• Title/Summary/Keyword: High-$T_{c}$

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Comparative study on Corrosion Inhibition of Vietnam Orange Peel Essential Oil with Urotropine and Insight of Corrosion Inhibition Mechanism for Mild Steel in Hydrochloric Solution

  • Bui, Huyen T.T.;Dang, Trung-Dung;Le, Hang T.T.;Hoang, Thuy T.B.
    • Journal of Electrochemical Science and Technology
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    • v.10 no.1
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    • pp.69-81
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    • 2019
  • The corrosion inhibiting mechanism of Vietnam orange peel essential oil (OPEO) for mild steel in 1 N HCl solution was investigated elaborately. Corrosion inhibition ability of OPEO was characterized by electrochemical polarization, electrochemical impedance spectroscopy (EIS), and weight loss method. In the corrosive solution, OPEO worked as a mixed inhibitor and the inhibition efficiency of OPEO increased with the increase of its concentration. High inhibition efficiencies over 90% were achieved for the concentration of 3 - 4 g/L OPEO, comparable to that of 3.5 g/L urotropine (URO), a commercial corrosion inhibitor for acid media used in industry. By using adsorption isotherm models (Langmuir, Temkin and Frumkin), thermodynamic parameters of adsorption were calculated. The obtained results indicated physical adsorption mechanism of OPEO on the steel surface. The components responsible for the corrosion inhibition activity of OPEO were not only D-limonene, but also other compounds, which contain C=O, C=C, O-H, C-O-C, -C=CH and C-H bonding groups in the molecules.

The Fabrication of PVA Polymer Coated on the Surface of B4C Nanocomposite by High Energy Ball Mill (고에너지볼밀을 이용한 PVA 고분자가 표면 코팅된 B4C 나노복합재 제조)

  • Uhm, Young-Rang;Kim, Jae-Woo;Jung, Jin-Woo;Rhee, Chang-Kyu
    • Journal of Powder Materials
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    • v.16 no.2
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    • pp.110-114
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    • 2009
  • Mechanical coating process was applied to form 89 %-hydrolyzed poly vinyl alcohol (PVA) onto boron carbide ($B_4C$) nanopowder using one step high energy ball mill method. The polymer layer coated on the surface of B4C was changed to glass-like phase. The average particle size of core/shell structured $B_4C$/PVA was about 50 nm. The core/shell structured $B_4C$/PVA was formed by dry milling. However, the hydrolyzed PVA of $98{\sim}99%$ with high glass transition temperature ($T_g$) was rarely coated on the powder. The $T_g$ of polymer materials was one of keys for guest polymer coating on to the host powder by solvent free milling.

Bi2Sr2CaCu2O8+d Thin Films Grown on (100) MgO Substrate by Metallorganic Decomposition Method (MOD 방법을 이용한 Bi2Sr2CaCu2O8+d 박막제작)

  • ;;;;Takayuki Ishibashi;Katsuaki Sato
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.11
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    • pp.1035-1040
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    • 2003
  • High $T_{c}$ superconducting B $i_2$S $r_2$CaC $u_2$ $O_{8+d}$ (BSCCO2212) films were prepared by a metallorganic decomposition (MOD) method. The metal organic solution of BSCCO2212 was spin-coated on MgO (100) substrates at 3000 rpm for 1 min. To achieve a high critical current density, we controlled heat-treatment conditions and atmosphere. The films were annealed at temperature 75$0^{\circ}C$ ∼ 80$0^{\circ}C$ in $O_2$ or air. We obtained c-axis orientated BSCCO thin films on MgO substrates. The annealed sample at 77$0^{\circ}C$ with $O_2$ showed the critical temperature about 77 K and critical current denstity of 1.19 ${\times}$ 10$^{5}$ A/$\textrm{cm}^2$ about 13 K.

Temperature Dependence of Microwave Properties of HTS Multipole Lowpass Filters Consisting of Microstrip Open-Stub Lines

  • Kim, Je-Ha;Han, Seok-Kil;Kang, Kwnag-Yong;Ahn, Dal
    • ETRI Journal
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    • v.19 no.2
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    • pp.48-58
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    • 1997
  • Using high quality high-$T_c$ superconducting (HTS) YBCO thin films, we designed and fabricated 3-pole, 5-pole, and 7-pole lowpass filters consisting of microstrip transmission lines and open-stub lines. We measured the microwave response of the filters in the temperature range of T=85 K to 27 K. AtT=30 K, the observed inband insertion loss was 0.14dB and 0.02dB for the 5-pole and 7-pole filters, respectively. The cut-off frequency was 4.7 GHz for the 5-pole filter and 7.9GHz for the 7-pole filter. To the authors' knowledge, the measured inband insertion losses are the best values reported so far for the open-stub line type HTS multipole lowpass filters. The skirt property of the 5-pole filter showed a large improvement over that of the 3-pole filter as predicted from the simulation. We found that, to obtain a stable performance, the HTS multipole lowpass filters should be operated at the temperatures between 60% and 70% of $T_c$.

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High-Temperature Degradation of Hot-Pressed $t-ZrO_2$ Co-doped with $Y_2O_3$ and $Nb_2O_5$ (Hot-press법으로 제조된 $Y_2O_3$$Nb_2O_5$가 첨가된 정방정 ZrO2의 고온열화)

  • 이득용;김대준;조경식
    • Journal of the Korean Ceramic Society
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    • v.34 no.9
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    • pp.915-920
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    • 1997
  • Tetragonal ZrO2 polycrystal (TZP), consisted of 90.24 mol% ZrO2-5.31 mol% Y2O3-4.45 mol% Nb2O5, were prepared using hot-press and mechanical properties and high-temperature degradation were investigated. The specimen, hot-pressed for 1 h at 140$0^{\circ}C$ in Ar atmosphere, exhibited flexural strength of 1010 MPa and fracture toughness of 7.5 MPam1/2 and experienced no low-temperature degradation below 40$0^{\circ}C$. However, as aged for 100h at temperatures higher than 40$0^{\circ}C$, TZP was suffered by high-temperature degradation due to an extensive cavitation caused by the oxidation of carbon. XPS observation revealed that the carbon incorporated in TZPs during hot-pressing exists as either an ether-type CO or a carbonyl-type C=O. Despite of the high-temperature degradation of t-ZrO2 co-doped with Y2O3 and Nb2O5, its flexural strength and fracture toughness were superior to those of the commercial 3 mol% Y2O3-TZP hot-pressed under the identical condition as determined before and after the aging treatments.

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A Study on the Advanced Treatment of Wastewater by Plants (식물을 이용한 오수의 고도처리에 관한 연구)

  • 이용두;김현희
    • Journal of Environmental Science International
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    • v.8 no.1
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    • pp.75-81
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    • 1999
  • In recent years increasing production and disposal of wastewater have caused an accelerated eutrophication of receiving waters. Therefore, in order to alleviate the detrimental impact of wastewater discharge, there is an increasing demand for removing the main nutrients, nitrogen and phosphorus, as well as the organic content of the waste water prior to disposal. This is effectively achieved by extended conventional treatment technology. However, the working expenses and energy requirements of such advanced treatment systems are rather high. So in a sparsely populated rural community is required development of wastewater treatment system combined with the regional characteristics. In this study, the systems are planted with Reeds and Amaryllis In A.C and estimated purification potential of system. The results obtained are as follows. BOD removal rate is 20% in the early stage, the last removal rate is 35% in A.C process and is 65% in Amaryllis+A.C process and is 50% in Reed+A.C process. T-N removal rate by Amaryllis is average 2.6g/$m^3$ㆍd, T-N removal rate by Reed is average 1.76g/$m^3$ㆍd. T-P removal rate by Amaryllis is average 0.27g/$m^3$ㆍd, T-P removal rate by Reed is average 0.25g/$m^3$ㆍd. BOD removal rate constant with retention time is 1.4494(1/d), T-N removal rate constant is 0.5428(1/d), T-P removal rate constant is 0.5287(1/d).

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The Study on Anti-obesity Effects of Mulberry Leaves Contained Herbal Mixture (상엽(桑葉) 함유 한약복합제 추출물의 항비만(抗肥滿)효과 연구)

  • Park, Jong Ik;Kang, Kyung Ha;Park, Eun Jung
    • The Journal of Pediatrics of Korean Medicine
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    • v.27 no.4
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    • pp.17-30
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    • 2013
  • Objectives This experimental study was designed to investigate the effects of Mulberry leaves contained herbal mixture (MLHM) on body weight, serum lipid level and adipocyte differentiation in high fat diet-fed obese mice. Methods Four-week old mice (wild-type C57/BL6) were used for all experiments. Cells were incubated with MLHM at the indicated concentration (0.04-4mg/ml) for 24h, and growth rate was assessed by MTT ((3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide) assay. 3T3-L1 preadipocytes were incubated in DMEM for 2 days with the indicated concentrations of MLHM, and on Day 6, the cells were fixed and the cellular lipid contents were assessed by Oil-Red-O staining. The expression of peroxisome proliferator-activated receptor ${\gamma}$ (PPAR ${\gamma}$) and cytidine-cytidine-adenosine-adenosine-thymine (CCAAT)/enhancer-binding proteins ${\alpha}$ (C/EBP ${\alpha}$) as adipocyte-specific proteins were determined by real time RT-PCR and western blotting. In addition, body weight gain and serum lipid levels were measured in the mice with obesity induced by the high fat-diet for four weeks. Results Though MLHM did not show toxicity even at the concentration of 4mg/ml, MLHM significantly inhibited the differentiation of 3T3-L1 preadipocites in a dose-dependent manner. Also, MLHM significantly reduced the expressions of PPAR ${\gamma}$ and C/EBP ${\alpha}$ in a dose-dependent manner. Furthermore, MLHM significantly reduced body weight gain and LDL-cholesterol contents in high fat diet-fed obese mice. Conclusions These results demonstrate that MLHM exerts anti-obesity effect in 3T3-L1 cells and mice with obesity by high-fat diet.

Efficiency Characteristics of DC-DC Boost Converter Using GaN, Cool MOS, and SiC MOSFET (GaN, Cool MOS, SiC MOSFET을 이용한 DC-DC 승압 컨버터의 효율 특성)

  • Kim, Jeong Gyu;Yang, Oh
    • Journal of the Semiconductor & Display Technology
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    • v.16 no.2
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    • pp.49-54
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    • 2017
  • In this paper, recent researches on new and renewable energy have been conducted due to problems such as energy exhaustion and environmental pollution, and new researches on high efficiency and high speed switching are needed. Therefore, we compared the efficiency by using high speed switching devices instead of IGBT which can't be used in high speed switching. The experiment was performed theoretically by applying the same parameters of the high speed switching devices which are the Cool MOS of Infineon Co., SiC C3M of Cree, and GaN FET device of Transform, by implementing the DC-DC boost converter and measuring the actual efficiency for output power and frequency. As a result, the GaN FET showed good efficiency at all switching frequency and output power.

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Novel Organic Electron Injectors for the Enhancement of Lifetime, Efficiency and Reduction in Operating Voltage in OLEDs

  • Kathirgamanathan, Poopathy;Arkley, Vincent;Surendrakumar, S.;Paramaswara, G.;Ganeshamurugan, S.;Antipan-Lara, J.;Ravichandran, S.;Kumaraverl, M.;Chan, Y.F.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1206-1209
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    • 2007
  • Both PM-OLEDs and AM-OLEDs are now in production. However, manufacturers are still concerned about life-time, voltage drift, operating voltage and efficiency in order to develop larger displays. Most material suppliers seem to be focussing on emitters and the benefits of introducing suitable charge transporters have been largely unexplored. OLED-T has developed a novel organic electron injector (Trade Name: EI-101) which evaporates at a very low temperature of $300^{\circ}C$ as opposed to the conventional LiF which requires $580^{\circ}C$. EI-101 has been found to increase the lifetime by up to 12%, reduce the voltage drift by up to 61% and increase the efficiency by up to 15%. The material can be handled in air and in situ Q-mass spectroscopy on extended thermal evaporation has confirmed its high stability for use in mass production.

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Photodecomposition of N-t-Butyl-N-chloro-$\omega$-phenylalkanesulfonamides in the Presence of Oxygen

  • Lee, Jong Hun;Kim Kyongtae
    • Bulletin of the Korean Chemical Society
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    • v.13 no.6
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    • pp.676-680
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    • 1992
  • Irradiation of N-t-butyl-N-chloro-3-phenylpropanesulfonamide (1a) in benzene at $20^{\circ}C$ using 450 W high pressure mercury arc lamp in the presence of oxygen affored N-t-butyl-3-phenylpropanesulfonamide (2), N-t-butyl-3-chloro-3-phenylpropanesulfonamide (3), and N-t-butyl-3-oxo-3-phenylpropanesulfonamide (4). Similarly, N-t-butyl-4- (5), N-t-butyl-4-chloro-4- (6), and N-t-butyl-4-phenylbutanesulfonamides (7) were obtained from N-t-butyl-N-chloro-4-phenylbutanesulfonamide (1b). However, irradiation of N-t-butyl-N-chloro-5-phenylpentanesulfonamide (1c) under the same conditions gave complex mixtures. These results indicate that sulfonamidyl radical generated from each of 1a and 1b can abstract intramolecularly a hydrogen atom from the benzylic position only by forming six and seven-membered transition states, respectively.