• 공업화학
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• 제24권5호
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• pp.456-470
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• 2013

중공사형 막은 지난 수십 년간 빠르게 성장하고 있는 새로운 기술의 하나이다. 또한, 고분자 소재를 이용한 분리막은 기체분리, 연료전지, 수처리, 폐수처리, 유기물 분리 등 여러 분야에서 주목 받고 있다. 그중에서도 액체분리용 역삼투(RO)와 한외여과(Ultrafiltration)막의 중간 특성을 갖는 나노여과(Nanofiltration)막은 상대적으로 역삼투 막에 비하여 낮은 투자비와 낮은 운전압력, 높은 투과 성능을 가지며 다가 음이온 염과 $200{\sim}1000gmol^{-1}$사이의 유기물에 대한 높은 제거율을 갖는 막이다. 본 논문에서는 NF 중공사 분리막의 소재, 제조 방법(상전이법과 계면중합법)에 따른 멤브레인의 구조 제어 및 다양한 특성 평가에 관한 연구동향을 살펴보고자 한다. 현재 대부분의 NF용 분리막은 평막형(plate and frame type)이나 나권형(spiral wound type)으로 제품화 되고 있는데, 중공사형(hollow-fiber type)의 제품화가 지연되고 있는 것은 기존 소재를 바탕으로 제조할 경우 강도면에서 안정적이지 못한 면이 있으므로 새로운 소재를 개발하거나 기존 소재의 개선이 필요할 것으로 보인다. 이러한 부분을 보완할 수 있을 만한 제조 기술이 확보된다면 중공사 형태의 나노여과막이 점차 나권형막을 대체하여 시장에서 높은 점유율을 나타낼 수 있을 것이다.

• 멤브레인
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• 제29권6호
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• pp.362-376
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• 2019

본 연구에서는 열유도상분리법(thermally induced phase separation)을 사용하여 제조한 플라워 형태의 단면을 갖는 PVDF [poly(vinylidene fluoride)] 중공사 분리막에 대한 친수화 코팅과 그에 따른 특성평가에 대한 연구를 수행하였다. 연구에 사용한 중공사 분리막은 (주)퓨어엔비텍에서 제조한 PVDF 소재의 분리막이었으며, 친수화 코팅 실험은 PEBAX 1657, 2533, 3533의 공중합체 고분자를 사용하여 농도가 다른 용액을 제조 후 딥 코팅 방법을 이용하여 실시하였다. 친수화 코팅이 된 중공사 분리막은 친수화 정도를 파악하기 위하여 SEM 촬영 및 접촉각 측정을 실시하였다. SEM 촬영 결과 코팅의 농도가 증가하고 코팅횟수가 증가할수록 코팅층의 두께가 두꺼워짐을 확인하였고, 접촉각 측정의 경우 코팅의 농도가 증가하고 코팅횟수가 증가할수록 접촉각이 낮아짐을 확인하였다. 기체 투과 실험 결과 코팅농도가 증가하고 코팅횟수가 증가할수록 산소 기체투과량이 감소하였으며 친수성이 높은 PEBAX 1657로 코팅한 중공사의 기체투과량이 PEBAX 2533과 3533으로 코팅된 중공사보다 낮은 기체투과량을 가짐을 확인하였다.

• 한국생산제조학회지
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• 제7권4호
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• pp.73-78
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• 1998

In this paper, we have studied about the thermal expansion of the ball screw used for the CNC machine tools. The hollow ball type is used for the ball screw. We have compared the conventional cooling system and function with the improved cooling system and function which is developed the path providing cooling oil in hollow ball screw. That is the temperature variation and positioning accuracy are analyzed of the ball screw. We have obtained the following results through this experiment. 1) The improved cooling system of the hollow ball screw for CNC machine tools was developed 2) The improved cooling system of the hollow ball screw has a large effectiveness on restraining the thermal expansion of the ball screw. 3) The positioning accuracy of the ball screw was improved about 2~4$\mu$m using temperature -controlled cooling oil.

• Computers and Concrete
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• 제19권5호
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• pp.567-577
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• 2017

This study presents investigation of the behavior of moderately thick reinforced concrete slabs having hollow cores with different parameters. The experimental part of this investigation includes testing eight specimens of solid and hollow-core slab models having (2.05 m) length, (0.6 m) width and (25 cm) thickness under two monotonic line loads. Load versus deflection was recorded during test at mid span and under load. Numerically, the finite element method is used to study the behavior of these reinforced concrete slabs by using ANSYS computer program. The specimens of slab models are modeled by using (SOLID65) element to represent concrete slabs and (LINK180) element to represent the steel bars as discrete axial members between concrete nodes. The finite element analysis has showed good agreement with the experimental results with difference of (4.71%-8.68%) in ultimate loads. A parametric study have been carried out by using ANSYS program to investigate the effects of concrete compressive strength, size and shape of core, type of applied load and effect of removing top steel reinforcement.

• Bulletin of the Korean Chemical Society
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• 제35권12호
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• pp.3583-3589
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• 2014

This study evaluated a simple and useful route to the synthesis of mesoporous $TiO_2$ microcapsules with a hollow macro-core structure. A hydrophilic precursor sol containing the surfactants in the hydrophobic solvents was deposited on PMMA polymer surfaces modified by non-thermal plasma to produce mesoporous shells after calcination. The surface of the PMMA polymer spheres was coated with $NH_4F$ and CTAB to control the interfacial properties and promote the subsequent deposition of inorganic sols. These hollow type mesoporous $TiO_2$ microcapsules could be applied as an efficient substrate for the immobilization of DNA oligonucleotides.

• Tribology and Lubricants
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• 제25권3호
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• pp.171-175
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• 2009

One of the critical issues associated with the 40mm long hollow cylinder's development and maintenance is the prediction of cylinder erosion. The actual firing test is the most accurate method to measure the cylinder erosion rate. But it costs a great deal and requires a long measurement time. Hence many empirical methods have been proposed to predict the erosion rate and life span of long hollow cylinders. An EFC formula is calculated. An approximate erosion formula for the ammunition type A is derived to interpolate 16 observation values up to 4,000 rounds. A new erosion equation and muzzle velocity formula are also suggested. Several numerical results are presented.

• Structural Monitoring and Maintenance
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• 제6권4호
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• pp.269-289
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• 2019

This study investigated experimentally the response of thick reinforced concrete specimens having hollow cores with critical parameters. The investigation includes testing of twelve specimens that are solid and hollow-core slab models. Each specimen consists of two pieces, the piece dimensions are (1.2 m) length, (0.3 m) width and (20 cm) thickness tested under both monotonic and repeated loading. The test program is carried out to study the effects of load type, core diameters, core shape, number of cores, and steel fiber existence. Load versus deflection at mid span, failure modes, and crack patterns were obtained during the test. The test results showed that core shape and core number has remarkable influenced on cracking pattern, ultimate load, and failure mode. Also, when considering repeated loading protocol, the ultimate load capacity, load at yielding, and ductility is reduced.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제53권2호
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• pp.62-66
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• 2004

This paper investigated the characteristics of a newly developed high density hollow cathode plasma (HCP) system and its application for the etching of silicon wafers. We used SF$_{6}$ and $O_2$ gases in the HCP dry etch process. Silicon etch rate of $0.5\mu\textrm{m}$/min was achieved with $SF_6$$O_2$plasma conditions having a total gas pressure of 50mTorr, and RF power of 100 W. This paper presents surface etching characteristics on a crystalline silicon wafer and large area cast type multicrystlline silicon wafer. The results of this experiment can be used for various display systems such as thin film growth and etching for TFT-LCDs, emitter tip formations for FEDs, and bright plasma discharge for PDP applications.s.

• 한국수소및신에너지학회논문집
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• 제29권6호
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• pp.620-626
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• 2018

Recently, fuel cell field is receiving much attention as an environmentally friendly energy in the world. Among the various types of fuel cells, in the case of PEMFC, ions move through the membrane in the middle of the unit cell. Therefore, proper moisture is required inside the PEMFC. In the case of membrane type humidifier, flat membrane or hollow fiber membrane is mainly used. Since various parameters can change the performance, the performance investigation has to be carried out with parameters. In this study, water transport of hollow fiber membrane was investigated in terms of principle operating conditions such as temperature and flow rate.

• Structural Engineering and Mechanics
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• 제62권1호
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• pp.113-123
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• 2017

The bi-material elastic system consisting of the circular hollow cylinder and the infinite elastic medium surrounding this cylinder is considered and it is assumed that on the inner free face of the cylinder a point-located axisymmetric time harmonic force, with respect to the cylinder's axis and which is uniformly distributed in the circumferential direction, acts. The shear-spring type imperfect contact conditions on the interface between the constituents are satisfied. The mathematical formulation of the problem is made within the scope of the exact equations of linear elastodynamics. The focus is on the frequency-response of the interface normal and shear stresses and the influence of the problem parameters, such as the ratio of modulus of elasticity, the ratio of the cylinder thickness to the cylinder radius, and the shear-spring type parameter which characterizes the degree of the contact imperfectness, on these responses. Corresponding numerical results are presented and discussed. In particular, it is established that the character of the influence of the contact imperfection on the frequency response of the interface stresses depends on the values of the vibration frequency of the external forces.