• Title/Summary/Keyword: High temperature environment

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High Temperature Corrosion of Alloy 617 in Impure Helium and Air for Very High-Temperature Gas Reactor (초고온가스로용 Alloy 617의 불순물 함유 헬륨/공기 중에서 고온부식 특성)

  • Jung, Sujin;Lee, Gyeong-Geun;Kim, Dong-Jin;Kim, Dae-Jong
    • Corrosion Science and Technology
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    • v.12 no.2
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    • pp.102-112
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    • 2013
  • A very high-temperature gas reactor (VHTR) is one of the next generation nuclear reactors owing to its safety, high energy efficiency, and proliferation-resistance. Heat is transferred from the primary helium loop to the secondary helium loop through an intermediate heat exchanger (IHX). Under VHTR environment Alloy 617 is being considered a candidate Ni-based superalloy for the IHX of a VHTR, owing to its good creep resistance, phase stability and corrosion resistance at high temperature. In this study, high-temperature corrosion tests were carried out at 850 - $950^{\circ}C$ in air and impure helium environments. Alloy 617 specimens showed a parabolic oxidation behavior for all temperatures and environments. The activation energy for oxidation was 154 kJ/mol in helium environment, and 261 kJ/mol in an air environment. The scanning electron microscope (SEM) and energy-dispersive x-ray spectroscopy (EDS) results revealed that there were a Cr-rich surface oxide layer, Al-rich internal oxides and depletion of grain boundary carbide after corrosion test. The thickness and depths of degraded layers also showed a parabolic relationship with the time. A corrosion rate of $950^{\circ}C$ in impure helium was higher than that in an air environment, caused by difference in the outer oxide morphology.

MoS2 Layers Decorated RGO Composite Prepared by a One-Step High-Temperature Solvothermal Method as Anode for Lithium-Ion Batteries

  • Liu, Xuehua;Wang, Bingning;Liu, Jine;Kong, Zhen;Xu, Binghui;Wang, Yiqian;Li, Hongliang
    • Nano
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    • v.13 no.11
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    • pp.1850135.1-1850135.8
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    • 2018
  • A one-step high-temperature solvothermal approach to the synthesis of monolayer or bilayer $MoS_2$ anchored onto reduced graphene oxide (RGO) sheet (denoted as $MoS_2/RGO$) is described. It was found that single-layered or double-layered $MoS_2$ were synthesized directly without an extra exfoliation step and well dispersed on the surface of crumpled RGO sheets with random orientation. The prepared $MoS_2/RGO$ composites delivered a high reversible capacity of $900mAhg^{-1}$ after 200 cycles at a current density of $200mAg^{-1}$ as well as good rate capability as anode active material for lithium ion batteries. This one-step high-temperature hydrothermal strategy provides a simple, cost-effective and eco-friendly way to the fabrication of exfoliated $MoS_2$ layers deposited onto RGO sheets.

Photosynthesis Monitoring of Rice using SPAR System to Respond to Climate Change

  • Hyeonsoo Jang;Wan-Gyu Sang;Yun-Ho Lee;Hui-woo Lee;Pyeong Shin;Dae-Uk Kim;Jin-Hui Ryu;Jong-Tag Youn
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.169-169
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    • 2022
  • Over the past 100 years, the global average temperature has risen by 0.75 ℃. The Korean Peninsula has risen by 1.8 ℃, more than twice the global average. According to the RCP 8.5 scenario, the CO2 concentration in 2100 will be 940 ppm, about twice as high as current. The National Institute of Crop Science(NICS) is using the SPAR (Soil-Plant Atmosphere Research) facility that can precisely control the environment, such as temperature, humidity, and CO2. A Python-based colony photosynthesis algorithm has been developed, and the carbon and nitrogen absorption rate of rice is evaluated by setting climate change conditions. In this experiment, Oryza Sativa cv. Shindongjin were planted at the SPAR facility on June 10 and cultivated according to the standard cultivation method. The temperature and CO2 settings are high temperature and high CO2 (current temperature+4.7℃ temperature+4.7℃·CO2 800ppm), high temperature single condition (current temperature+4.7℃·CO2 400ppm) according to the RCP8.5 scenario, Current climate is set as (current temperature·CO2400ppm). For colony photosynthesis measurement, a LI-820 CO2 sensor was installed in each chamber for setting the CO2 concentration and for measuring photosynthesis, respectively. The colony photosynthetic rate in the booting stage was greatest in a high temperature and CO2 environment, and the higher the nitrogen fertilization level, the higher the colony photosynthetic rate tends to be. The amount of photosynthesis tended to decrease under high temperature. In the high temperature and high CO2 environment, seed yields, the number of an ear, and 1000 seed weights tended to decrease compared to the current climate. The number of an ear also decreased under the high temperature. But yield tended to increase a little bit under the high temperature and high CO2 condition than under the high temperature. In addition, In addition to this study, it seems necessary to comprehensively consider the relationship between colony photosynthetic ability, metabolite reaction, and rice yield according to climate change.

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Characteristics of Heptane Droplet Vaporization in High-Pressure and Temperature Flow Field (고온 고압 유동장에서 햅탄 액적의 기화 특성)

  • Ko, Jung-Bin;Koo, Ja-Ye
    • Journal of ILASS-Korea
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    • v.9 no.4
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    • pp.83-89
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    • 2004
  • Vaporization characteristics of a liquid heptane droplet in high-pressure and temperature flow field are numerically studied. Variable thermodynamic and transport properties and high-pressure effects are taken into account in order to consider real gas effects. Droplet Vaporization in convective environments was investigated on the basis of droplet vaporization in quiescent and convective environment. In quiescent environments, droplet lifetime is directly proportional to pressure at the subcritical temperature range but it is inversely proportional to pressure at the supercritical temperature range. In convective environment, droplet deformation becomes stronger by increasing Reynolds number due to increase of velocity while droplet deformation is relatively weak at a higher pressure for the same Reynolds number cases.

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A Case Study on Thermal Performance for Transparent Glazing Space Considering Solar Radiation in Summer (여름철 일사를 고려한 투명 투과체 공간의 열환경 특성에 관한 사례연구)

  • Ryu, Young-Hee;Seo, Hye-Soo;Lee, Min-Jung;Nam, Ji-yeon;Song, Mi-Na;Chun, Chung-Yoon
    • KIEAE Journal
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    • v.3 no.1
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    • pp.31-36
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    • 2003
  • Recently, buildings with transparent glazing on exterior walls have increased. The transparent glazing on exterior walls gives an impression of opening through introducing external environment's elements to inside of the building, and has various merits and so on, but has defects in controling indoor environments. Especially, the excess of solar radiation in summer increases cooling load causing discomforts to occupants providing radiant environment with high temperature. Cooling load mainly depends on electricity comparing to heating load and intents to centralize specific time. So it is necessary to work out a countermeasure. In this study, showed P building with transparent glazing on exterior walls as a case, investigated indoor thermal performance, numerical analysis of P building in summer through comparing dry-sauna which is represented as radiant environment with high temperature. In the results of this study, transparent glazing space has radiant environment with high temperature such as dry-sauna because of the excess of solar radiation. Accordingly countermeasures are considered in building planning. As concrete methods, there are adiabatic effects using double glazing, use of sunscreen, blind, ventilation facilitation using natural draft, decrease of surface temperature through evaporation cooling and cooling coils.

Fracture toughness of high performance concrete subjected to elevated temperatures Part 1 The effects of heating temperatures and testing conditions (hot and cold)

  • Zhang, Binsheng;Cullen, Martin;Kilpatrick, Tony
    • Advances in concrete construction
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    • v.2 no.2
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    • pp.145-162
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    • 2014
  • In this study, the fracture toughness $K_{IC}$ of high performance concrete (HPC) was determined by conducting three-point bending tests on eighty notched HPC beams of $500mm{\times}100mm{\times}100mm$ at high temperatures up to $450^{\circ}C$ (hot) and in cooled-down states (cold). When the concrete beams exposed to high temperatures for 16 hours, both thermal and hygric equilibriums were generally achieved. $K_{IC}$ for the hot concrete sustained a monotonic decrease tendency with the increasing temperature, with a sudden drop at $105^{\circ}C$. For the cold concrete, $K_{IC}$ sustained a two-stage decrease trend, dropping slowly with the heating temperature up to $150^{\circ}C$ and rapidly thereafter. The fracture energy-based fracture toughness $K_{IC}$' was found to follow similar decrease trends with the heating temperature. The weight loss, the fracture energy and the modulus of rapture were also evaluated.

Oxidation Behaviors of STS Series in Oxidizer-Rich Environment Using H2O2/Catalytic Reaction (H2O2/촉매 반응을 이용한 산화제 과잉 환경에서의 STS 계열 산화 거동)

  • Shin, Donghae;Choi, Jiseon;Shin, Minku;Ko, Youngsung;Kim, Seonjin;Han, Yeongmin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.923-927
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    • 2017
  • Metal exposed to high temperature/high pressure/oxidizer-rich environment may cause rapid oxidation(ignition and combustion). Therefore, this study was performed for the selection of metal appropriate for high temperature/high pressure/oxidizer-rich environment. In order to make the high temperature, high pressure and oxidizer-rich environment, the test facility utilizing the catalytic reaction of hydrogen peroxide was constructed and the metal oxidation and ignition of the STS series metals were evaluated. The result showed that the change of the selected material (discoloration) and the surface roughness were observed, but the change in the weight and thickness of the specimen was not significant.

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Influences of Environmental Conditions and Refractory Organic Matters on Organic Carbon Oxidation Rates Measured by a High Temperature Combustion and a UV-sulfate Methods (다양한 환경요인과 난분해성 유기물에 따른 고온산화 및 UV산화방식 총 유기탄소 산화율 변화)

  • Jung, Heon-Jae;Lee, Bo-Mi;Lee, Keun-Heon;Shin, Hyun-Sang;Hur, Jin
    • Journal of Korean Society on Water Environment
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    • v.32 no.1
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    • pp.98-107
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    • 2016
  • This study examined the effects of environmental conditions and the presence of refractory organic matter on oxidation rates of total organic carbon (TOC) measurements based on high temperature combustion and ultraviolet-sulfate methods. Spectroscopic indices for prediction of oxidation rates were also explored using the UV spectra and fluorescence excitation-emission matrix (EEM) of humic acids. Furthermore, optimum TOC instrument conditions were suggested by comparing oxidation rates of a standard TOC material under various conditions. Environmental conditions included salts, reduced ions, and suspended solids. Salts had the greatest influence on oxidation rates in the UV-sulfate method. However, no effect was detected in the high temperature combustion method. The UV-sulfate method showed lower humic substance oxidation rates, refractory natural organic matter, compared to the other methods. TOC oxidation rates for the UV-sulfate method were negatively correlated with higher specific-UV absorbance, humification index, and humic-like EEM peak intensities, suggesting that these spectroscopic indices could be used to predict TOC oxidation rates. TOC signals from instruments using the UV-sulfate method increased with increasing chamber temperature and increasing UV exposure durations. Signals were more sensitive to the former condition, suggesting that chamber temperature is important for improving the TOC oxidation rates of refractory organic matter.

Estimation of Expected Temperature Using Heat Balance Model and Observation Data

  • Kim, Eun-Byul;Park, Jong-Kil;Jung, Woo-Sik
    • Asian Journal of Atmospheric Environment
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    • v.9 no.3
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    • pp.214-221
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    • 2015
  • This study considers mean skin temperature to calculate expected temperature using the new heat balance model because the skin temperature is the most important element affecting the heat balance outdoors. For this, we measured the skin temperature in high temperature condition of Korea and applied it to calculate the expected temperature. The calculated expected temperature is compared with the result calculated using previous models which use the estimated mean skin temperature by considering metabolic rate only. Results show that the expected temperatures are higher when measured mean skin temperature is applied to the model, compared to the expected temperature calculated by applying mean skin temperature data calculated using metabolic rate like previous models. The observed mean skin temperature was more suitable for outside conditions and expected temperature is underestimated when mean skin temperature calculated by the equation using metabolic rate is used. The model proposed in this study has a few limitations yet, but it can be applied in various ways to facilitate practical responses to extreme heat.

Consideration of Temperature and Slip Correction for Photothermal Spectrometry

  • Lee, Jeonghoon
    • Asian Journal of Atmospheric Environment
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    • v.9 no.1
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    • pp.86-90
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    • 2015
  • Temperature was considered to estimate the minimum detectable absorption coefficient of aerosol particles from photothermal spectroscopy. Light energy absorbed by subsequent emission from the aerosol results in the heating of the aerosol sample and consequently causes a temperature change as well as changes in thermodynamic parameters of the sample. This thermal effect is the basis of photothermal spectroscopy. Photothermal spectroscopy has several types of techniques depending on how the photothermal effects are detected. Photothermal interferometry traces the photothermal effect, refractive index, using an interferometer. Photoacoustic spectroscopy detects the photothermal effect, sound wave, using a microphone. In this study, it is suggested that the detection limit for photothermal spectroscopy can be influenced by the introduction of a slip correction factor when the light absorption is determined in a high temperature environment. The minimum detectable absorption coefficient depends on the density, the specific heat and the temperature, which are thermodynamic properties. Without considering the slip correction, when the temperature of the environment is 400 K, the minimum detectable absorption coefficient for photothermal interferometry increases approximately 0.3% compared to the case of 300 K. The minimum detectable absorption coefficient for photoacoustic spectroscopy decreases only 0.2% compared to the case of 300 K. Photothermal interferometry differs only 0.5% point from photoacoustic spectroscopy. Thus, it is believed that photothermal interferometry is reliably comparable to photoacoustic spectroscopy under 400 K.