• Journal of the Korean Magnetic Resonance Society
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• v.2 no.1
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• pp.66-83
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• 1998

Study on spin-rotation relaxation of nuclear spins located on a methyl group can reveal valuable dynamic information related to the internal rotation of methyl group itself. Toward this end we have measured methyl carbon-13 spin-rotation of methyl group itself. Toward this end we have measured methyl carbon-13 spin-rotational relaxation rate in toluene and 2-chloro-p-xylene over the temperature range of 179-363K. To interpret the temperature dependence of measured spin-rotational relaxation rate we have revised the temperature dependence of measured spin-rotational relaxation rate we have revised the expression derived thus far by other authors and reproduced experimental data on the basis of the newly derived expression. The results confirmed that our expression leads to better agreement with experimental data than the previous one over observed temperature range, especially at high temperature.

• Proceedings of the Korean Magnestics Society Conference
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• 2000.09a
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• pp.461-461
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• 2000

We have investigated electronic structuresof antiferromagnetic YBaCo_2O_5 using the local spin-density approximation (LSDA) + U method. The charge and orbital ordered insulating ground state is correctly obtained with the strong on-site Coulomb interaction. Co^{2+} and Co^{3+} ions are found to be in the high spin (HS) and intermediate spin (IS) state, respectively. The tetragonal to orthorhombic structural transition is responsible for the ordering phenomena and the spin states of Co ions. The large contribution of the orbital moment to the total magnetic moment indicates that the effect of the spin-orbit coupling is very important in YBaCo_2O_5.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.35 no.1
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• pp.58-65
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• 2022

The field of liquid crystal display (LCD) is constantly in the spotlight and the process of depositing an alignment layer in the LCD manufacturing process is very important to obtain excellent performance such as low-power driving and high-speed response to improve LCD performance. Therefore, research on liquid crystal (LC) alignment is being actively conducted. When manufacturing LCD, it is necessary to consider the effect of the alignment layer thickness as one of the factors affecting various LCD performances. In addition, previous studies confirmed the LC alignment characteristics correlate with the rotation speed in the spin coating process. Therefore, the electro-optical properties of the LCD were investigated by manufacturing a polyimide alignment layer by varying the rotation speed in the spin coating process in this study. It was confirmed that the thickness of the polyimide alignment layer was controlled according to the spin coating conditions. The average transmittances of anti-parallel LC cells at the spin coating speed of 2,500 rpm and 3,000 rpm are about 60%, which indicates that the LC cell has relatively higher performance. At the spin coating speed of 3,000 rpm, the voltage-transmittance curve of twisted nematic (TN) LC cell was below 1.5 V, which means that the TN LC cell operated at a low power. In addition, high-speed operating characteristics were confirmed with a response time of less than 30 ms. From these derived data, we confirmed that the ideal spin coating speed is 3,000 rpm. And these results provide an optimized polyimide alignment layer process when considering enhanced future LCD manufacturing.

• Bulletin of the Korean Chemical Society
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• v.24 no.7
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• pp.981-985
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• 2003

Fluorine-19 NMR solution measurements have been made for various phenyl-fluorinated iron porphyrin complexes. Large chemical shifts for phenyl fluorine signals of iron(III) and iron(II) are observed, and these signals are sensitive to electronic structure. The chemical shift differences in ortho-phenyl fluorine signals between high-spin ferric and low-spin ferric tetrakis(pentafluorophenyl)porphyrins are approximately 40 ppm, whereas the differences are approximately 7 ppm between high- and low-spin states of ferrous tetrakis(pentafluorophenyl)porphyrin complexes. Analysis of fluorine-19 isotropic shifts for the iron(III) tetrakis(pentafluorophenyl) porphyrin using fluorine-19 NMR indicates there is a sizable contact contribution at the ortho-phenyl fluorine ring position. Large phenyl fluorine-19 NMR chemical shift values, which are sensitive to the oxidation and spin states, can be utilized for identification of the solution electronic structures of iron(III) and iron(II) porphyrin complexes.

• Korean Journal of Cognitive Science
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• v.27 no.1
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• pp.129-157
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• 2016

This study investigates speech perception in noise (SPIN) in Korean. A new type of Korean SPIN test was developed by adopting a similar format to the English SPIN test. The predictability effects, noise effects and their interactions were examined in order to verify the previous findings based on English. The data from 14 Korean adults collected with this new type of Korean SPIN test confirmed the previous findings: first, the participants' overall performance was better in low noise conditions than in high noise conditions. Secondly, there was a tendency for highly predictable words to be more accurately perceived than less predictable words especially in high noise conditions. The results were interpreted in such a way that the listeners actively used both types of information: acoustic information and contextual information in speech perception. When the acoustic property of the speech sound was degraded with noise, the listeners took advantage of the linguistic contextual information in their processing of the speech sound. The findings of this study conform to those of the previous studies based on the English SPIN test. In addition, a possible effect of the frequency of target word was also found, calling for further investigation in this field of research in Korean. Implications of the results were also discussed. (Cyber Hankuk University of Foreign Studies)

• Journal of Sensor Science and Technology
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• v.30 no.6
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• pp.451-455
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• 2021

Porous copper bromide (CuBr) films are highly advantageous for detecting ammonia (NH₃). The fabrication of porous CuBr films requires complex high-temperature processes or multistep processes. Herein, we report the uncomplicated preparation of porous CuBr films by a spin-coating method and the films' excellent NH₃ sensing properties. The porous films were prepared by spin-coating 100, 150, and 200 mM CuBr solutions, and then dried in a vacuum oven for 2 h. All the films showed a high NH₃ response; in particular, the film prepared using a 100 mM CuBr solution showed an extremely high response (resistance ratio = 852) to 5 ppm NH₃. The film also showed fast response and recovery times, 272 s and 10 s respectively, even at room temperature. The outstanding NH₃ sensing characteristics were explained in relation to the porosity and thickness of the prepared films. The high-performance NH₃ sensors used in this study can be used for both indoor air quality and environmental monitoring applications.

• Journal of Sensor Science and Technology
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• v.23 no.6
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• pp.377-382
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• 2014

Detecting and segmenting diffuse targets in laser ranging data is a critical problem for tactical reconnaissance. In this study, we propose a new method that facilitates the characterization of diffuse irregularly shaped objects using "spin images," i.e., local 2D histograms of laser returns oriented in 3D space, and a clustering process. The proposed "cluster-based spin imaging" method resolves the problem of using standard spin images for diffuse targets and it eliminates much of the computational complexity that characterizes the production of conventional spin images. The direct processing of pre-segmented laser points, including internal points that penetrate through a diffuse object's topmost surfaces, avoids some of the requirements of the approach used at present for spin image generation, while it also greatly reduces the high computational time overheads incurred by searches to find correlated images. We employed 3D airborne range data over forested terrain to demonstrate the effectiveness of this method in discriminating the different geometric structures of individual tree clusters. Our experiments showed that cluster-based spin images have the potential to separate classes in terms of different ages and portions of tree crowns.

• Proceedings of the Korean Magnestics Society Conference
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• 2000.05a
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• pp.150-151
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• 2000

• Bulletin of the Korean Chemical Society
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• v.22 no.4
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• pp.413-416
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• 2001

• Proceedings of the Korean Magnestics Society Conference
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• 1999.10a
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• pp.104-105
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• 1999