• Title/Summary/Keyword: Hollow structure

Search Result 350, Processing Time 0.037 seconds

Facile Synthesis of Hollow CuO/MWCNT Composites by Infiltration-Reduction-Oxidation Method as High Performance Lithium-ion Battery Anodes

  • Zheng, Gang;Li, Zhiang;Lu, Jinhua;Zhang, Jinhua;Chen, Long;Yang, Maoping
    • Journal of Electrochemical Science and Technology
    • /
    • v.11 no.4
    • /
    • pp.399-405
    • /
    • 2020
  • Hollow copper oxide/multi-walled carbon nanotubes (CuO/MWCNT) composites were fabricated via an optimized infiltration-reduction-oxidation method, which is more facile and easy to control. The crystalline structure and morphology were characterized by X-ray diffraction (XRD), and transmission electron microscopy (TEM). The as-prepared CuO/MWCNT composites deliver an initial capacity of 612.3 mAh·g-1 and with 80% capacity retention (488.2 mAh·g-1) after 100 cycles at a current rate of 0.2 A·g-1. The enhanced electrochemical performance is ascribed to the better electrical conductivity of MWCNT, the hollow structure of CuO particles, and the flexible structure of the CuO/MWCNT composites.

Design of Blank Support Structure for Large and Curved Thick Plate Forming (대면적 후곡판 성형을 위한 블랭크 지지구조 설계)

  • Kwak, B.S.;Yoon, M.J.;Jeon, J.Y.;Kang, B.S.;Ku, T.W.
    • Transactions of Materials Processing
    • /
    • v.27 no.1
    • /
    • pp.18-27
    • /
    • 2018
  • As one of the functional metal parts in steam turbine diaphragm assembly, the hollow-partitioned turbine nozzle (stator) has large and thick geometries, as well as an asymmetric configuration. Therefore it is hard to support a metal blank in the die cavity. To ease this situation and control posture and position of metal blank (workpiece), a blank support structure is newly introduced. The blank support structure is basically composed of enlarged arms from the blank, guide pins and linear bearings. It can help to control the intermediate blank without a critical sliding phenomenon. The operation mechanism of this blank support structure, during thick plate forming for the hollow-partitioned turbine nozzle stator, is first evaluated. A series of FEM-based numerical simulations, with respect to the width of the guide arm as geometric design parameters, are carried out to investigate its applicable range. As the results, it is observed the blank support structure for this thick plate forming can guide the workpiece to have stable posture during the plate forming process.

Application of Hierarchical ZnCo2O4 Hollow Nanofibers for Anode Materials in Lithium-ion Batteries (계층적 구조를 갖는 중공형 ZnCo2O4 나노 섬유의 리튬이온배터리 음극소재 적용)

  • Jeong, Sun Young;Cho, Jung Sang
    • Korean Chemical Engineering Research
    • /
    • v.57 no.4
    • /
    • pp.559-564
    • /
    • 2019
  • Hierarchical $ZnCo_2O_4$ hollow nanofibers were prepared by electrospinning and subsequent heat-treatment process. The spinning solution containing polystyrene (PS) nanobeads was electrospun to nanofibers. During heat-treatment process, PS nanobeads in the composite were decomposed and therefore generated numerous pores uniformly in the structure, which facilitated the heat transfer and gas penetration into the structure. The resulting hierarchical $ZnCo_2O_4$ hollow nanofibers were applied as an anode material for lithium-ion batteries. The discharge capacity of the nanofibers was $815mA\;h\;g^{-1}$ ($646mA\;h\;cm^{-3}$) after the 300th cycle at a high current density of $1.0A\;g^{-1}$. However, $ZnCo_2O_4$ nanopowders showed the discharge capacity of $487mA\;h\;g^{-1}$ ($450mA\;h\;cm^{-3}$) after 300th cycle. The excellent lithium ion storage property of the hierarchical $ZnCo_2O_4$ hollow nanofibers was attributed to the synergetic effects of the hollow nanofiber structure and the $ZnCo_2O_4$ nanocrystals composing the shell. The hierarchical hollow nanofiber structure introduced in this study can be extended to various metal oxides for various applications, including energy storage.

Comparison of dyeing properties of nylon hollow fiber used for heat-insulating lightweight fabrics (보온경량성 직물용 나일론 중공사의 염색성 비교)

  • Zhang, Lianping;Chong, Ji-Won;Lee, Jae-Woong;Kim, Sam-Soo
    • Proceedings of the Korean Society of Dyers and Finishers Conference
    • /
    • 2008.04a
    • /
    • pp.156-158
    • /
    • 2008
  • Hollow fibers have been used in rather different fields of general textile use and in special-purpose products because of their unique structure. Hollow fibers have profitable properties for some applications because of their large surface/volume ratio. In this paper, dyeing properties of nylon hollow fiber were investigated. Nylon regular fiber and hollow fiber were used in the dyeing experiment. The samples were dyed with three kinds of acid dyes. Effects of dyeing temperature, pH of the dye bath, and dye concentration on dyeing properties were examined.

  • PDF

Fabrication of Polymeric Hollow Spheres Having Macropores by a Quenching and Sublimation Process

  • Im, Sang-Hyuk;Park, O-Ok;Kwon, Moo-Hyun
    • Macromolecular Research
    • /
    • v.11 no.6
    • /
    • pp.518-522
    • /
    • 2003
  • We fabricated polymeric hollow spheres having macropores, which combine the advantageous properties of porous materials and hollow spheres. To fabricate such spheres, a polystyrene/methylmethacrylate solution was dispersed in water by vigorously stirring and then the suspension was quenched using liquid nitrogen. Water and methyl methacrylate present in the quenched suspension were readily sublimated by freeze-drying. Conclusively, the hollow-sphere structure and the macropores of its shell were created by the processes of liquid nitrogen-quenching and sublimation of methyl methacrylate domains within the shell, respectively.

Development of a Plasma Gun System for Ion Plating with Long Lifetime (이온 플레이팅용 장수명 플라즈마 건 장치의 개발)

  • Choi, Young-Wook
    • The Transactions of The Korean Institute of Electrical Engineers
    • /
    • v.57 no.1
    • /
    • pp.78-81
    • /
    • 2008
  • A hollow cathode which has extremely stable discharge characteristic has been developed. This is composed of the two separated lanthanum hexaboride(LaB6) of a disk type in the tube as the electron emitters. The way of design is of great advantage to extend the surface discharge area of the LaB6, which is also useful for optimal fixing of the LaB6. The hollow cathode is capable of producing 30 kW(100 V, 300 A) of power continuously. Because the generated plasma beam with the high temperature(above $3000^{\circ}C$) from the hollow cathode passes through the center hole of the two intermediate electrodes, it is designed with the high temperature material of the tungsten and the suitable structure of the water cooling. The combinations of the hollow cathode and the two intermediate electrodes are practically useful for the ion plating plasma beam source.

An Analytic Study of Composite Hollow Core Slab Subjected with Box Type Beams (박스형 철골빔이 적용된 프리스트레스 할로우-코어 합성슬래브의 해석연구)

  • Hong, Sung-Gul;Seo, Do-Won
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2005.11a
    • /
    • pp.311-314
    • /
    • 2005
  • This research aims to analyze of prestressed composite hollow-core slab and box type steel beam. The smeared crack model used in abaqus for the modeling of hollow core reinforced concrete, including cracking of the concrete, rebar and concrete interaction using the tension stiffening concept, and rebar yield. The structure modeled is a simply supported hollow core spancrete slab subjected spa-h beams and prestressed in one direction. The hollow core spancrete slab is subjected to four-point bending. The concrete-rebar interaction that occur as the concrete begins to crack are of major importance in determining the spancrete slab's response between its initial, deformation and its collapse. This smeared crack model used in analysis involved non-liner concrete analysis concept.

  • PDF

Fabrication of Porous Alumina Ceramics Using Hollow Microspheres as the Pore-forming Agent

  • Nie, Zhengwei;Lin, Yuyi
    • Journal of the Korean Society of Manufacturing Technology Engineers
    • /
    • v.24 no.4
    • /
    • pp.368-373
    • /
    • 2015
  • Porous alumina ceramics with two different pore sizes were fabricated using hollow microspheres as the pore-forming agent. The relative density, total porosity, and microstructure of the obtained alumina ceramics were studied. It was found that the total porosity of sintered samples with different amounts of hollow microsphere content, from 2.0 to 4.0 wt%, was 69.3-75.6%. The interconnected and spherical cell morphology was obtained with 3.0 wt% hollow microsphere content. The resulting ceramics consist of a hierarchical structure with large-sized cells, and small-sized pores in the cell walls. Moreover, the compressive strength of the sintered samples varied from 8.3-11.5 MPa, corresponding to hollow microsphere contents of 2.0-4.0 wt%.

Effect of High-Temperature Spinning and PVP Additive on the Properties of PVDF Hollow Fiber Membranes for Microfiltration

  • Cha, Bong-Jun;Yang, Jung-Mok
    • Macromolecular Research
    • /
    • v.14 no.6
    • /
    • pp.596-602
    • /
    • 2006
  • The effect of high-temperature spinning and poly(vinyl pyrrolidone) (PVP) additive on poly(vinylidene fluoride) (PVDF) hollow fiber membranes was investigated using differential scanning calorimetry, X-ray diffraction measurement, and scanning electron microscopy, together with the corresponding microfiltration performances such as water flux, rejection rate, and elongational strength. Using high-temperature spinning, porous hollow fiber membranes with particulate morphology were prepared through PVDF crystallization. The particulate structure of the membranes was further modified by the addition of miscible PVP with PVDF. Due to these effects, the rejection rate and strength of the fibers were increased at the expense of reduced water flux and mean pore size, which indicates that high-temperature spinning and PVP addition are vary effective to control the morphology of PVDF hollow fiber membranes for microfiltration.

Preparation of PVDF/PEI double-layer composite hollow fiber membranes for enhancing tensile strength of PVDF membranes

  • Yuan, Jun-Gui;Shi, Bao-Li;Ji, Ling-Yun
    • Membrane and Water Treatment
    • /
    • v.5 no.2
    • /
    • pp.109-122
    • /
    • 2014
  • Polyvinylidene fluoride (PVDF) hollow fiber membrane is widely used for water treatment. However, the weak mechanical strength of PVDF limits its application. To enhance its tensile strength, a double-layer composite hollow fiber membrane, with PVDF and polyetherimide as the external and inner layers, respectively, was successfully prepared through phase inversion technique. The effects of additive content, air gap distance, N,N-dimethyl-acetamide content in the inner core liquid, and the temperature of external coagulation bath on the membrane structure, permeation flux, rejection, tensile strength, and porosity were determined. Experimental results showed that the optimum preparation conditions for the double-layer composite hollow fiber membrane were as follows: PEG-400 and PEG-600, 5 wt%; air gap distance, 10 cm; inner core liquid and the external coagulation bath should be water; and temperature of the external coagulation bath, 40 C. A single layer PVDF hollow fiber membrane (without PEI layer) was also prepared under optimum conditions. The double-layer composite membrane remarkably improved the tensile strength compared with the single-layer PVDF hollow fiber membrane. The permeation flux, rejection, and porosity were also slightly enhanced. High-tensile strength hollow fiber PVDF ultrafiltration membrane can be fabricated using the proposed technique.