• Title/Summary/Keyword: High-energy density

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수소발생반응에 대한 Pyrites 표면 촉매 성능 예측: 밀도 범함수 이론 계산 (Identification of a Universal Relation between a Thermodynamic Variable and Catalytic Activities of Pyrites toward Hydrogen Evolution Reaction: Density Functional Theory Calculations)

  • 강준희;황지민;한병찬
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2017년도 춘계학술대회 논문집
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    • pp.87.1-87.1
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    • 2017
  • High functional catalyst to efficiently produce clean and earth-abundant renewable fuels plays a key role in securing energy sustainability and environmental protection of our society. Hydrogen has been considered as one of the most promising energy carrier as represented by focused research works on developing catalysts for the hydrogen evolution reaction (HER) from the water hydrolysis over the last several decades. So far, however, the major catalysts are expensive transition metals. Here using first principles density functional theory (DFT) calculations we screen various pyrites for HER by identifying fundamental descriptor governing the catalytic activity. We enable to capture a strong linearity between experimentally measured exchange current density in HER and calculated adsorption energy of hydrogen atom in the pyrites. The correlation implies that there is an underlying design principle tuning the catalytic activity of HER.

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구조물 연결부의 질량부과 효과 : SEA실험 및 해석 결과 비교 (Added Mass Effect on Structural Junction: Comparison of SEA Experimental Results with Analysis)

  • 김관주;김정태;윤태중;박봉현
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2002년도 춘계학술대회논문집
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    • pp.359-364
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    • 2002
  • Statistical energy method is widely used for the prediction of vibrational and acoustical behavior of complex structures, such as ship building and automobile in mid-, high frequency ranges. However. in order to convince this SEA result, it is important to verify estimated SEA parameters, e. g. modal density, energy in each subsystem, damping loss factor, coupling loss factor. with possible other method. For modal density parameter, the experimental estimations via Experimental Modal Analysis are checked with those from finite element method for both beam- plate and plate-plate cans. Loss factors are calculated by Lyon's simple method for the two subsystem. finally. modal experiments are carried out by varying the mass added on the junction of two subsystem for the purpose of investigating the influence on the coupling loss factor's behavior.

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기계화학적 합금화된 나노 Fe-6.5Si 분말의 자기 펄스압에 의한 동적성형 (Dynamic Compaction of Mechanochemically Alloyed Fe-Si Nano Powders by Magnetic Pulsed Pressure)

  • 이근희;이창규;김흥회;윤종운;이기선
    • 한국분말재료학회지
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    • 제12권1호
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    • pp.24-29
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    • 2005
  • Nano Fe-6.5wt%Si powders have been synthesized by mechano-chemical process (MCP) for an application of soft magnetic core. Owing to hard and brittle characteristics of Fe-6.5Si nano powders having large surface area, it is very difficult to reach high density more than 70% of theoretical density (~7.4 g/$cm_3$) by cold compaction. To overcome such problem a magnetic pulsed compaction (MPC), which is one of dynamic compaction techniques, was applied. The green density was achieved about 78% (~5.8 g/$cm_3$) by MPC at room temperature.

High Energy Density for Drying of Coated Webs-Porous Burner Combustion a New Approach

  • Schneider, Heiko;Krieger, Reinhold
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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    • pp.205-208
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    • 2006
  • Existing gas fired burners work in the medium wave IR range at $1000^{\circ}C$ and an energy density of $200kW/m^{2}$. The patented porous burner technology reaches the short wave IR spectrum ($1450^{\circ}C$) and comes up to an energy density of $1000kW/m^{2}$. This technology is of great interest for various applications in paper industry. Speeding up existing coating lines can be realized without a major revamp of the line. Main characteristics of this new developed technology enable a better process control. In this paper the porous burner technology for paper industry is evaluated.

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액체수소의 Exergy를 이용한 연료전지 시스템의 성능향상 (The Performance Improvement of Fuel Cell System by using LH2 Exergy)

  • 박동필;정귀성;오병수
    • 한국수소및신에너지학회논문집
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    • 제12권3호
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    • pp.211-217
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    • 2001
  • From wood to coal and petroleum, mankind has used various fuel. Since using such fuel, mankind has developed power source of mechanism. We obtain numerous power from caloric force. Present energy supply is based on the fossil fuel. Fossil fuel has high energy density and is convenient for transportation and storage. Human being prepared countermeasure of energy economy, high energy efficiency and substitution energy for limits of fossil fuel. High energy efficiency among them is very important. This research will improve total output by physical exergy recovery of $LH_2$-fuel cell system.

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복합평판구조물의 고주파수 대역 유체/구조 연성 소음진동예측을 위한 에너지흐름유한요소해석 (Energy Flow Finite Element Analysis for High Frequency Acoustic and Vibrational Prediction of Complicated Plate Structures Considering Fluid-Structure Interaction)

  • 윤태흠;박영호
    • 대한조선학회논문집
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    • 제60권1호
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    • pp.20-30
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    • 2023
  • In this paper, the Energy Flow Finite Element Analysis (EFFEA) was performed to predict the acoustic and vibrational responses of complicated plate structures considering improved Fluid-Structure Interaction (FSI). For this, a new power transfer relationship was derived at the area junction where two different fluids are in contact on both sides of the plate. In order to increase the reliability of EFFEA of complicated plate structures immersed in a high-density fluid, the corrected flexural wavenumber and group velocity considering fluid-loading effect were derived. As the specific acoustic impedance of the fluid in contact with the plate increases, the flexural wavenumber of the plate increases. As a result, the flexural group velocity is reduced, and the spatial damping effect of the flexural energy density is increased. Additionally, for the EFFEA of arbitary-shaped built-up structures, the energy flow finite element formulation for the acoustic tetrahedral element was newly performed. Finally, for validation of the derived theory and developed software, numerical applications of complicated plate structures submerged in seawater or air were successfully performed.

에너지 저장장치를 갖는 고 전력밀도 및 저가격형 태양광 인버터 시스템 (High Power Density and Low Cost Photovoltaic Power Conditioning System with Energy Storage System)

  • 금문환;장두희;홍성수;한상규;사공석진
    • 전력전자학회논문지
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    • 제16권6호
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    • pp.587-593
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    • 2011
  • 본 논문에서는 고 전력밀도 및 저가형으로 구성 가능한 새로운 구조의 계통 연계형 태양광 인버터 시스템을 제안한다. 제안 시스템은 태양전지의 최대 전력점 추종기능과 배터리의 충 방전 기능을 단일 전력단으로 구성함으로써, 고 전력밀도 및 저가격형 시스템 구성이 가능하다. 또한, 제안 시스템은 배터리를 링크 캐패시터에 직렬 연결함으로써 링크 캐패시터의 전압 스트레스를 배터리 전압만큼 저감할 수 있으므로 가격저감 효과가 크다. 최종적으로 제안 시스템의 우수성과 신뢰성 검증을 위하여 1.5kW급 태양광 인버터 시스템의 시작품을 제작하였고, 이를 이용한 실험결과를 바탕으로 제안 시스템의 타당성을 검증한다.

Materials Properties of Nickel Electrodeposits as a Function of the Current Density, Duty Cycle, Temperature and pH

  • Kim, Dong-Jin;Kim, Myung Jin;Kim, Joung Soo;Kim, Hong Pyo
    • Corrosion Science and Technology
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    • 제5권5호
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    • pp.168-172
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    • 2006
  • Alloy 600 having a superior resistance to a corrosion is used as a steam generator tubing in nuclear power plants. In spite of its high corrosion resistance, there are many tubings which experience corrosion problems such as a SCC under the high temperature and high pressure environments of nuclear power plants. The Alloy 600 tubing can be repaired by using a Ni electroplating having an excellent SCC resistance. In order to carry out a successful Ni electrodeposition inside a steam generator tubing, the effects of various parameters on the material properties of the electrodeposit should be elucidated. Hence this work deals with the effects of an applied current density, duty cycle($T_{on}/(T_{on}+T_{off})$) of a pulse current, bath temperature and solution pH on the material properties of Ni electrodeposit obtained from a Ni sulphamate bath by analyzing the current efficiency, potentiodynamic curve, hardness and stress-strain curve. Hardness, YS(yield strength) and TS(tensile strength) decreased whereas the elongation increased as the applied current density increased. This was thought to be by a concentration depletion at the interface of the electrodeposit/solution, and a fractional decrease of the hydrogen reduction reaction. As the duty cycle increased, the hardness, YS and TS decreased while the elongation increased. During an off time at a high duty cycle, the concentration depletion could not be recovered sufficiently enough to induce a coarse grain sized electrodeposit. With an increase of the solution temperature and pH, the YS and TS increased while the elongation decreased. The experimental results of the hardness and the stress-strain curves can be supplemented by the results of the potentiodynamic curve.

연료전지 무인항공기의 고도와 체공시간에 대한 특성 분석 및 최신 연구동향 (Research Trend and Analysis of Altitude and Endurance for Fuel Cell Unmanned Aerial Vehicles)

  • 조성현;김민진;손영준;양태현
    • 한국수소및신에너지학회논문집
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    • 제25권4호
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    • pp.393-404
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    • 2014
  • Unmanned aerial vehicles (UAVs) have been applied to not only military missions like surveillance and reconnaissance but also commercial missions like meteorological observation, aerial photograph, communication relay, internet network build and disaster observation. Fuel cells make UAVs eco-friendly by using hydrogen. Proton exchange membrane fuel cells (PEMFCs) show low operation temperature, high efficiency, low noise and high energy density and those characterisitcs are well fitted with UAVs. Thus Fuel cell based UAVs have been actively developed in the world. Recently, fuel cell UAVs have started to develope for high altitude UAVs because target altitude of UAVs is expanded upto stratosphere altitude. Long endurance of UAVs is essential to improve effects of the missions. Improvement of UAV endurance time could be fulfilled by developing a hydrogen fuel storage system with high energy density and reducing the weight of UAVs. In this paper, research trend and analysis of fuel cell UAVs are introduced in terms of their altitude and endurance time and then the prospect of fuel cell UAVs are shown.

[ $(Th,U)O_2$ ] Pellets: Fabrication and Thermal Properties

  • Kang Ki Won;Yang Jae Ho;Kim Keon Sik;Song Kun Woo;Lee Chan Bock;Jung Youn Ho
    • Nuclear Engineering and Technology
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    • 제35권4호
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    • pp.299-308
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    • 2003
  • Fabrication technique of $(Th,U)O_2$ pellets has been investigated. Powder mixtures of $ThO_2\;and\;UO_2$ were milled in two different ways-dry and wet milling. Milled powder was compacted and sintered to $(Th,U)O_2$ pellets. The wet-milled powder leads to a $(Th,U)O_2$ pellet having a high sintered density and uniform distribution of U and Th, compared to the dry-milled powder. The sintered density of a $(Th,U)O_2$ pellet tends to decrease by increasing the content of $ThO_2$. The thermal conductivity of $ThO_2\;and\;(Th,U)O_2$ pellets was measured by the laser flash method. The thermal conductivity of the $ThO_2$ pellet is higher than that of the $UO_2$ pellet, and the thermal conductivities of $(Th,U)O_2$ pellets containing $65wt\%\;and\;35wt\%\;ThO_2$ pellets are lower than that of the $UO_2$ pellet.