• Title/Summary/Keyword: Hollow Particles

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Development of Adsorptive Permeation Membrane (APM) and Process for Separation of $CO_2$ from gas mixtures (이산화탄소 분리를 위한 흡착투과막 및 공정 개발)

  • Yeom, Choong Kyun;Ahn, Hyo Sung;Kang, Kyeong Rok;Kim, Joo Yul;Han, Jin-Soo;Kwon, Keun-Oh
    • Membrane Journal
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    • v.23 no.6
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    • pp.409-417
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    • 2013
  • Adsorptive permeation hollow fiber membrane (APM) has been developed for effectively separating $CO_2$ from gas mixture. Inside the APM, zeolite 13X particles were uniformly dispersed without covering their surfaces by a symmetric porous structure of polypropylene lattice. In this study, $CO_2/N_2$ mixture was used as a simulated gas mixture. Separation was achieved by adsorbing $CO_2$ on the zeolite particles in the APM and then permeating $N_2$ into permeate side in passing all the feed gas through the APM. Adsorptive permeation tests were carried out with a set of APM modules, and the adsorptive permeation performances of the modules were analyzed from the test results. After saturation of the adsorbent with $CO_2$, the APM was regenerated by desorption of $CO_2$ from it through vacuuming both inside of outside of the APM hollow fiber, and the regeneration process of the APM by vacuuming was discussed in terms of regeneration efficiency and energy consumption.

A Study on Properties of Domestic Fly Ash and Utilization as an Insulation material (국산 Fly Ash의 특성 및 단열재로의 이용에 관한 연구)

  • 박금철;임태영
    • Journal of the Korean Ceramic Society
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    • v.20 no.2
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    • pp.135-146
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    • 1983
  • This study is to investigate the properties of domestic fly ash for utilization as data in regard to fly ash which is by-product of domestic coal powder plants and the possibility of utilization as insulation material of domestic fly ash. Composition refractoriness size distribution density contents of hollow particles and crystalline phase were examined as the properties of domestic fly ash. As to the fired test pieces of fly ash by itself that varied contents of hollow particles with four kinds and of the fly ash-clay-saw dust system linear shrinkage bulk density app. porosity compressive strength thermal conductivity and structures were investigated for the possibility of utilization as an insulation material. The results are as follows : 1. The properties of the fly ash I) The constituent particle of the fly ash is spherical and it contains not a few hollow particles (floats by water 0.30-0.50 floats by $ZnCl_2$ aq.(SpG=1.71) 6.97-16.72%). ii) The chemical compositions of fly ash are $SiO_243.9-54.1%$ , $Al_2O_321.0-30.7%$ Ig loss is 7.4-24.1% and the principal of Ig loss is unburned carbon. iii) Fly ash was not suitable to use for mortar and concrete mixture because Ig. loss value is higher than 5% 2. Utilization as insulation material I) The test pieces of original fly ash floats by water floats by ZnCl2 aq(SpG=1.71) p, p t by ZnCl2 aq.(SpG=1.71) that were fired at 110$0^{\circ}C$ represented 0.11-0.18 kcal/mh$^{\circ}$ C as thermal conductivity value. ii) The test pieces which (76.5-85.5) wt% fly ash-(8.5, 9.5) wt% clay-(5.0-15.0) wt% saw dust system(68.0-72.0) wt% fly ash -(17.0-18.0)wt% clay-(10.0-15.0) wt% saw dust system and 59.5 wt% fly ash-25.5 wt% clay-15.0wt% saw dust system were fired at 110$0^{\circ}C$ the thermal conductivity was less than 0.1Kcal/mh$^{\circ}$ C. iii) In view of thermal conductivity and economic aspect insulation materials which added saw dust as blowing agent and clay as inorganic binder are better than that of fly ash as it is or separated hollow fly ash particles. iv) When the saw dust contents increased in the (59.5-90.0) wt% saw dust system and when amount of clay de-creased and firing temperature decreased under the condition of equal addition of saw dust app. porosity increased but bulk density compressive strength and thermal conductivity decreased.

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Facile Synthesis of Hollow CuO/MWCNT Composites by Infiltration-Reduction-Oxidation Method as High Performance Lithium-ion Battery Anodes

  • Zheng, Gang;Li, Zhiang;Lu, Jinhua;Zhang, Jinhua;Chen, Long;Yang, Maoping
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.399-405
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    • 2020
  • Hollow copper oxide/multi-walled carbon nanotubes (CuO/MWCNT) composites were fabricated via an optimized infiltration-reduction-oxidation method, which is more facile and easy to control. The crystalline structure and morphology were characterized by X-ray diffraction (XRD), and transmission electron microscopy (TEM). The as-prepared CuO/MWCNT composites deliver an initial capacity of 612.3 mAh·g-1 and with 80% capacity retention (488.2 mAh·g-1) after 100 cycles at a current rate of 0.2 A·g-1. The enhanced electrochemical performance is ascribed to the better electrical conductivity of MWCNT, the hollow structure of CuO particles, and the flexible structure of the CuO/MWCNT composites.

Separation of Colloidal Particles by Osmotic Sink Field Flow Fractionation Using UF Hollow Fiber Membranes

  • Shin, Se-Jong;Min, Byoung-Ryul;Park, Jin-Won;Ahh, Ik-Sung;Lee, Kang-Taek;Lee, Jae-Hoon
    • Korean Membrane Journal
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    • v.3 no.1
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    • pp.59-68
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    • 2001
  • Unlike existent field flow fractionation, new method, osmotic sink field flow fractionation is introduced and used ultrafiltration hollow fiber membranes as separation channel. This hollow fiber osmotic sink field flow fractionation is called HF-OSFFF. A theory that describes the retention, relaxation, resolution, plate number for the system, has been developed and experimentally verified by separation model of po1ystyrene latex beads. At external field, it is measured that radial flow rates change according to various concentrations of PEG solutions. Concentration of PEG solution vs. radial flow rate is a linear relation. For diameter distribution of unknown polymer sample, HF-OSFFF compared with the commercial capillary hydrodynamic flow fractionation (CHDF).

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Controlled Morphology of Particles Prepared by Electrospray Technique (전기분무법에 의해 제조되는 미립자의 형상 제어)

  • Nguyen, The Dung;Choi, Jin-hoon;Yoon, Ji-Ae;Kim, Kyo-Seon
    • Journal of Industrial Technology
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    • v.35
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    • pp.67-71
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    • 2015
  • Various structures of particles were prepared by electrospray technique. In this research, solid particles were formed by electrospraying a solution of ethanol containing polyvinyl and tetraethyl orthosilicate. During the electrospray process, the ethanol solvent was evaporated, resulting in the solidification of precursors, forming solid particles. Evaporation of ethanol solvent also enhanced the mass transport which facilitated the development of porous and hollow structures.

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Characteristics of Particles Structure of Delactosed Nonfat Dry Milk (탈유당 탈지분유의 입자구조 특성에 관한 연구)

  • 송재철;박현정;신완철
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.24 no.2
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    • pp.341-345
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    • 1995
  • In comparison with calcium caseinate, delactosed nonfat dry milk has a greater particle size but also a higher bulk density, reflecting the differences in their composition and physical structure. Particles of delactosed nonfat dry milk were bigger than those of nonfat dry milk as a result of swelling and aggregation. The particle size was shown not to be correlated with the bulk density. The differences in particle characteristics between delactosed nonfat dry milk and nonfat dry milk were caused by the removal of lactose producing highly porous particles. The particles of delactosed nonfat dry milk were observed to be much more irregular, rough, hollow, fragile, and swelling as a result of solvent treatment.

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A Study of Vibration Damping Control for Hollow Drive Shaft (자동차용 중공 구동축의 진동감쇠제어 연구)

  • Park, Jeong-Heon;Hong, Sung-Geun;Lee, Kwang-Hee;Lee, Chul-Hee;Kim, Cheol-Hyun;Cho, Won-Oh
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.22 no.6
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    • pp.582-587
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    • 2012
  • This paper presents a solution of the vibration reduction in the hollow shafts by using magentorehological( MR) elastomer. Proposed active damping structure is built by embedding the MR elastomers whose elastic modulus is controllable by an applied magnetic field. MR elastomers consist of synthetic rubber filled with micron-sized magnetizable particles. For reduction of vibration, dynamic damper of hollow shaft is designed by using MR elastomer and equipped in the hollow shaft for the application to drive shaft. Experiment results are shown through the experiments to confirm the effect of MR elastomer dynamic damper for vibration reduction. Thus, the designed damping structure can be applied to vibration absorber used in drive shafts as well as the propeller shafts.

Fabrication of Oxygen Sensitive Particles and Characteristic Analysis (산소감응성 입자 제조 및 특성 분석 연구)

  • Jeong, Won-Taek;Yi, Seung-Jae;Kim, Hyun-Dong;Kim, Kyung-Chun
    • Journal of the Korean Society of Visualization
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    • v.9 no.4
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    • pp.41-46
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    • 2011
  • Oxygen sensitive functional particles(OSParticle) were fabricated by three different methods for using the particles as oxygen sensors and PIV tracers. The used methods were a physical coating method, an ion-exchange method and a dispersion polymerization method. The physical coating method is dipping $SiO_2$ hollow particles into dye solution then drying. This method is very simple, but particles are not uniform in diameter and luminescence. The particles fabricated by the ion-exchange method have very uniform diameter and well doped. However, it can not be used in water since the particles are hydrophobic. In case of the dispersion polymerization method, the diameter of OSParticles is quite uniform. The diameter of OSParticles can be changed by controlling the quantity of AIBN (2,2'-azobis isobutyronitrile). For the purpose of dissolved oxygen concentration measurement in micro scale water flows, the dispersion polymerized OSParticles turn out to be the most superior functional particles. The luminescent intensity of OSParticles was tested with the variation of dissolved oxygen concentration in water samples. As a result, the luminescent intensity of OSParticles is monotonically decreased with increasing DO (Dissolved oxygen) concentration of water.

Fabrication of Porous Ceramics and Multi-layered Ceramics Containing Porous Layers; I. Pore Structure (다공성 세라믹스와 다공질층을 포함하는 적층체의 제조에 관한 연구;I. 기공구조)

  • 이해원;윤복규;송휴섭
    • Journal of the Korean Ceramic Society
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    • v.31 no.9
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    • pp.1044-1052
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    • 1994
  • Tape casting technique was successfully applied to produce porous ceramics and multi-layered ceramics containing porous layers, where spherical hollow polymer particles were introduced as pore precursors. In the presence of extreme differences in density and size between Al2O3 and pore precursor particles, hindered settling was effective in preventing segregation of component particles and packing behavior of mixed powders was improved through bimodal packing. There were two transitions in packing behavior of mixed powders. The first transition took place at 40~50 vol% pore precursor addition, where majority of pores changed from close to open pore state. The other transition occured at 60~70 vol% pore precursor addition, where pore precursor particles formed a continuous network structure.

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