• Title/Summary/Keyword: High temperature history

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A Study on Crystallization of Thermoplastic Aromatic Polymer (열가소성 방향족 폴리머의 결정화 특성에 대한 연구)

  • Park, Dong-Cheol;Park, Chang-Wook;Shin, Do-Hoon;Kim, Yun-Hae
    • Composites Research
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    • v.31 no.2
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    • pp.63-68
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    • 2018
  • Thermoplastic composite has been limitedly used in high performance aerospace industry due to relatively low mechanical properties even though it has various advantages. But, thermoplastic aromatic polymer composite has recently been researched and utilized much. In this study, PEEK and PPS neat resin film as representative thermoplastic aromatic polymer were processed through continuous heating, cooling and reheating cycle. Property change such as glass transition temperature and melting temperature were identified and crystallinity variation by different cooling rate were evaluated. In the first (heating) run, polymer specimens were kept for 5 minutes at higher temperature than melting point to remove previous thermal history, and crystallization reaction was controlled by adjusting cooling rate to 2, 5, 10, 20 and $40^{\circ}C/minute$ in the second (cooling) run. In the third (heating) run, specimen crystallinity were verified by measuring the melting enthalpy. The initial specimens containing high portion of amorphous structure exhibited cold crystallization and clear glass transition in the first run whereas they did not show in the third run due to the increase of crystalline structure portion. As cooling rate decreases through the second cooling run, the crystallinity of the specimen increased. PEEK polymer had 21.9~39.3% crystallinity depending on cooling rate change whereas PPS polymer showed 29.1~31.2%.

Influence of Bubble Sheet Applying Methods on Temperature of Exposed Joint Rebar at Wall Surface of Load-Bearing Wall Structure Building During Winter (동절기 벽식구조 건축물 벽부분의 버블시트 포설방법 변화가 이음부 노출철근의 온도에 미치는 영향)

  • Han, Cheon-Goo;Lee, Jea-Hyeon;Kim, Min-Sang
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.2
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    • pp.149-155
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    • 2017
  • In this research, the surface covered curing method using the double-layered bubble sheet was evaluated. This double-layered bubble sheet has outstanding insulating performance with its low heat conductivity and high economic feasibility with its high durability. However, in the case of wall-typed building construction, the area of exposed rebar is curious on curing performance with the double-layered bubble sheet in spite of the double-layered bubble sheet showed favorable performance for slab. Therefore, in this research, regarding the actually constructed wall-typed apartment building, the most efficient curing method was suggested based on the evaluation of curing performance depending on temperature distribution depending on various location of covered or exposed rebar. As a result, the D method was determined as the most efficient curing method without any concern of early-age frost damage. However, by considering easiness of construction, the B method of covering the pieced double-layered bubble sheet on gap between rebars can be another option of desired result.

Biak and Wakatobi reefs are the two hottest hotspots of coral reef fish diversity and abundance in the Indonesian Archipelago

  • Imam Bachtiar;Edwin Jefri;Muhammad Abrar;Tri Aryono Hadi
    • Fisheries and Aquatic Sciences
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    • v.25 no.11
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    • pp.549-558
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    • 2022
  • The Indonesian Archipelago has a very complex geological history, along with equatorial warm sea temperature, resulting in diverse types of coral reefs and high diversity of coral reef fish. Many livelihoods of the coastal community are dependent on coral reef fisheries. The present study aimed to determine which region and location in the Indonesian Archipelago has the most diverse and abundant coral reef fish. The archipelago was divided into four regions: the Indian Ocean, Sunda Shelf, Wallacea, and the Pacific Ocean. Data were obtained from a national coral reef monitoring program of the Indonesian Research Center for Oceanography (RCO)-the National Board for Research and Innovation (BRIN). The reef fish data were collected using the underwater visual census method, from 321 belt transects on 24 locations (districts) across the archipelago. The results show that coral reef fish diversity of the Pacific region was the highest across the archipelago for all three trophic levels, i.e., corallivore, herbivore, and carnivore fish. The Pacific Ocean region also had the highest fish abundance for the three trophic levels. Comparison among locations revealed that the best ten locations in reef fish diversity and abundance were Sabang, Mentawai, Makassar, Selayar, Buton, Luwuk, Ternate, Raja Ampat, Biak, and Wakatobi. Wakatobi reefs showed their supremacy in carnivore fish diversity and abundance, while Biak reefs were the best in herbivore fish. The abundance of corallivore fish was also considerably high in Sabang reefs, but it is still lower than in Raja Ampat, Biak, and Wakatobi reefs. These results provide empirical evidence that the coral reefs of Wakatobi and Biak are the hottest hotspots of coral reef fish diversity and abundance in the Indonesian Archipelago.

Gold-Silver Mineralization of Taechang-Boryeon and Geumwang Mines in Northeastern Chungcheong Provinces (충청도(忠淸道) 동북부(東北部) 태창(泰昌)·보연(寶蓮), 금왕(金旺) 광산(鑛山)의 금은광화작용(金銀鑛化作用))

  • Choi, Seon Gyu;Park, No Young;Park, Sung Won
    • Economic and Environmental Geology
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    • v.19 no.spc
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    • pp.193-206
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    • 1986
  • A number of auriferous veins occur in the Precambrian metamorphic terrain from Chungju to Mugeug district. These gold (-silver) deposits consist mainly of the fissure-filling quartz veins intruding the Precambrian gneiss or schist and Jurassic or Cretaceous granite. These gold (-silver) deposits can be 'divided into two mineralization epochs, (a) gold-rich veins related to Daebo igneous activity, and (b) gold-silver veins related to Bulgugsa igneous activity. These two groups of ore deposits with different generation can be characterized by the mode of occurrence of ore vein and the ore mineral associations. The auriferous quartz veins of Taechang and Boryeon mines associated with late Jurassic igneous activity are massive in character, and show the simple mineral assemblages and low Ag/Au ratio in the ores, representing a single mineralization system. The ore minerals are predominantly quartz containing minor or trace amonts of pyrrhotite, sphalerite, galena, pyrite, chalcopyrite and electrum. Electrum is closely associated with pyrrhotite and has chemical compositions from 61.4 to 78.5 atomic % Au. Fluid inclusion data suggest that ore minerals were deposited at temperatures between 238 and $390^{\circ}C$ from $CO_2$-rich fluids. The gold and/or silver-bearing quartz veins of Geumwang mine related to middle Cretaceous igneous activity are characterized by the multistage history, diverse mineral assemblages with high Ag/Au ratio in the ores. The ores of Geumwang mine have two contrasting mineral assemblages (1) pyrite+galena+sphalerite+arsenopyrite+electrum+argentite, representing the higher gold mineralization, and (2) pyrite+chalcopyrite+ galena +sphalerite+ arsenopyrite+silver sulfosalts+ electrum+ native silver+argentite, representing the higher silver mineralization. Electrum is closely associated with pyrite and has chemical compositions from 11.2 to 49.9 atomic % Au. The depositional environment during the higher gold mineralization can be estimated as the range of both temperature and sulfur fugacity, T= $200{\sim}300^{\circ}C$, log f ($S_2$) = $10^{-10}{\sim}10^{-15}$. The higher silver mineralization may be interpreted to have formed a range of falling temperature ($150{\sim}200^{\circ}C$) and low sulfur fugacity($10^{-10}{\sim}10^{-15}$). These temperature data are consistent with homogenization temperatures of fluId inclusions in quartz. Thus, the gold veins related to the Daebo igneous activity may be formed by the environment of higher temperature and pressure than the gold-silver veins associated with the Bulgugsa igneous activity.

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Effect of Aging Time on the Sonic Conductivity of $PEO_8LiClO_4/Al_2O_3$ Composite Polymer Electrolytes ($PEO_8LiClO_4/Al_2O_3$ 복합 고분자 전해질에서의 이온 전도도의 노화 현상)

  • Choi, Byoung-Koo;Park, Young-Hwan
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.263-268
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    • 2007
  • Most of current works on the PEO-salt electrolytes has been focused on the enhancement of ionic conductivity with an addition of nano-ceramic fillers, but the significant drop of the conductivity with storage time is still in question and has been frequently overlooked. The conductivity drop with aging time has been assumed to come from the incorporation of ceramic particles. However, according to authors, the reported high-temperature values of the conductivity of pure $PEO_8LiCIO_4$ electrolytes are nearly in agreements, but the low temperature values are in great discrepancy reaching up to 10000 times. It indicates that the conductivity at ambient temperature is greatly dependent on the thermal history and sample preparations. In this paper, we showed that the ionic conductivities of both $PEO_8LiCIO_4$ and $PEO_8LiClO_4/Al_2O_3$ polymer electrolytes are strongly dependent on the thermal pretreatment and aging time. The conductivity drop with aging time of both ceramic-free and ceramic composite electrolytes has been measured to be nearly parallel. We showed that the conductivity relaxation with aging time is inherent irrespective of the incorporation of nano-ceramic fillers, since the PEO electrolytes at ambient temperature are in two-phase nature being in non-equilibrium state, never reaching completion.

Kinetics Determination of Quality Changes for the Optimization of Food Dehydration (식품건조공정 최적화에의 적용을 위한 품질 변화 Kinetics 결정)

  • Lee, Dong-Sun;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
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    • v.20 no.2
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    • pp.272-279
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    • 1988
  • Kinetics of ascorbic acid destruction and browning were evaluated by the dynamic test using actual drying data in order to apply in the optimization of food dehydration. Radish was chosen as a test material because it has many typical quality characteristics during drying. Radish was dried in the cabinet dryer with being measured in moisture, food temperature, ascorbic acid and browning. Using moisture and temperature history, proposed kinetic model was integrated and parameters of the model were searched by the iteration scheme to show minimum discrepancy between predicted and experimental data. Ascorbic acid destruction and browning were represented by first and zero order reaction respectively. Arrhenius equation was used to describe temperature dependence. Several mathematical functions of moisture dependence were compared in the model simplicity and residual sum of square. Attained kinetic models were analyzed as functions of temperature and moisture. Rate of ascorbic acid destruction was low at high moisture content, increased with moisture decrease to show a maximum at the moisture of $9{\sim}12g/g$ dry solid, and then decreased up to full dryness. Browning rate increased with moisture decrease to show a sharp maximum at $4{\sim}6g/g$ dry solid and decreased with further moisture decrease.

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Fluid Inclusions Trapped in Xenoliths from the Lower Crust/upper Mantle Beneath Jeju Island (I): A Preliminary Study (제주도의 하부지각/상부맨틀 기원의 포획암에 포획된 유체포유물: 예비연구)

  • Yang, Kyounghee
    • The Journal of the Petrological Society of Korea
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    • v.13 no.1
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    • pp.34-45
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    • 2004
  • This paper describes the textural relations of mantle xenoliths and fluid inclusions in mantle-derived rocks found in alkaline basalts from Jeju Island which contain abundant ultramafic, felsic, and cumulate xenoliths. Most of the ultramafic xenoliths are spinel-lherzolites, composed of olivine, orthopyroxene, clinopyroxene and spinel. The felsic xenoliths considered as partially molten buchites consist of quartz and plagioclase with black veinlets, which are the product of ultrahigh-temperature metamorphism of lower crustal materials. The cumulate xenoliths, clinopyroxene-rich or clinopyroxene megacrysts, are also present. Textural examination of these xenoliths reveals that the xenoliths are typically coarse grained with metamorphic characteristics, testifying to a complex history of evolution of the lower crust/upper mantle source region. The ultramafic xenoliths contain protogranular, porphyroclastic and equigranular textures with annealing features, indicating the presence of shear regime in upper mantle of the Island. The preferential associations of spinel and olivine with large orthopyroxenes suggest a previous high temperature equilibrium in the high-Al field and the original rock-type was a Al-rich orthopyroxene-bearing peridotite without garnet. Three types of fluid inclusions trapped in mantle-derived xenoliths include CO$_2$-rich fluid (Type I), multiphase silicate melt (glass ${\pm}$ devitrified crystals ${\pm}$ one or more daughter crystals + one or more vapor bubbles) (Type II), and sulfide (melt) inclusions (Type III). C$_2$-rich inclusions are the most abundant volatile species in mantle xenoliths, supporting the presence of a separate CO$_2$-rich phase. These CO$_2$-rich inclusions are spatially associated with silicate and sulfide melts, suggesting immiscibility between them. Most multiphase silicate melt inclusions contain considerable amount of silicic glass. reflecting the formation of silicic melts in the lower crust/upper mantle. Combining fluid and melt inclusion data with conventional petrological and geochemical information will help to constrain the fluid regime, fluid-melt-mineral interaction processes in the mantle of the Korean Peninsula and pressure-temperature history of the host xenoliths in future studies.

Status and Awareness of Excessive Heat Exposure among Agricultural Workers (일부 농업인의 고온노출에 대한 실태와 인지도 조사)

  • Lee, Dong-Hyun;Kim, Dong-Seob;Chung, Jin-Wook;Lee, Kwan;Lim, Hyun-Sul
    • Journal of agricultural medicine and community health
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    • v.43 no.1
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    • pp.9-17
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    • 2018
  • Objectives: This study was to assess the status and awareness of excessive heat exposure among agricultural workers. Methods: We selected a total of 90 farmers from a villages of Gyeongju-si, during August, 2015. We carried out the temperature measurement for nine times and derived Health Index (HI) and Wet Bulb Globe Temperature (WBGT) index. We compared the HI, WBGT and excessive heat warnings. Status of high temperature exposure, lifestyle, medical history, and awareness about excessive health related exposure illness assessed using survey questionnaires. Results: The matching rates between the WBGT and the HI during excessive heat warning were high, but when it was a non-excessive heat warning, there were days of excessive HI or WBGT. Out of 90 farmers surveyed, 78 cases (86.7%) were in their 60s and older age group. Slightly more than two third (71.1%) farmers were farming in the dawn-morning (71.1%), and the daily working hours were less than 4 hours (54.4 %), but only 23.3% among farmers took regular breaks. Of total, 14.4% farmers experienced excessive heat exposure related illness in order of tiredness, lethargy, dizziness, headaches, and sweating. Overall, the awareness of the danger for excessive heat and the heat wave warnings were high at 70.0% and 74.4%, respectively. Conclusions: Politically, the excessive heat warnings should not be taken into account the simple temperature measurement but, have to consider WBGT and HI standards at the same time. Farmers need to be promoted and educated to prevent the excessive heat related illness by periodically increasing their rest time during farming.

Cesium Release Behavior during the Thermal Treatment of High Bum-up Spent PWR Fuel (고연소도 경수로 사용후핵연료의 열처리에 따른 세슘 방출거동)

  • Park, Geun-Il;Cho, Kwang-Hun;Lee, Jung-Won;Park, Jang-Jin;Yang, Myung-Seung;Song, Kee-Chan
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.1
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    • pp.53-64
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    • 2007
  • The dynamic release behavior of Cs from high burn-up spent PWR fuel was experimentally performed under the conditions of a thermal treatment process such as voloxidation and sintering conditions. In voloxidation process, influence of the oxidation and reduction atmosphere on the Cs release characteristic using fragment type of spent fuel heated up to $1,500^{\circ}C$ was compared. In sintering process, temperature history effect on Cs release behavior was evaluated using green pellet under 4% $H_2/Ar$ environment. Temperature range for complete Cs release from spent fuel fragment under voloxidation condition was about $800^{\circ}C{\sim}1,200^{\circ}C$, but that of green pellet under the reduction atmosphere was $1,100^{\circ}C{\sim}1,400^{\circ}C$. Key parameters on Cs release behavior from spent fuel was powder formation as well as the diffusion rate of Cs compound to grain boundary and fuel surface.

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Seasonal Variation in Abundance and Species Composition of Surf Zone Fish Assemblage at Taecheon Sang Beach, Korea (大川海濱 碎波帶 魚類群集의 季節變化)

  • 신민철;이태원
    • 한국해양학회지
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    • v.25 no.3
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    • pp.135-144
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    • 1990
  • Fish assemblage occupying the surf zone habitat of Taecheon sand beach in Cheonsu Bay was analyzed using monthly samples collected by a beach seine from September 1984 through August 1985. During each sampling period five hauls were completed, one at each 2-hour interval during the spring tide. Of 35 species identified, Favonigobius gymnauchen, Sillago japonica, Konosirus punctatus, Sardinella zunasi and chaenogobius mororana accounted for 79% of the individuals collected, and F. gymnauchen, s. japonica, K. punctatus, S. zunasi and Kareius bicoloratus constituted 67% of the biomass obtained. Overall abundance in terms of numbers and in biomass were 0.13 individuals/m$^2$ and 0.33g/m$^2$, respectively. A larger number of individuals and greater biomass was observed during the warmer months showing significant correlation with water temperature. High abundance of June was related to the occurrence of adult F. gymnauchen. A large number of individuals and great biomass was collected in August and September, a period of high abundance in juveniles of the seasonal species such as S. japonica, K. punctatus and S. zunasi. Temperature and habitat occupation according to life history of the dominant species might be the primary factors of the marked seasonality of the surf zone fish populations in the study area.

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