• 제목/요약/키워드: High-$T_{c}$

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Bi-Pb-Sr-Ca-Cu-O계 산화물 고온초전도체의 특성에 관한 연구 (A Study on the Characteristic of High Tc Oxide Superconductor, Bi-Pb-Sr-Ca-Cu-O System)

  • 김양수;이민상;이민호;진영철
    • 열처리공학회지
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    • 제4권1호
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    • pp.13-18
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    • 1991
  • The formation of high $T_c$ phase is very sluggish and c parameter of unit cell of high $T_c$ phase is about $37{\AA}$. High $T_c$ oxide superconductor with a $T_c$ above 100 K has been successfully prepared by solid state reaction method in BiSrCaCuO system by Pb adding. The microstructure related to the formation of the high $T_c$ phase has been investigated. As compared with YBCO compound, the formation reaction of the high $T_c$ requires long time heat treatment. It is due to the transformation from the low $T_c$ phase to high $T_c$ phase. The sintering just below the melting point of the calcined powder mixture is effective on the formation of the high $T_c$ phase in Pb-added BiSrCaCuO system. The growth of the high $T_c$ superconducting phase has a thin plate shape, which is characterized by the c parameter of $37{\AA}$. The formation of the high $T_c$ phases is delayed by the excessive addition of Pb. The lattice parameter(c) of the unit cell (both the low and high $T_c$ phases) is increased with increase of Pb.

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복합응력이 작용하는 균열 배관에 대한 천이 크리프 조건에서의 C(t)-적분 예측 (I) - 탄성-크리프 - (Estimations of the C(t)-Integral in Transient Creep Condition for Pipe with Crack Under Combined Mechanical and Thermal Stress (I) - Elastic-Creep -)

  • 송태광;김윤재
    • 대한기계학회논문집A
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    • 제33권9호
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    • pp.949-956
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    • 2009
  • The C(t)-integral describes amplitude of stress and strain rate field near a tip of stationary crack under transient creep condition. Thus the C(t)-integral is a key parameter for the high-temperature crack assessment. Estimation formulae for C(t)-integral of the cracked component operating under mechanical load alone have been provided for decades. However, high temperature structures usually work under combined mechanical and thermal load. And no investigation has provided quantitative estimates for the C(t)-integral under combined mechanical and thermal load. In this study, 3-dimensional finite element analyses were conducted to calculate the C(t)-integral of elastic-creep material under combined mechanical and thermal load. As a result, redistribution time for the crack under combined mechanical and thermal load is re-defined through FE analyses to quantify the C(t)-integral. Estimates of C(t)-integral using this proposed redistribution time agree well with FE analyses results.

Edge-Cracking Behavior of CoCrFeMnNi High-Entropy Alloy During Hot Rolling

  • Won, Jong Woo;Kang, Minju;Kwon, Heoun-Jun;Lim, Ka Ram;Seo, Seong Moon;Na, Young Sang
    • Metals and materials international
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    • 제24권6호
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    • pp.1432-1437
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    • 2018
  • This work investigated edge-cracking behavior of equiatomic CoCrFeMnNi high-entropy alloy during hot rolling at rolling temperatures $500{\leq}T_R{\leq}1000^{\circ}C$. Edge cracks did not form in the material rolled at $500^{\circ}C$, but widened and deepened into the inside of plate as $T_R$ increased from $500^{\circ}C$. Edge cracks were most severe in the material rolled at $1000^{\circ}C$. Mn-Cr-O type non-metallic inclusion and oxidation were identified as major factors that caused edge cracking. The inclusions near edge region acted as preferential sites for crack formation. Connection between inclusion cracks and surface cracks induced edge cracking. Rolling at $T_R{\geq}600^{\circ}C$ generated distinct inclusion cracks whereas they were not serious at $T_R=500^{\circ}C$, so noticeable edge cracks formed at $T_R{\geq}600^{\circ}C$. At $T_R=1000^{\circ}C$, significant oxidation occurred at the crack surface. This accelerated edge crack penetration by embrittling the crack tip, so severe edge cracking occurred at $T_R=1000^{\circ}C$.

MDR1 C3435T and C1236T Polymorphisms: Association with High-risk Childhood Acute Lymphoblastic Leukemia

  • Pongstaporn, Wanida;Pakakasama, Samart;Chaksangchaichote, Panee;Pongtheerat, Tanett;Hongeng, Suradej;Permitr, Songsak
    • Asian Pacific Journal of Cancer Prevention
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    • 제16권7호
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    • pp.2839-2843
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    • 2015
  • Background: MDR1, one of the most important drug-transporter genes, encodes P- glycoprotein (P-gp)-a transporter involved in protecting against xenobiotics and multi-drug resistance. The significance of the genetic background in childhood acute lymphoblastic leukemia (ALL) is not well understood. Materials and Methods: To evaluate whether C3435T and C1236T MDR1 polymorphisms are associated with the occurrence and outcome of ALL, 208 children with ALL (median age 5.0 yr) and 101 healthy Thai children were studied by polymerase chain reaction-restriction fragment-length polymorphism (PCR-RFLP) assay. Results: C3435T and C1236T MDR1 polymorphism are significantly associated with the high-risk group (OR= 2.6, 95%CI =1.164-5.808; P=0.028 and OR= 2.231, 95%CI =1.068-4.659; p=0.047, respectively), indicating that both may be candidates for molecular markers in the high-risk group of ALL.

고온 이산화황 환경 내 내열 크롬강에 대한 부식특성 연구 (High Temperature Corrosion Properties of Heat Resistant Chrome Steels in SO2 Atmosphere)

  • 이한상;정진성;김의현
    • 대한금속재료학회지
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    • 제47권2호
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    • pp.99-106
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    • 2009
  • The high temperature corrosion properties of heat resistant steels were investigated in oxidation atmosphere including sulfur dioxide. The heat resistant steels of T22, T92, T122, T347HFG and T304H were evaluated at 620, $670^{\circ}C$ for 400 hours. The corrosion rates showed a decreasing tendency while chrome contents of those steels increased from 2 mass.% to 19 mass.%. The in crease in temperature increasement has an more effect on the corrosion rates of low chrome steels than high chrome steels. The weight gains of T22, T92, T304H at $670^{\circ}C$ were 3.7, 1.65, 1.23 times compared with those at $620^{\circ}C$. The external scale formed on T22 was composed of hematite, magnetite and Fe-Cr spinel and internal layer including iron oxide mixed with sulfide. The scales formed on T92, T122, T304H consisted of an outer layer of hematite and inner layer of chrome oxide and hematite. The proportion of chrome oxide at inner layer was increased when the chrome contents in heat resistant steels were increased.

An automated measurement system for the microwave surface resistance of high-T$_c$ superconductor films

  • Lee, J.H.;Lim, J.;Lee, Jung-Hun;Lee, Sang-Young
    • 한국초전도학회:학술대회논문집
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    • 한국초전도학회 2000년도 High Temperature Superconductivity Vol.X
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    • pp.173-178
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    • 2000
  • A prototype for a highly sensitive, automated measurement system for the microwave surface resistance of high-T$_c$ superconductor films was set up, and tested by measuring the microwave surface resistances of high-T$_c$ YBa$_2$Cu$_3$O$_{7-{\delta}}$(YBCO) films at the frequency of about 19.6 GHz and the temperature of 30 K ${\sim}$ 90 K. An open-ended TE$_{011}$ mode sapphire-loaded cylindrical cavity resonator was used as the measurement probe, where YBCO films were used as the endplates of the cylindrical cavity. The characteristics of the measurement system include functions to display the unloaded ${\varrho}$ and the resonant frequency of the TE$_{011}$ mode resonator as well as the microwave surface resistance of the YBCO films, all simultaneously as a function of temperature. Applicability of the measurement system for investigating the homogeneity in the microwave properties of large high-T$_c$ superconductor films is discussed.

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An Automated Measurement System for the Microwave Surface Resistance of High-$T_c$ Superconductor Films

  • Lee, J.H.;Lim, J.;Lee, Jung-Hun;Lee, Sang-Young
    • Progress in Superconductivity
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    • 제2권1호
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    • pp.27-32
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    • 2000
  • A prototype for a highly sensitive, automated measurement system for the microwave surface resistance of high-$T_c$ superconductor films was set up, and tested by measuring the microwave surface resistances of high-$T_c$ $YBa_2Cu_3O_{7-\delta}$ (YBCO) films at the frequency of about 19.6 GHz and the temperature of 30 K $\sim$ 90 K. An open-ended $TE_{011}$ mode sapphire-loaded cylindrical cavity resonator was used as the measurement probe, where YBCO films were used as the endplates of the cylindrical cavity. The characteristics of the measurement system include functions to display the unloaded Q and the resonant frequency of the $TE_{011}$ mode resonator as well as the microwave surface resistance of the YBCO films, all simultaneously as a function of temperature. Applicability of the measurement system for investigating the homogeneity in the microwave properties of large high-$T_c$ superconductor films is discussed.

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페놀수지의 C.T.I에 미치는 영향 (Influence of the C.T.I of phenolic resin)

  • 이보호;박동화;정인성
    • E2M - 전기 전자와 첨단 소재
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    • 제1권1호
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    • pp.70-77
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    • 1988
  • This paper describes the influence of the electrode materials, moisture content, electrolyte density, temperature, surface state, ion absorbent on the C.T.I of phenolic resin by the I.E,C, 112 method. C.T.I are increased for electrode materials with low hydrogen overvoltage and high soluble point. Increusing moisture content of samples increased by logarithmical on the droplet number to tracking breakdown. Increasing electrolyte temperature region above 70-80(.deg.C) decreased hydrogen over-voltage, following the density changes are decreased by C.T.I=1/aD$^{2}$-bD+C.

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