• Title/Summary/Keyword: High-Temperature Superconductors

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Ceramics superconducting Energy Materials (세라믹 에너지 재료)

  • Lee, Sang-Heon
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1238-1239
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    • 2008
  • The high Tc supeconductor of ceramic oxides type was studied for finding its application field. The results reportaed in this paper on the stability of the ceramic superconductors and the resistance to ripening in the BCO liquid phase at elevated temperature opens a processing window for engineering the microstructure of large superconductor at the nanoscale level. The results suggest further that the introduction of highly efficient artifical pinning center to bulk ceramics superconductor.

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Effects of Preparation conditions of sintered GdBa$_2$Cu$_3$Ox on the microstructures and electrical properties (소결체 GdBa$_2$Cu$_3$Ox의 제조 조건이 미세구조 및 전기적 특성에 미치는 영향)

  • 김시열;임호빈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1988.10a
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    • pp.102-104
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    • 1988
  • GdBa$_2$Cu$_3$Ox superconductors were prepared by ceramic powder compacting method. X-ray powder diffraction patterns and SEM microphotographs were taken to analyze phase and microstructure, and electrical properties were investigated by 4-point probe method. The results show that the $N_2$atmosphere enhances the formation of high Tc(critical temperature) phase, but the Tc is independent of sintering conditions.

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Resonant Frequency Modulation of High Temperature Superconductors Subjected to Optical Pulse Energy and Temperature (광학 펄스 에너지와 온도 변화에 의한 고온 초전도체의 공명 진동수 변조)

  • Cho, Shin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.11
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    • pp.1061-1067
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    • 2005
  • The resonant frequency modulation of $YBa_2Cu_3O_{7-x}$ meander lines has been investigated as functions of optical pulse energy and temperature by using a network analyzer. The frequency-domain measurements are performed by controlling both the resonant frequency and the frequency width. The meander lines, configured in a microstrip geometry, are illuminated by optical pulses from an actively mode-locked Nd:YAG laser. The variation of the resonant frequency shows a quadratic dependence on the reduced optical pulse energy $P/P_c$, where $P_c$ is defined as the critical optical pulse energy at which resonance signal has disappeared. As for the dependence on temperature, the results are in good agreement with the previously reported data.

Synthesis of YBa2Cu3O7-y Powder using a Powder Reaction Method and Fabrication of the Bulk Superconductors (분말 반응법에 의한 YBa2Cu3O7-y 합성과 벌크 초전도체의 제조)

  • Jeon, Young Ju;Park, Seung Yeon;You, Byung Youn;Park, Soon-Dong;Kim, Chan-Joong
    • Journal of Powder Materials
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    • v.20 no.2
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    • pp.142-147
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    • 2013
  • $YBa_2Cu_3O_{7-y}$ (Y123) powders for the fabrication of bulk superconductors were synthesized by the powder reaction method using $Y_2O_3$ (99.9% purity), $BaCO_3$ (99.75%) and CuO (99.9%) powders. The raw powders were weighed to the cation ratio of Y:Ba:Cu=1:2:3, mixed and calcined at $880^{\circ}C-930^{\circ}C$ in air with intermediate repeated crushing steps. It was found that the formation of Y123 powder was more sensitive to reaction temperature than reaction time. The calcined Y123 powder and a mixture of (Y123 + 0.25 mole $Y_2O_3$ + 1 wt.% $CeO_2$, $Y_{1.5}Ba_2Cu_3O_x$ (Y1.5)) were used as raw powders for the fabrication of poly-grain or single grain superconductors. The superconducting transition temperature ($T_{c,onset}$) of the sintered Y123 sample was 91 K and the transition width was as large as 11 K, whereas the $T_{c,onset}$ of the melt-grown Y1.5 sample was 90.5 K and the transition width was 3.5 K. The critical current density ($J_c$) at 77 K and 0 T of the sintered Y123 was 700 $A/cm^2$, whereas the $J_c$ of the top-seeded melt growth (TSMG) processed Y1.5 sample was $3.2{\times}10^4\;A/cm^2$. The magnetic flux density (H) at 77 K of the TSMG-processed Y123 and Y1.5 sample showed the 0.53 kG and 2.45 kG, respectively, which are 15% and 71% of the applied magnetic field of 3.5 kG. The high H value of the TSMG-processed Y1.5 sample is attributed to the formation of the larger superconducting grain with fine Y211 dispersion.

Breakdown Properties of Cryogenic Coolant for Pancake Coil Type High $T_{c}$ Superconducting Equipment (Pancake coil형 고온초전도 기기의 응용을 위한 극저온 냉매의 절연파괴 특성)

  • 백승명;정종만;이진호;김상현
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2002.02a
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    • pp.185-188
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    • 2002
  • In the design of superconducting power equipments such as transformer, cable and fault current limit, knowledge of the dielectric behavior of both liquid and gaseous at very low temperatures is very importance. Especially, Electrical properties of liquid nitrogen($LN_{2}$) and gaseous nitrogen($GN_{2}$) have become of great interest again since the discovery of high temperature superconductors. However, many sources of $LN_{2}$and $GN_{2}$ problems in the test of pancake coil model arising form the deficiency of insulation data. Therefore, this paper describes the results of an experimental study on the ac breakdown voltage($V_{B}$) properties of $LN_2$ and Air under the electrode of simulated HTS pancake coil. The ac breakdown voltage of $GN_{2}$ have been measured by pancake coil-pancake coil gaps over the temperature range of 293 K to 77 K.

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Development of Bi-system High-$T_c$ Superconductor by PJL Method (PJL 법에 의한 Bi계 고온 초전도체의 개발)

  • Jung, Jin-In;Park, Yong-Pil;Lee, Joon-Ung
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.924-925
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    • 1999
  • Bi-system high-$T_c$ superconductors with the nominal composition $(Bi_{0.7}Pb_{0.3})_2-Sr_{2}Ca_{2}Cu_{3}O_{x}$ have been prepared by PJL method. The critical temperature (offset temperature) of the sample annealed for 13 hours in air was 102K. And the results of X-ray diffraction(XRD) patterns, scanning electron microscope (SEM) images and energy dispersive X-ray (EDX) spectra analyses, it was found that PJL method is so effective to reduce the heat treatment period.

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Electrical Properties of High Tc Superconductors Using the Pyrolysis Method for Renewed Electric Power Energy

  • Lee Sang-Heon
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.5
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    • pp.217-220
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    • 2005
  • We have fabricated a superconducting YBCO system according to the pyrolysis method and low pressure apparatus. In our experiment, the X-ray diffraction pattern of the non doped YBaCuO layer indicated that the superconductor contained only 90K phase crystal. The critical temperature and critical current density for a thick layer at $650^{\circ}C$ were Tc=90 K and $Jc=6{\times}10^{4}A/cm^2$ at 90K. In low pressure apparatus, the 90 K phase YBaCuO was grown at a lower temperature compared with the normal system. Tc and Jc at $650^{\circ}C$ were Tc = 90 K and $Jc=6{\times}10^{4}A/cm^2$ at 90K.

Cryogenic milling for the fabrication of high Jc MgB2 bulk superconductors

  • Kim, D.N.;Kang, M.O.;Jun, B.H.;Kim, C.J.;Park, H.W.
    • Progress in Superconductivity and Cryogenics
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    • v.19 no.2
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    • pp.19-24
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    • 2017
  • Cryogenic milling which is a combined process of low-temperature treatment and mechanical milling was applied to fabricate high critical current density $(J_c)MgB_2$ bulk superconductors. Liquid nitrogen was used as a coolant, and no solvent or lubricant was used. Spherical Mg ($6-12{\mu}m$, 99.9 % purity) and plate-like B powder (${\sim}1{\mu}m$, 97 % purity) were milled simultaneously for various time periods (0, 2, 4, 6 h) at a rotating speed of 500 rpm using $ZrO_2$ balls. The (Mg+2B) powders milled were pressed into pellets and heat-treated at $700^{\circ}C$ for 1 h in flowing argon. The use of cryomilled powders as raw materials promoted the formation reaction of superconducting $MgB_2$, reduced the grain size of $MgB_2$, and suppressed the formation of impurity MgO. The superconducting critical temperature ($T_c$) of $MgB_2$ was not influenced as the milling time (t) increased up to 6 h. Meanwhile, the critical current density ($J_c$) of $MgB_2$ increased significantly when t increased to 4 h. When t increased further to 6 h, however, $J_c$ decreased. The $J_c$ enhancement of $MgB_2$ by cryogenic milling is attributed to the formation of the fine grain $MgB_2$ and a suppression of the MgO formation.

Pseudogap behavior in interlayer tunneling spectroscopy in $Bi_{2}Sr_{2}CaCu_{2}O_{8+x}$

  • Bae Myung-Ho;Choi Jae-Hyun;Lee Hu-Jong
    • Progress in Superconductivity
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    • v.7 no.1
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    • pp.1-5
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    • 2005
  • A pseudogap in the normal-state quasiparticle density of states of $high-T_c$ superconductors has been revealed in many different kinds of experiments. The existence of the pseudogap and the superconducting gap, and the correlation between them has attracted considerable attention because they are believed to be a key to understanding the mechanism of the $high-T_c$ superconductivity. The interlayer tunneling spectroscopy, excluding the surface-dependent effect, is one of the most accurate means to examine the electron spectral characteristics both in the superconducting and the normal states. In this study, a new constant-temperature intrinsic tunneling spectroscopic technique, excluding the overheating effect using the in-situ temperature monitoring combined with the digital proportional-integral-derivative control, is introduced. The implication on the $high-T_c$ superconductivity of the detailed temperature dependencies of the observed spectral weight in $Bi_{2}Sr_{2}CaCu_{2}O_{8+x}\;high-T_c$ material for overdoped and underdoped levels is discussed.

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Anisotropic superconductivity of high quality FeSe1-x Single crystal

  • Kwon, Chang Il;Ok, Jong Mok;Kim, Jun Sung
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.4
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    • pp.26-30
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    • 2014
  • We investigate the upper critical field anisotropy ${\Gamma}_H$ and the magnetic penetration depth anisotropy ${\Gamma}_{\lambda}$ of a high-quality $FeSe_{1-x}$ single crystal using angular dependent resistivity and torque magnetometry up to 14 T. High quality single crystals of $FeSe_{1-x}$ were successfully grown using $KCl-AlCl_3$ flux method, which shows a sharp superconducting transition at $T_C{\sim}9K$ and a high residual resistivity ratio of ~ 25. We found that the anisotropy ${\Gamma}_H$ near $T_C$ is a factor of two larger than found in the poor-quality crystals, indicating anisotropic 3D superconductivity of $FeSe_{1-x}$. Similar to the 1111-type Fe pnictides, the anisotropies ${\Gamma}_{\lambda}$ and ${\Gamma}_H$ show distinct temperature dependence; ${\Gamma}_H$ decreases but ${\Gamma}_{\lambda}$ increases with lowering temperature. These behaviors can be attributed to multi-band superconductivity, but different from the case of $MgB_2$. Our findings suggest that the opposite temperature dependence of ${\Gamma}_{\lambda}$ and ${\Gamma}_H$ is the common properties of Fe-based superconductors.