• Title/Summary/Keyword: High-pressure hydrogen

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Numerical Evaluation of Flow Nature at the Downstream of a Ball Valve Used for Gas Pipelines with Valve Opening Rates (개도율에 따른 가스파이프라인용 볼 밸브 후류유동의 수치평가)

  • KIM, CHUL-KYU;LEE, SANG-MOON;JANG, CHOON-MAN
    • Journal of Hydrogen and New Energy
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    • v.29 no.4
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    • pp.370-377
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    • 2018
  • Ball valve has been widely used in the field of high-pressure gas pipeline as an important component because of its low flow resistance and good leakage performance. The present paper focuses on the flow nature at the downstream of the ball valve used for gas pipelines according to valve opening rates. Steady 3-D RANS equations, SC/Tetra, have been introduced to analyze the flow characteristics inside the ball valve. Numerical boundary conditions at the inlet and outlet of the valve system are imposed by mass flow-rate and pressure, respectively. Velocity distributions obtained by numerical simulation are compared with respect to the valve opening rates of 30, 50, and 70%. Cavity distributions, asymmetry flow velocity and the flow stabilization point at each opening rate are also compared. When the valve opening rates are 30 and 50%, the flow stabilization requires the sufficient length of 10D or more due to the influence of the recirculation flow at the downstream of the valve.

Numerical Study on the Production of Methane Hydrate by Depressurization Method (감압법을 이용한 메탄하이드레이트 생산에 대한 수치적 연구)

  • Kim, Jin-Hong;Chun, Won-Gee;Kim, Nam-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.519-523
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    • 2007
  • Gas(or methane) hydrates are solid solutions when water molecules are linked through hydrogen bonding and create host lattice cavities that can enclose a large variety of guest gas molecules. The natural gas hydrate crystal may exist at low temperature above the normal freezing point of water and high pressure greater than about 30 bars. A lot of quantities of natural gas hydrates exists in the earth and many production schemes are being studied. In the present investigation, depressurization method was considered to predict the production of gas and the simulation of the two phase flow - gas and water - in porous media is being carried out. The simulation show about the fluid flow in porous media have a variety of applications in industry. Results provide the appearance of gas and water production, the pressure profile, the saturation of gas/ water/ hydrates profiles and the location of the pressure front.

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Prediction of Hydrodynamic Behavior of Unsaturated Ground Due to Hydrogen Gas Leakage in a Low-depth Underground Hydrogen Storage Facility (저심도 지중 수소저장시설에서의 수소가스 누출에 따른 불포화 지반의 수리-역학적 거동 예측 연구)

  • Go, Gyu-Hyun;Jeon, Jun-Seo;Kim, YoungSeok;Kim, Hee Won;Choi, Hyun-Jun
    • Journal of the Korean Geotechnical Society
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    • v.38 no.11
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    • pp.107-118
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    • 2022
  • The social need for stable hydrogen storage technologies that respond to the increasing demand for hydrogen energy is increasing. Among them, underground hydrogen storage is recognized as the most economical and reasonable storage method because of its vast hydrogen storage capacity. In Korea, low-depth hydrogen storage using artificial protective structures is being considered. Further, establishing corresponding safety standards and ground stability evaluation is becoming essential. This study evaluated the hydro-mechanical behavior of the ground during a hydrogen gas leak from a low-depth underground hydrogen storage facility through the HM coupled analysis model. The predictive reliability of the simulation model was verified through benchmark experiments. A parameter study was performed using a metamodel to analyze the sensitivity of factors affecting the surface uplift caused by the upward infiltration of high-pressure hydrogen gas. Accordingly, it was confirmed that the elastic modulus of the ground was the largest. The simulation results are considered to be valuable primary data for evaluating the complex analysis of hydrogen gas explosions as well as hydrogen gas leaks in the future.

Toxicity Reduction and Improvement of Anticancer Activities from Rhodiola sachalinensis A. Bor by Ultra High Pressure Extracts Process (초고압 공정에 의한 홍경천의 독성 감소 및 항암활성 증진)

  • Kim, Cheol-Hee;Kwon, Min-Chul;Qadir, Syed Abdul;Hwang, Baik;Nam, Jong-Hyeon;Lee, Hyeon-Yong
    • Korean Journal of Medicinal Crop Science
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    • v.15 no.6
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    • pp.411-416
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    • 2007
  • This study was performed to investigate the reduction of toxicity and improvement of anticancer activities from R. sachalinensis by ultra high pressure extracts process. The cytotoxicity on human kidney cell (HEK293) and human lung cell (HEL299) was showed below 20.4% and 21.6% as compare to normal extracts in adding 1.0 $mg/m{\ell}$ concentration. This showed that toxic materials through ultra high pressure processing is broken or degraded. Because bond such as hydrogen bond, electrostatic bond, Van der waals bond, the hydrophobic bond, can be broken by high pressure. The anticancer activity was also increased in over 7% by high pressure processing in A549, AGS, MCF-7 and Hep3B cells. The result showed that extraction by high pressure have low cytotoxicity and high anticancer activity. So, the high pressure extraction technology can play an important role in eruption of new material with high biological activity.

A Numerical Modeling of the Temperature Dependence on Electrochemical Properties for Solid Oxide Electrolysis Cell(SOEC) (고체 산화물 수전해 시스템(SOEC)에서 전기화학적 특성의 온도 의존성에 대한 수치 모델링)

  • Han, Kyoung Ho;Jung, Jung Yul;Yoon, Do Young
    • Journal of Energy Engineering
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    • v.29 no.2
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    • pp.1-9
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    • 2020
  • In recent days, fuel cell has received attention from the world as an alternative power source to hydrocarbon used in automobile engines. With the industrial advances of fuel cell, There have been a lot of researches actively conducted to find a way of generating hydrogen. Among many hydrogen production methods, Solid Oxide Electrolysis Cell(SOEC) is not only a basic way but also environment-friendly method to produce hydrogen gas. Solid Oxide Electrolysis Cell has lower electrical energy demands and high thermal efficiency since it is possible to operate under high temperature and high pressure conditions. For these reasons, experimental researches as well as studies on numerical modeling for Solid Oxide Electrolysis Cell have been under way. However, studies on numerical modeling are relatively less enough than experimental accomplishments and have limited performance prediction, which mostly is considered as a result from inadequate effects of electrochemical properties by temperature and pressure. In this study, various experimental studies of commercial Membrane Electrode Assembly (MEA) composed of Ni-YSZ (40wt%, Ni-60 wt% YSZ)/8-YSZ (TOSOH, TZ8Y)/LSM (La0.9Sr0.1MnO3) was utilized for improving effectiveness of SOEC model. After numerically analyzing effects of electrochemical properties according to operating temperature, causing the largest deviation between experiments and simulation are that Charge Transfer Coefficient (CTC), exchange current density, diffusion coefficient, electrical conductivity in SOEC. Analyzing temperature effect on parameter used in overpotential model is conducted for modeling of SOEC. cross-validation method is adopted for application of various MEA and evaluating feasibility of model. As a result, the study confirm that the numerical model of SOEC based on structured process of effectiveness evaluation makes performance prediction better.

Simulating reactive distillation of HIx (HI-H2O-I2) system in Sulphur-Iodine cycle for hydrogen production

  • Mandal, Subhasis;Jana, Amiya K.
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.279-286
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    • 2020
  • In this article, we develop a reactive distillation (RD) column configuration for the production of hydrogen. This RD column is in the HI decomposition section of the sulphur - iodine (SI) thermochemical cycle, in which HI decomposition and H2 separation take place simultaneously. The section plays a major role in high hydrogen production efficiency (that depends on reaction conversion and separation efficiency) of the SI cycle. In the column simulation, the rigorous thermodynamic phase equilibrium and reaction kinetic model are used. The tuning parameters involved in phase equilibrium model are dependent on interactive components and system temperature. For kinetic model, parameter values are adopted from the Aspen flowsheet simulator. Interestingly, there is no side reaction (e.g., solvation reaction, electrolyte decomposition and polyiodide formation) considered aiming to make the proposed model simple that leads to a challenging prediction. The process parameters are determined on the basis of optimal hydrogen production as reflux ratio = 0.87, total number of stages = 19 and feeding point at 8th stage. With this, the column operates at a reasonably low pressure (i.e., 8 bar) and produces hydrogen in the distillate with a desired composition (H2 = 9.18 mol%, H2O = 88.27 mol% and HI = 2.54 mol%). Finally, the results are compared with other model simulations. It is observed that the proposed scheme leads to consume a reasonably low energy requirement of 327 MJ/kmol of H2.

Status of the Real-time Safety Monitoring System of Hydrogen Refueling Station According to the Operation (수소충전소 실시간 이중 모니터링 시스템 운영을 통한 안전성 향상)

  • Lee, Jin-Woo;Park, Jong-Hee;Kim, Dae-Hyun;Tak, Song-Su;Yang, Byung-Jo
    • Journal of the Korean Institute of Gas
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    • v.25 no.6
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    • pp.92-97
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    • 2021
  • In accordance with the revision of the Enforcement Regulations of the High-Pressure Gas Safety Management Act in February 2021, from August 27, 2021, the operation status of safety devices such as gas leak detection and alarm devices, emergency shut-off devices and flame detectors installed at hydrogen vehicle charging stations can be monitored in real time. It is transmitted and operated by the computer system managed by Korea Gas Safety Corporations. We intend to share the results of statistical analysis of abnormal signals that have occurred along with the results of the monitoring system construction so that they can be used for the safety management of hydrogen refueling stations, and to seek future safety management directions.

A Computational Study on DME HCCI Combustions Characteristics with Methanol Concentrations (DME HCCI 운전조건에서 Methanol 분율에 따른 HCCI엔진연소 특성에 관한 수치해석적 연구)

  • Lee, Hyowon;Lim, Ocktaeck;Park, Kyuyeol;Cho, Wonjun;Baek, Youngsoon
    • Journal of Hydrogen and New Energy
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    • v.25 no.1
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    • pp.79-86
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    • 2014
  • In Dimethyl Ether (DME) indirect production processes, DME have a reforming process to separate Methanol. DME has a high cetane number and Methanol has a high octane number. Each fuel has a different combustion characteristics and reactivity. So, this paper was investigated on the combustion characterisitics of DME and Methanol. Basically, Methanol has a effect of retarding ignition. However, Within 10% of total carbon mole number in DME, Methanol slightly changed the onset timing of Low Temperature Reaction (LTR) with increasing thermal-ignition preparation range. It means that controlling combustion phasing of DME can be possible without eliminated LTR. In case of IMEP, the ranges.

Firing Test of Core Engine for Pre-cooled Turbojet Engine

  • Taguchi, Hideyuki;Sato, Tetsuya;Kobayashi, Hiroaiki;Kojima, Takayuki;Fukiba, Katsuyoshi;Masaki, Daisaku;Okai, Keiichi;Fujita, Kazuhisa;Hongoh, Motoyuki;Sawai, Shujiro
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.115-121
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    • 2008
  • A core engine for pre-cooled turbojet engines is designed and its component performances are examined both by CFD analyses and experiments. The engine is designed for a flight demonstration of precooled turbojet engine cycle. The engine uses gas hydrogen as fuel. The external boundary including measurement devices is set within $23cm{\times}23cm$ of rectangular cross section, in order to install the engine downstream of the air intake. The rotation speed is 80000 rpm at design point. Mixed flow compressor is selected to attain high pressure ratio and small diameter by single stage. Reverse type main combustor is selected to reduce the engine diameter and the rotating shaft length. The temperature at main combustor is determined by the temperature limit of non-cooled turbine. High loading turbine is designed to attain high pressure ratio by single stage. The firing test of the core engine is conducted using components of small pre-cooled turbojet engine. Gas hydrogen is injected into the main burner and hot gas is generated to drive the turbine. Air flow rate of the compressor can be modulated by a variable geometry exhaust nozzle, which is connected downstream of the core engine. As a result, 75% rotation speed is attained without hazardous vibration and heat damage. Aerodynamic performances of both compressor and turbine are obtained and evaluated independently.

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석탄 합성가스로부터 효율적인 생물학적 수소 생산에 관한 연구

  • 강환구;전희진
    • KSBB Journal
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    • v.15 no.3
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    • pp.268-273
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    • 2000
  • A microbiological hydrogen production process was optimized. Anaerobic photosynthetic bacteria like Rhodospirillum rubrum which is known to produce hydrogen from carbon monoxide efficiently and remove sulfur was used. To evaluate the potenital of this microorganism the optimization of media fermentation condition light intensity and light requirement for CO conversionwas tried in batch cultures and the continuous fermenter was also applied for this process. The gas residence time on CO conversion was sought out to get high conversion of carbon monoxide to hydrogen. Through this study the possibility of microbial synthtics gas concersion process was proposed.

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