• Journal of Korean Society of Environmental Engineers
• /
• v.27 no.12
• /
• pp.1270-1276
• /
• 2005

When gas/particle partitioning of PAHs in the atmosphere approached an equilibrium state, the slope of linear regression between gas/particle partitioning coefficient($logK_p$) and subcooled liquid vapour pressure($logP_L^O$) was -1. But it was alleged that the slope of equilibrium state might not be -1 in real atmospheric environment due to heterogeneous characteristics of particulate matter. In This study, it would be found if gas/particle partitioning of PAHs segregated with particle size in equilibrium state was based on the hypothesis mentioned above. We have calculated the slopes of $logK_p$ v.s. $logP_L^O$ after collecting 10 set samples which consisted of particulate and vaporous phases. The slope was close to -1 in equilibrium states. But despite of equilibrium state, all slopes segregated with particle size were not close to -1 and those were gentler with larger particle size. The difference of slopes in equilibrium states was almost against the assumption of gas/particle partitioning theory. When the gas/particle partitioning was due to adsorption, the desorption enthalpy was different in each particle size. When it was absorption, the activity coefficient was different. The difference of desorption enthalpy and activity coefficient in each particle size indicate the heterogeneous characteristics of the bulk particle. This may be the reason for slope variation with particle size even though in an equilibrium state.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.3 no.4
• /
• pp.76-90
• /
• 2000

The estimation of material cycle of pollutants is necessary for the environment management in coastal zone. Model for material budgets are useful tools to understand the phenomena of natural system and to provide an insight into the complex processes including physical, chemical and biological processes occuring in natural system. Budgets of fresh water, salt and nutrients were estimated in order to clarify the characteristics of seasonal material cycle in Keum river estuary. Inflow volumes of freshwater into system was approximately 1.014×10/sup 8/～12.565×10/sup 8/m³/month and discharge in Keum river has occupied 99.7% of total freshwater. Seasonal variations of freshwater volume in the system were found to be very high in the range of about 4 ～ 14 times due to rainfall in summer season. Existing water mass of freshwater in system calculated by salt budget was approximately 0.339×10/sup 8/～0.652×10/sup 8/m³. Mean residence time of freshwater was calculated to be about 1.6～10.0day, and exchange time was calculated to be about 2.2～11.9day. Mean residence time was short as 1.6day in summer due to precipitation, and long as 10.1day in winter due to a drought. Inflow masses of DIP and DIN were approximately 5.57～32.68ton/month and 234.93～2,373.39ton/month, respectively. Seasonal inflow mass of DIP was larger than the outflow mass except for summer season. Thus, we postulate that accumulation of DIP in the system will happen. Residence times of DIP and DIN were calculated to be 1.1～6.4day and 1.8～10.9day, respectively. The ratio of water residence time versus DIP, DIN residence time was calculated to be 0.39～2.31 times and 0.83～1.13 times, respectively.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.14 no.3
• /
• pp.184-191
• /
• 2011

Preliminary design of a mooring system for a floating wave energy converter(WEC) is performed. A mooring line is designed to consist of two parts; the one is a chain in heavy weight laid on the seabed and linked to an anchor on the seabed and the other is a light weight chain suspended at a floater. A high weight chain laid on the seabed can contribute to mitigate dynamic energy propagated from top oscillation and decrease anchor weight and volume. Through a low weight chain suspended between a floater and seabed the WEC's function to produce energy from wave can be affected in minimum by the motion of a chain. The static and dynamic analyses for the designed mooring system were carried out to evaluate WEC system's safety. The present study shows that the designed gravity anchor moves horizontally due to the tension exerted on the anchor in the severe ocean environmental condition. The present mooring system should be redesigned to satisfy the safety requirements. The present study will be useful to predict the safety of the mooring system under ocean environment.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.10 no.3
• /
• pp.219-228
• /
• 2012

A long-term R&D program for HLW disposal technology development was launched in 1997 in Korea and Korea Reference disposal System(KRS) for spent fuels had been developed. After then, a recycling process for PWR spent fuels to get the reusable material such as uranium or TRU and to reduce the volume of radioactive waste, called Pyro-process, is being developed. This Pyro-process produces several kinds of wastes including metal waste and ceramic waste. In this study, the characteristics of the waste from Pyro-process and the concepts of a disposal container for the wastes were described. Based on these concepts, thermal analyses were carried out to determine a layout of the disposal area of the ceramic wastes which was classified as a high level waste and to develop the disposal system called A-KRS. The location of the final repository for A-KRS is not determined yet, thus to review the potential repository domains, the possible layout in the geological characteristics of KURT facility site was proposed. These results will be used in developing a repository system design and in performing the safety assessment.

• Analytical Science and Technology
• /
• v.14 no.5
• /
• pp.442-450
• /
• 2001

In this study, we collected PM10(particulate matter less than $10{\mu}m$) by using a high volume air sampler from March 2000 to September 2000 to investigate the contamination level and the distribution characteristics of heavy metals in the ambient air in Ulsan area. Samples were pretreated by the microwave extraction methods, and heaby metals (Cr, Cu, Zn, Cd, Ni, As, and Pb) were quantified by using and ICP-MS system. The highest PM10 concentrations in the ambient air were $85.6{\mu}g/m^3$ and the aberage value was $37.1{\mu}g/m^3$. The maximum levels of each heavy metal were as follows: $2.5{\mu}g/m^3$ for Fe(Yeocheon-dong), $0.41{\mu}g/m^3$ for Zn(Nammok-2-dong), $0.061{\mu}g/m^3$ for Cd(Yeocheon-dong), $0.20{\mu}g/m^3$ for Pb(Yeocheon-dong), $0.037{\mu}g/m^3$ for Ni(Yeoncheon-dong), $0.88{\mu}g/m^3$ for Cu(Yaeum-dong), $0.042{\mu}g/m^3$ for Cr(Yaeum-dong), and $0.015{\mu}g/m^3$ for As(Onsan). Among concentration of heavy metals, Ni and Zn compounds were highly correlated with a correlation coefficient of 0.87 at Nammok-2-dong.

• Analytical Science and Technology
• /
• v.5 no.4
• /
• pp.389-399
• /
• 1992

Liquid Chromatographic behavior of Pd(II) in Isonitrosoethylacetoacetate lmine, $Pd(IEAA-NR)_2$ (R=H, $CH_3$, $C_2H_5$, $n-C_3H_7$, $C_6H_5-CH_2$, $n-C_4H_9$) chelates were investigated by reversed-phase HPLC on Micropak MCH-5 column using methanol/water as mobile phase. The optimum conditions for the separation of $Pd(IEAA-NR)_2$ chelates were examined with respect to the effect of the flow rate, sample solvent, mobile phase strength and column temperature. It wass found that metal chelates were properly eluted in an acceptable range of capacity factor value($0{\leq}log\;k^{\prime}{\leq}1$). The dependence of the logarithm of capacity factor(k') on the volume fraction of water in the binary mobile phase was examined. Also, the dependence of k' on the liquid-liquid extration distribution ratio($D_c$) in methanol-water/n-alkane extration system was investigated. Both kinds of dependence are linear, which susggests that the retention of the electroneutral metal chelate is largely due to the solvophobic effect. Standard adsorption enthalpy changes (${\Delta}H^{\circ}$) and standard adsorption entropy changes (${\Delta}S^{\circ}$) of Pd(II) Isonitrosoethylacetoacetate imine chelates on Micropak MCH-5 column were calculated by measuring capacity factor with changing temperature of the column.

• Analytical Science and Technology
• /
• v.7 no.3
• /
• pp.329-338
• /
• 1994

The retention behaviors of natural gas components were studied on a single column by gas chromatography. The dead time, $t_0$ was obtained by using extrapolation of homologous series to determine capacity factors. The plots of retention data for homologous series and carbon number at different temperatures were shown to converge into a single point, which point was determined as a dead time. The results of the effect of temperature on the column efficiency for n-butane exhibited the plate number, N incerased with temperature, but the resolution among the fast eluted components decreased. The adsorption enthalpy (${\Delta}H^0{_{ads}}$) for each component on 28% DC 200 stationary phase was determined, and in order to investigate the retention behaviors of natural gas components the regression analysis of log $t_R$, log k' and log ${\alpha}$ vs. van der Waals volume(Vw), molecular connectivity index(X) and hydrophobic fragmental constant(f) were carred out. Good correlation was found between log k' vs. Vw, and log k' vs. f. The correlations between the physical properties of natural gas and the physical parameters were investigated by the linear regression analysis. The relationships between Vw vs. molecular weight and heating value(${\Delta}H_{comb}$), X vs. boiling point, and f vs. molecular weight, boiling point and heating value exhibited the high correlation coefficient more than 0.99. Using the regression equation between the heating value of natural gas and Vw the predicted heating values from $C_6$ to $C_{10}$ showed good agreement with those reported in the literature within 0.2% relative error.

• Analytical Science and Technology
• /
• v.26 no.2
• /
• pp.125-134
• /
• 2013

This study was demonstrated to estimate the measurement uncertainty of 23 multiple-component amino acids from beef bone extract by high performance liquid chromatography (HPLC). The sources of measurement uncertainty (i.e. sample weight, final volume, standard weight, purity, standard solution, calibration curve, recovery and repeatability) in associated with the analysis of amino acids were evaluated. The estimation of uncertainty obtained on the GUM (Guide to the expression of uncertainty in measurement) and EURACHEM document with mathematical calculation and statistical analysis. The content of total amino acids from beef bone extract was 36.18 g/100 g and the expanded uncertainty by multiplying coverage factor (k, 2.05~2.36) was 3.81 g/100 g at a 95% confidence level. The major contributors to the measurement uncertainty were identified in the order of recovery and repeatability (25.2%), sample pretreatment (24.5%), calibration-curve (24.0%) and weight of the reference material (10.4%). Therefore, more careful experiments are required in these steps to reduce uncertainties of amino acids analysis with a better personal proficiency improvement.

• Journal of Bio-Environment Control
• /
• v.15 no.3
• /
• pp.244-249
• /
• 2006

This study examined the growth characteristics of broad-leaved container seedlings of Stewartia pseudocamellia, Tilia manshurica and Chionanthus retusus in relation to the raw material properties of the container medium in a green house for 4 months in order to develop optimum container medium for broad-leaved container seedlings. Among the container media used, the high level of the height growth and root collar diameter growth of broad-leaved container seedlings of Stewartia pseudocamellia, Tilia manshurica, Chionanthus retusus was found in the container media with relatively more cocopeat or peatmoss, and the dry matter production of the aerial part and the subterranean part. Also, concerning physiological characteristics, the photosynthetic rate of broad-leaved container seedlings increased in proportion to the volume of cocopeat and peatmoss in the container media. The effect of container media on the growth of broad-leaved container seedlings needs continuous study on the irrigation and fertilization programs along with the study on physiological characteristics including growth characteristics, biomass production and photosynthesis.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.12 no.2
• /
• pp.865-871
• /
• 2011

Presently, the location and direction information are certainly needed for the autonomous vehicle of the ship. Among them, the direction information is a essential elements to automatic steering system. And the gyro-compass, the magnetic-compass and the GPS compass are the sensor indicating the direction. The gyro-compasses are mainly used in the large-sized ship of the GMDSS(Global Maritime Distress & Safety System). The precision and the reliability of the gyro-compasses are excellent but big volume and high price are disadvantage. The magnetic-compass has relatively fine precision and inexpensive price. However, the disadvantage is in the influence by the magnetism object including the steel structure of a ship, and etc. In the case of the GPS compass, the true north is indicated according to the change of the location information but in case of the minimum number of satellites or stopping of a ship or exercise in the error range, the exact direction cannot be obtained. In this paper, the performance of the GPS compass was improved by using the least-square curve fitting method for the mutual trade off of the angle sensor. The algorithm which improves the precision of an azimuth by applying the weighted value according to the size of covariance error was proposed with GPS-compass and magnetic compass. The characteristic and the performance of the proposed algorithm were analyzed and verified through experimentation. The applicability of the proposed algorithm was shown through the experimental result.