• Title/Summary/Keyword: High-Temperature Degradation

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Biodegradable PLA-based Biocomposites with Spent Coffee Grounds as Degradation Accelerator: Hydrolytic Degradation and Characterization Research

  • Kim, Youngsan;Lim, Daekyu;Kwon, Sangwoo;Jang, Hyunho;Park, Su-il
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.2
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    • pp.89-95
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    • 2022
  • The goal of this study was to evaluate the effect of spent coffee grounds (SCG) biofiller on the morphological, thermal, mechanical and hydrolytic degradation characteristics of poly(lactic acid) (PLA) based biocomposites. The PLA-based biocomposite films were fabricated by using a high-viscosity kneading and hot-pressing machine. The PLA/SCG biocomposites were analyzed with SEM, DSC, TGA, UTM and hydrolytic degradation test. Aggregation in the PLA matrix is a result of increasing SCG concentrations. In the thermal properties, it was described that the cold crystallization temperature (Tcc) decreased as SCG was added to PLA. When SCG was incorporated to PLA, the degradation onset temperature (Tonset) revealed a diminish. The elastic modulus increased while tensile strength of PLA diminished as SCG was applied. Through hydrolysis analysis, the decomposition of PLA was accelerated with the addition of SCG. This research confirmed the possibility of devloping an eco-friendly packaging material with high degradability as SCG hasten the breakdown of PLA.

Evaluation of the Ductile-Brittle Transition Behavior of fracture Toughness by Material Degradation (열화에 따른 파괴인성치의 연성-취성 천이거동 평가)

  • 석창성;김형익;김상필
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.5
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    • pp.140-147
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    • 2003
  • As the huge energy transfer systems like as nuclear power plant and steam power plant are operated for a long time at a high temperature, mechanical properties are changed and ductile-brittle transition temperature is raised by degradation. So it is required to estimate degradation in order to assess the safety, remaining life and further operation parameters. The sub-sized specimen test method using surveillance specimen was developed for evaluating the integrity of metallic components. In this study, we would like to present the evaluation technique of the ductile-brittle transition temperature by the sub-sized specimen test. The four classes of the thermally aged 1Cr-1Mo-0.25V specimens were prepared using an artificially accelerated aging method. The tensile test and fracture toughness test were performed. The results of the fracture toughness tests using the sub-sized specimens were compared with the evaluation technique of the ductile-brittle transition temperature.

Material Properties Degradation of Composite Body Panel Exposed to High Temperature (복합재료 Body Panel의 고온열화 특성)

  • Pyun, Hyun-Joong;Nam, Hyun-Wook;Han, Kyung-Seop
    • Proceedings of the KSME Conference
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    • 2000.11a
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    • pp.219-224
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    • 2000
  • A research for development of composite body panel is in progress for lightening tare. Low specific weight LPMC (Low pressure molding compound) has advantages such as lightweight and resistance to dent and corrosion. In this study, tensile, bending and impact tests for the LPMC and SPRC35 (High tension steel plate) were carried out and compared. Although mechanical properties of SPRC35 are better than the LPMC, the LPMC satisfies basic requirements for car body panel. The high temperature exposed LPMC were degraded due to fiber-matrix debonding and deterioration of resin.

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A Study of Upgrading Wax Oil Obtained from Pyrolysis of Mixed Plastic Waste with Film Type - The Influence of Catalyst Amount and Reaction Temperature (필름형 혼합폐플라스틱의 열분해로부터 얻은 왁스오일의 고급화연구 - 촉매 양과 반응온도의 영향 -)

  • Lee, Kyong-Hwan;Song, Kwang-Sup;Nam, Ki-Yun
    • New & Renewable Energy
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    • v.5 no.4
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    • pp.52-58
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    • 2009
  • Upgrading of pyrolysis wax oil using HZSM-5 catalyst has been conducted in a continuous fixed bed reactor at $450^{\circ}C$, 1hour, LHSV 3.5/h. The catalytic degradation was studied with a function of catalyst amount and reaction temperature. The raw pyrolysis wax oil shows relatively high boiling point distribution ranging from around $300^{\circ}C$ to $550^{\circ}C$, which has considerably higher boiling point distribution than that of commercial diesel. The catalytic degradation using HZSM-5 catalyst shows the high conversion of pyrolysis wax oil to light hydrocarbons. The liquid product obtained shows high gasoline range fraction as around 90% fraction and considerably high aromatic fraction in liquid product. Here, the experimental variable such as catalyst amount and reaction temperature was influenced on the product distribution.

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Pixel Circuit with High Immunity to the Degradation of TFTs and OLED for AMOLED Displays

  • Lin, Chih-Lung;Tu, Chun-Da
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.473-476
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    • 2008
  • A simple voltage compensation pixel circuit for AMOLED is produced using low temperature polycrystalline silicon (LTPS) technology. Its operation is verified by AIM-SPICE. Simulation results show that the pixel circuit has high immunity to variation of LTPS-TFT and reduces the drop in luminance due to the degradation of the OLED.

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Operating Method to Maximize Life Time of 5 kW High Temperature Polymer Exchange Membrane Fuel Cell Stack (5 kW 고온 고분자연료전지 스택 수명 극대화를 위한 운전 방법론)

  • KIM, JIHUN;KIM, MINJIN;SOHN, YOUNG-JUN;YU, SANGSEOK
    • Journal of Hydrogen and New Energy
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    • v.27 no.2
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    • pp.144-154
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    • 2016
  • HT-PEMFC (high temperature polymer electrolyte membrane fuel cell) using PA (phosphoric acid) doped PBI (polybenzimidazole) membrane has been researched for extending the lifetime. However, the existing work on durability of HT-PEMFC focuses on identifying degradation causes of lab scale. The short life time of HT-PEMFC is still the problem for its commercialization. In this paper, an operating method to maximize life time of 5kW HT-PEMFC stack are proposed. The proposed method includes major steps such as minimization of OCV (Open Circuit Voltage) exposure, control of the proper stack temperature, and N2 purging for the stack. This long life operating method was based on the fragmentary results of degradation from previous research works. Experimentally, the 5 kW homemade HT-PEMFC stack was operated for a long time based on the proposed method and the stack successfully can operate within the desired degradation rate for the target life time.

Analysis of Thermal Degradation Mechanism by Infrared High-speed Heating of CF-PEKK Composites in Hot Press Forming (핫프레스 공정 기반 CF-PEKK 복합재의 근적외선 고속가열에 의한 열적 열화 반응의 메커니즘 분석)

  • Lee, Kyo-Moon;Park, Soo-Jeong;Park, Ye-Rim;Park, Seong-Jae;Kim, Yun-Hae
    • Composites Research
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    • v.35 no.2
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    • pp.93-97
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    • 2022
  • The application of infrared heating in the hot press forming of the thermoplastic composites is conducive to productivity with high-speed heating. However, high energy, high forming temperature, and high-speed heating derived from infrared heating can cause material degradation and deteriorate properties such as re-melting performance. Therefore, this study was conducted to optimize the process conditions of the hot press forming suitable for carbon fiber reinforced polyetherketoneketone(CF/PEKK) composites that are actively researched and developed as high-performance aviation materials. Specifically, the degradation mechanisms and properties that may occur in infrared high-speed heating were evaluated through morphological and thermal characteristics analysis and mechanical performance tests. The degradation mechanism was analyzed through morphological investigation of the crystal structure of PEKK. As a result, the size of the spherulite decreased as the degradation progressed, and finally, the spherulite disappeared. In thermal characteristics, the melting temperature, crystallization temperature and heat of crystallization tend to decrease as degradation progresses, and the crystal structure disappeared under long-term exposure at 460℃. In addition, the low bonding strength was observed on the degraded surface, and the bonding surfaces of PEKK did not melt intermittently. In conclusion, it was confirmed that the CF/PEKK composite material degraded at 420℃ in the infrared high-speed heating. Furthermore, the spherulite experienced morphological changes and the re-melting properties of thermoplastic materials were degraded.

Load Current and Temperature Measurement for Measuring the Insulation Resistance of the 6.6 kV Cable (6.6 kV 케이블의 절연저항 측정을 위한 부하전류 및 온도 측정)

  • Park, Yong-Kyu;Cho, Young-Seek;Lee, Kwan-Woo;Um, Kee-Hong;Park, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.1
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    • pp.46-50
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    • 2015
  • The cable degradation process is largely divided into three steps; Step 1 : Thermal degradation, Step 2 : Weibull degradation, Step 3 : Partial discharge. it is progress in step order. This article aims to explain the process of cable degradation using the method of insulation resistance and accordingly to compose and manufacture a system of measuring the life of electrical cable. Before measuring the insulation resistance, a system of measuring the temperature and current of cables was made, and the established system was installed for test on the site of a power plant to collect the measured data. The current sensor was used TFC30P80A-CL420, and temperature sensor was used the DK-1270 PT100 sensor as RTD sensor. When measured the temperature and the load current at the same position, was confirmed that in case of the load current value was high, also temperature value high. Therefore, the correlation between load currents and temperature was verified, and the analysis of diagnostic data was evaluated, which could be utilized in identifying the fault condition of cable systems.

Inter-lamina Shear Strength of MWNT-reinforced Thin-Ply CFRP under LEO Space Environment

  • Moon, Jin Bum;Kim, Chun-Gon
    • Composites Research
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    • v.30 no.1
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    • pp.7-14
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    • 2017
  • In this paper, the inter-lamina shear strength (ILSS) of multi-wall carbon nanotube (MWNT) reinforced carbon fiber reinforced plastics (CFRP) and thin-ply composites were verified under low earth orbit (LEO) space environment. CFRP, MWNT reinforced CFRP, thin-ply CFRP and MWNT reinforced thin-ply CFRP were tested after aging by using accelerated ground simulation equipment. The used ground simulation equipment can simulate high vacuum ($2.5{\times}10^{-6}torr$), atomic oxygen (AO, $9.15{\times}10^{14}atoms/cm^2{\cdot}s$), ultraviolet light (UV, 200 nm wave length) and thermal cycling ($-70{\sim}100^{\circ}C$) simultaneously. The duration of aging experiment was twenty hours, which is an equivalent duration to that of STS-4 space shuttle condition. After the aging experiment, ILSS were measured at room temperature ($27^{\circ}C$), high temperature ($100^{\circ}C$) and low temperature ($-100^{\circ}C$) to verify the effect of operation temperature. The MWNT and thin-ply shows good improvement of ILSS at ground condition especially with the thin-ply. And after LEO exposure large degradation of ILSS was observed at MWNT added composite due to the thermal cycle. And the degradation rate was much higher under the high temperature condition. But, at the low temperature condition, the ILSS was largely recovered due to the matrix toughening effect.

Consideration of Electrical Properties in Field-aged Photovoltaic Module (태양전지모듈의 노화현상에 따른 전기적 특성 고찰)

  • Kang, Gi-Hwan;Yu, Gwon-Jong;Ahn, HyungKeun;Han, Deuk-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.12
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    • pp.1289-1295
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    • 2004
  • In this paper, degradation in field-aged PV modules including degradation of interconnect, discoloration of encapsulant and hot spot have been observed and analyzed. From the results, photovoltaic module installed for 6 years shows around 16 % drop of electrical properties due to the interconnect degradation and PV module passed 18 years has been found to drop of around 20 % mainly by the encapsulant discoloration. Furthermore the difference between low and high temperature of PV array at hot spot goes up to 3$0^{\circ}C$ and it leads to interconnect degradation. On the other hands, the temperature difference was observed to be around 15$^{\circ}C$ at the encapsulant discoloration spot of PV array.