• Title/Summary/Keyword: High-pressure argon

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Formation Mechanism and Corrosion-Resistance of Magnesium Film by Physical Vapour Deposition Process (물리증착법에 의해 제작한 마그네슘 박막의 형성기구와 내식특성)

  • 이명훈
    • Journal of Advanced Marine Engineering and Technology
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    • v.18 no.2
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    • pp.54-63
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    • 1994
  • Mg thin films were prepared on SPCC(cold-rolled steel) substrates by vasuum evapoaration and ion-plating. The influence of argon gas pressure and substrates bias voltage on the crystal orientation and morphology of the film was determined by using X-ray diffraction and scanning electron micrography (SEM), respectively. And the effect of crystal orientation and morphology of the Mg thin films on corrosion behavior was estimated by measuring the anodic polarization curves in deaerated 3% NaCl solution. The crystal orientation of the Mg films deposited at high argon gas pressure exhibited a (002) preferred orientation, regardless of the substrate bias voltage. Film morphology changed from a columnar to a granular structure with the increase of argon gas pressure. The morphology of the films depended not only on argon gas pressure but also bias voltage ; i.e., the effect of increasing bias voltage was similar to that of decreasing argon gas pressure. The influences of argon gas pressure and bias voltage were explained by applying the adsorption inhibitor theory and the sputter theory. And also, this showed that the corrosion resistance of the Mg thin films can be changed by controlling the crystal orientaton and morphology.

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A Study on the Influence Coaxial Parallel Magnetic Field upon Plasma Jet (II) (Plasma Jet의 동축평행자계에 의한 영향에 관한 연구 2)

  • Choon Saing Jhoun
    • 전기의세계
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    • v.22 no.5
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    • pp.19-32
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    • 1973
  • This paper treats with some of plasma jet behaviors under magnetic field for the purpose of controlling important characteristics of plasma jet in the practices of material manufacturings. Under the existence and non-existence of magnetic field, the pressure distribution, flame length, stability and noise of plasma jet are comparatively evaluated in respect of such parameters as are current, gap of electrode, quantity of argon flow, magnetic flux density, diameter and length of nozzle. The results are as follows: 1) the pressure, the length and the noise of plasma jet rise gradually with the increase of are current, and have high values under identical arc current as the diameter of nozzle increases, but reverse phenomenon tends to appear in the noise. 2) The pressure, the flame length and the noise increase with the increased quantity of argon flow, and the rising slope of noise is particularly steep. Under magnetic field, the quantity of argon flow in respect of flame length has the critical value of 80(cfh). 3) The pressure and length of flame decrease with small gradient value as the length of gap increases, but the noise tends to grow according to the increase of nozzle diameter. 4) The pressure and the length of jet flame decrease inversly with the increase of magnetic flux density, which have one critical value in the 100 amps of arc current and two values in 50 amps. The pressure of jet flame can be below atomospher pressure in strong magnetic field. 5) "The constriction length of nozzle has respectively the critical value of 6(mm) for pressure and 23(mm) for the length of flame. 6) Fluctuations in the wave form of voltage become greater with the increase of argon flow and magnetic flux density, but tends to decrease as arc current increases, having the frequency range of 3-8KHz. The wave form of noise changes almost in parallel with that of voltage and its changing value increases with argon flow, arc current and magnetic flux density, having the freuqency range of 6-8KHz. The fluctuation of jet presurre is reduced with the increase of argon flow and magnetic flux density and grows with arc current.rent.

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Selection of working fluid for cryosurgical probe considering biological heat transfer

  • Hwang, Gyu-Wan;Jeong, Sang-Kwon
    • Progress in Superconductivity and Cryogenics
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    • v.9 no.4
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    • pp.46-49
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    • 2007
  • This paper describes the sensitive cooling performance change of J-T refrigerator for cryosurgical probe due to its working fluid. The analytical results of using 50 bar nitrous oxide are compared with the case of 300 bar argon. Bio-heat equation is numerically solved to investigate the effect of the probe temperature and the cooling power of the J-T refrigerator. The refrigerator using 50 bar nitrous oxide has larger cooling power above 185 K than the one with 300 bar argon, which enables fast cooling at early stage of cryosurgery, but the biological tissue away from the probe tends to be cooled slowly after the probe reaches its lowest operating temperature. When the repeated freeze-thaw cycle is employed for main tissue destruction mechanism, using high pressure nitrous oxide is more advantageous than argon if the freezing operation is within 2-3 minutes. The probe with high pressure argon is more suitable for the case of longer freeze-thaw cycle with fewer repetitions.

Luminance Properties of Argon Gas Using Inductively Coupled Plasma (유도 결합형 플라즈마를 이용한 아르곤 가스의 휘도 특성)

  • Lee, Young-Hwan;Her, In-Sung;Hwang, Myung-Keun;Choi, Yong-Sung;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1915-1917
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    • 2004
  • Inductively coupled plasma is commonly used for electrodeless lamp due to its ease of plasma generation. Optical characteristics significantly depend on the RF power and gas pressure of the plasma. This paper describes the measurement of luminance as a function of RF power and gas pressure with a goal of finding optimal operating conditions of the electrodeless lamp. The gas pressure was varied from 10 [mTorr] to 500 [mTorr] and the RF power was varied from 10 [W] to 200 [W]. It was found that the luminance tends to be decreased when argon pressure is increased, and the luminance is increased as RF power is increased. It was also found that the luminance per unit RF power is high when the argon pressure is low and when the RF power is in the range of 30 [W]${\sim}$40 [W].

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Luminance Efficacy of Inductively Coupled Argon Plasma (유도결합형 플라즈마에서의 아르곤 가스의 광 효율)

  • Lee, Young-Hwan;Pack, Kwang-Hyeon;Choi, Yong-Sung;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 2004.11a
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    • pp.299-301
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    • 2004
  • Inductively coupled plasma is commonly used for electrodeless lamp due to its ease of plasma generation. Optical characteristics significantly depend on the RF power and gas pressure of the plasma. This paper describes the measurement of luminous efficacy as a function of RF power and gas pressure with a goal of finding optimal operating conditions of the electrodeless lamp. The gas pressure was varied from 10 [mTorr] to 100 [mTorr] and the RF power was varied from 10 [W] to 120 [W]. It was found that the luminous flux tends to be decreased when argon pressure is increased, and the luminous flux is increased as RF fewer is increased. It was also found that the luminance efficacy is high when the argon pressure is low and when the RF power is low.

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Hydrogen Embrittlement of Two Austenitic High-Manganese Steels Using Tensile Testing under High-Pressure Gaseous Hydrogen (고압 수소 가스 하 인장 시험을 이용한 두 오스테나이트계 고망간강의 수소취화 특성 평가)

  • Lee, Seung-Yong;Baek, Un-Bong;Nam, Seung Hoon;Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.26 no.7
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    • pp.353-358
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    • 2016
  • The hydrogen embrittlement of two austenitic high-manganese steels was investigated using tensile testing under high-pressure gaseous hydrogen. The test results were compared with those of different kinds of austenitic alloys containing Ni, Mn, and N in terms of stress and ductility. It was found that the ultimate tensile stress and ductility were more remarkably decreased under high-pressure gaseous hydrogen than under high-pressure gaseous argon, unlike the yield stress. In the specimens tested under high-pressure gaseous hydrogen, transgranular fractures were usually observed together with intergranular cracking near the fracture surface, whereas in those samples tested under high-pressure gaseous argon, ductile fractures mostly occurred. The austenitic high-manganese steels showed a relatively lower resistance to hydrogen embrittlement than did those with larger amounts of Ni because the formation of deformation twins or microbands in austenitic high-manganese steels probably promoted planar slip, which is associated with localized deformation due to gaseous hydrogen.

PARAMETER STUDY ON PLASMA-POLYMERIZATION OF LANTHANIDE DIPHTHALOCYANINE FILMS FOR ELECTROCHEMICAL DEVICES

  • Kashiwazaki, Naoya;Yamana, Masao
    • Journal of the Korean institute of surface engineering
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    • v.29 no.6
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    • pp.739-744
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    • 1996
  • Lanthanide diphthalocyanines have interesting properties on electrochemical and chemical redox reactions. It is however, difficult to use because of thier short device life. Plasma-polymerization attends to improvement thier device life. Yb-diphthalocyanine ($YbPc_2$) polymer film was deposited in a parallel plate electrodes-type RF plasma reactor. $YbPc_2$ was sublimed into the argon plasma, and polymer film was obtained on a substrate. Radio frequency was constant of 13.56MHz. Pressure of argon gas, sublimation rate of $YbPc_2$ and RF power were variable parameters depending on film quality. Surface of polymer films include a lot of sub-micron order lumps. It was indicated that size of lumps depends on polymerization degree controled by parameters. Size of lumps and polymerization degree are increased with RF power. However, by the high RF power over 40W, polymerization degree is decreased with RF power and surface of film is rough. In condition of RF power is high, polymerization will compete with etching of film. We obtained good films for electrochromic display with RF power of 20W, argon gas pressure of 8.0 Pa and sublimationrate of $1.2 \times 10$ mol/min, and good films for gas sensor with RF power of 30W, argon gas pressure of 10.6Pa and sublimation rate of $1.2 \times 10$ mol/min.

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Luminescence Properties of Argon and Neon Gas Using an Inductively Coupled Plasma (유도결합형 Ar, Ne 가스에서의 플라즈마 발광 특성)

  • Her, In-Sung;Lee, Young-Hwan;Lee, Jong-Chan;Choi, Yong-Sung;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.220-223
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    • 2004
  • Inductively coupled plasma is commonly used for electrodeless lamp due to its ease of plasma generation. Optical characteristics significantly depend on the RF power and gas pressure of the plasma. This paper describes the measurement of luminance as a function of RF power and gas pressure with a goal of finding optimal operating conditions of the electrodeless lamp. The gas pressure was varied from 10[mTorr] to 300[mTorr] or 500[mTorr] and the RF power was varied from 10[W] to 200[W]. It was found that the luminance tends to be decreased when argon and neon pressure is increased, and the luminance is increased as RF power is increased. It was also found that the luminance per unit RF power is high when the argon and neon pressure is low and when the RF power is in the range of $30[W]{\sim}40[W]$ or 10[W].

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OPTIMAL SPUTTERING CONDITIONS FOR HIGH-DENSITY MAGNETIC RECORDING MEDIA BY FTS

  • Noda, Kohki;Kawanabe, Takashi;Naoe, Masahiko
    • Journal of the Korean institute of surface engineering
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    • v.29 no.6
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    • pp.824-828
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    • 1996
  • Co-based alloy thin films ddeposited by fcing targets sputtering(FTS) were investigated for use in high-density magnetic recording media to determine how their magnetic properties are dependent on the sputtering conditions, and thus to find appropriate parameters that allow the sputtering and thin films to meet the specificiations for magnetic properties. FTS can discharge at lower working gas pressure than other sputtering methods such as dcmagnetron sputteing because the plasma is sufficiently confined by a magnetic field applied perpendicular to both of the target planes, which results in plasma-free substrates. Co-Cr-Ta films were deposited by FTS on glass and silicon substrates at substrate temperature between room temperature and $350^{\circ}C$, and at argon gas pressure between 0.1 and 10mTorr. The films were also deposited on polyimide tapes at substrate temperature of $130^{\circ}C$ and argon gas pressure of 1 mTorr. The effective advantages of Ta as an additional element were investigated, using the same films on the tapes. As a result of the experiment, it was found that better magnetic properties were obtained in the ranges of higher temperature and lower argon gas pressure with background pressure in thr range of $1.5 \times 10^{-6}$ Torr. Ta addition at 2 to 4 atomic percent almost havled the Co-Cr grain sizes, indicating that Ta addition at an appropriate atomic percent is effective for improving the microstructure and characteristics of Co-Cr films.

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PAHs Formation Characteristics and Fullerenes $(C_{60},\;C_{70})$ Synthesis in a Low-Pressure $C_6H_6/Ar/O_2$ Flame (저압 $C_6H_6/Ar/O_2$ 화염에서 PAHs 생성 특성 및 플러렌$(C_{60},\;C_{70})$ 합성에 대한 연구)

  • Lee, G.W.;Kim, Y.W.;Hwang, J.;Jrung, J.;Choi, M.
    • Journal of the Korean Society of Combustion
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    • v.7 no.4
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    • pp.36-44
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    • 2002
  • Carbon molecules with closed-cage structures are called fullerenes $(C_{60},\;C_{70})$, whose applications include super-conductors, sensors, catalysts, optical and electronic device, polymer composites, and biological and medical materials. The synthesis of fullerenes has been recently studied with low-pressure benzene/argon/oxygen flames. The formation of fullerene is known as molecular weight growth processes of PAHs (polycyclic aromatic hydrocarbon). This study presents results of PAHs and fullerene measurements performed in a low-pressure benzene/argon/oxygen normal co-flow laminar diffusion flame. Through the central tube of the burner, benzene vapors carried by argon are injected. The benzene vapors are made in a temperature-controlled bubbler. The burner is located in a chamber, equipped with a sampling system for direct collection of condensable species from the flame, and exhausted to a vacuum pump. Samples of the condensable are analyzed by HPLC (High Performance Liquid Chromatography) to determine the yields of PAHs and fullerene. Also, we computed mole fraction of fullerene and PAHs in a nearly sooting low pressure premixed, one-dimensional benzene/argon/oxygen flame (equivalence ratio ${\Phi}=2.4$, pressure=5.33kPa). The object of computation was to investigate the formation mechanism of fullerenes and PAHs. The computations were performed with CHEMKIN/PREMIX. As a result of this study, fullerenes were synthesized in a low pressure (20torr) $C_6H_6/Ar/O_2$ flames and the highest concentration of fullerene was detected just above the visible surface of a flame.

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