of reaction rate. When initial feed free fatty acid content below 10% and the reaction was catalyzed by PTS, concentration of free fatty acid in reaction mixture was increased in the middle of reaction time by hydrolysis of triglyceride in reaction mixture. Also, if silica gel was added into the reaction mixture which had initial feed free fatty acid content below 50%, final conversion was increased by the adsorption of moisture produced. The SCX catalyst made the esterification reaction of free fatty acid to progress like in case of PTS catalyst. However, when initial feed free fatty acid content below 10%, concentration of free fatty acid in. reaction mixture was decreased monotonically and not increased in the middle of reaction time on the contrary to the case of PTS. Thus, SCX catalyst accomplished more high value of final conversion than PTS catalyst for the initial feed fatty acid content range from 50% to 5% In case of initial feed free fatty acid content of 1% and mole ratio of methanol was 2, concentration of free fatty acid in reaction mixture increased over the initial feed free fatty acid content for all kind of catalysts used. Although SCX catalyst was added into reaction mixture which had 1% of initial feed fatty acid content, final conversion was hardly raised by mole ratio of methanol.

• Transactions of the Korean Society for Noise and Vibration Engineering
• /
• v.26 no.2
• /
• pp.141-147
• /
• 2016

Underwater cavitation is one of the most important issues because it causes not only vibration and erosion of submerged bodies but also significant flow noise problems. In this paper, flow noise due to cavitation flows around the NACA66 MOD hydrofoil is numerically investigated. The cavitation flow simulation is conducted using the Reynolds-Averaged Navier-Stokes equations based on finite difference methods. To capture the cavitation phenomena accurately and effectively, the homogeneous mixture model with the Merkle's cavitation model is applied. The predicted results are compared with available experimental data in terms of pressure coefficients and volume fraction, which confirms the validity of numerical results. Based on flow field analysis results, hydro-acoustic noise field due to the cavitation flow is predicted using the Ffowcs-Williams and Hawkings equation derived from the Lighthill's acoustic analogy. The typical lift dipole propagation patterns are identified.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.26 no.8
• /
• pp.1138-1144
• /
• 2002

Recently GDI(Gasoline Direct Injection) engine is spot-lighted to achieve higher thermal efficiency under partial loads and better performance at full loads. To realize this system, it is essential to make both stratified combustion and homogeneous combustion. Spray pattern must be optimized according to injection timing because ambient pressure in combustion chamber is varied with crank angle. In this experimental study, two types of visualization system such as laser scattering method and schlieren method were developed to clarity the spray behavior during on intake stroke. As the ambient pressure increases, thepenetration length and spray angle show a tendancy to decrease due to rising resistance caused by the drag force of the ambient air. Distribution of injected fuel on intake stroke has a significant effect on homogeneous mixture in the cylinder. These results provide the information on macroscopic wall-wet growth in the cylinder and design factors for developing GDI injector.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.22 no.1
• /
• pp.157-164
• /
• 2014

Dual fuel combustion strategy with di-methl ether (DME) and gasoline was tested in a compression ignition engine. Characteristics of combustion and emissions were analyzed with the variation of engine operating parameters such as fuel proportion, DME injection timing, intake oxygen concentration, DME injection pressure and so forth. Gasoline was injected into the intake manifold to form the homogeneous mixture with intake charge and DME was injected directly into the cylinder at the late compression stroke to ignite the homogeneous gasoline-air mixture. Dual fuel combustion strategy was advantageous in achievement of higher thermal efficiency and low NOx emission compared with DME single fuel combustion. Higher thermal efficiency was attributed to the lower heat tranfer loss from the decreased combustion temperature since the amount of lean premixed combustion was increased with the larger amount of gasoline proportion. Lower NOx emissions were also possible by lowering the combustion temperature.

• Journal of the Korean Society of Combustion
• /
• v.18 no.4
• /
• pp.12-20
• /
• 2013

The ignition delay time is an important factor to understand the combustion characteristics of internal combustion engine. In this study, ignition delay times of cool and thermal flame were observed separately in homogeneous charge compression ignition(HCCI) engine. This study presents numerical investigation of ignition delay time of n-heptane and alcohol(ethanol and n-butanol) binary fuel. The $O_2$ concentration in the mixture was set 9-10% to simulate high exhaust gas recirculation(EGR) rate condition. The numerical study on the ignition delay time was performed using CHEMKIN codes with various blending ratios and EGR rates. The results revealed that the ignition delay time increased with increasing the alcohol fraction in the mixture due to a decrease of oxidation of n-heptane at the low temperature. From the numerical analysis, ethanol needed more radical and higher temperature than n-butanol for oxidation. In addition, thermal ignition delay time is sharply increasing with decreasing $O_2$ fraction, but cool flame ignition delay time changes negligibly for both binary fuels. Also, in high temperature regime, the ignition delay time showed similar tendency with both blends regardless of blending ratio and EGR rate.

• Journal of computational fluids engineering
• /
• v.17 no.1
• /
• pp.78-85
• /
• 2012

Cavitation causes a great deal of noise, damage to components, vibrations, and a loss of efficiency in devices, such as propellers, pump impellers, nozzles, injectors, torpedoes, etc., Thus, cavitating flow simulation is of practical importance for many engineering systems. In this study, a two-phase flow solver based on the homogeneous mixture model has been developed. The flow characteristics around an axisymmetric cylinder were calculated and then validated by comparing with the experimental results in the cavitation water tunnel at the Korea Ocean Research & Development Institute. The results show that this solver is highly suitable for simulating the cavitating flows. After the code validation, the cavity length with changes of water depth, angle of attack and velocity were obtained.. Cavitation inception was also calculated for various operational conditions.

• Journal of computational fluids engineering
• /
• v.19 no.2
• /
• pp.17-23
• /
• 2014

Cavitation causes a great deal of noise, damage to components, vibrations, and a loss of efficiency in devices, such as propellers, pump impellers, nozzles, injectors, torpedoes, etc. Thus, the cavitating flow simulation is of practical importance for many engineering systems. In the present work, a two-phase flow solver based on the homogeneous mixture model has been developed. The solver employs an implicit preconditioning, dual time stepping algorithm in curvilinear coordinates. The flow characteristics around Clark-Y hydrofoil were calculated and then validated by comparing with the experimental data. The lift and drag coefficients with changes of angle of attack and cavitation number were obtained. The results show that cavity length and lift, drag coefficient increase with increasing angle of attack.

• Journal of computational fluids engineering
• /
• v.18 no.1
• /
• pp.13-21
• /
• 2013

Cavitating flow is usually formed on the surface of a high speed underwater object. When a object moves near a free surface at very high speed, the cavity signature becomes one of the major factors to be overcome by sensors of military satellite. The present work was to study the free surface effect on the ventilated cavitation. The governing equations were Navier-Stokes equations based on a homogeneous mixture model. The multiphase flow solver used an implicit preconditioning method in the curvilinear coordinate system. The cavitation model used here was the one first presented by Merkle et al.(2006) and redeveloped by Park & Ha(2009). Computations considered the free surface effects were carried out with a NACA0012 hydrofoil and the corresponding results were compared with the experimental data to have a good agreement. Calculations were then performed considering the ventilated cavitation, including the effect of non-condensable gas under the free surface effects.

• Journal of Powder Materials
• /
• v.11 no.2
• /
• pp.105-110
• /
• 2004

In this study the possibility to obtain a homogeneous mixture and to produce solid solutions and intermetallic compounds of Fe and Al nano particles by simultaneous pulsed wire evaporation (S-PWE) have been investigated. The Fe and Al wires with 0.45 mm in diameter and 35 mm in length were continuously co-fed by a special mechanism to the explosion chamber and simultaneously exploded. The characteristics, e.g., phase composition, particle shape, and specific surface area of Fe-Al nano powders have been analyzed. The synthesized powders, beside for Al and $\alpha$-Fe, contain significant amount of a high-temperature phase of $\gamma$-Fe, Fe Al and traces of other intermetallics. The phase composition of powders could be changed over broad limits by varying initial explosion conditions, e.g. wire distance, input energy, for parallel wires of different metals. The yield of the nano powder is as large as 40 wt ％ and the powder may include up to 46 wt % FeAl as an intermetallic compound.

• Journal of the Korean Data and Information Science Society
• /
• v.26 no.6
• /
• pp.1295-1303
• /
• 2015

In a mixture experiment, one may be interested in estimating not only main effects but also some interactions. Main effects and interactions may be estimated through appropriate designs such as simplex-centroid designs. However, the estimability problems, implied by the sum to one functional relationship among the factors, have strong consequences on the confounding and identifiability of models for such designs. To handle these problems, we address homogeneous polynomial model based on the computational commutative algebra (CCA) instead of using $Scheff{\acute{e}}s$ canonical model which is typically used. The problem posed here is to give how to choose estimable main effects and also some low-degree interactions. The theory is tested using a fraction of simplex-centroid designs aided by a modern computational algebra package CoCoA.