• Korean Chemical Engineering Research
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• 제57권1호
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• pp.133-141
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• 2019

침전법으로 환류방법 또는 수열합성법을 이용하여 산 염기점을 갖는 고비표면적 지르코니아를 합성하였다. 제조된 지르코니아는 침전제로 수산화암모늄 수용액을 사용하여 Zr 용액의 pH를 2에서 10 범위 내에서 조절하였으며 질소흡착분석, X-선 회절분석(XRD), 이소프로판올 승온탈착법(IPA-TPD), 주사전자현미경 분석, X-선 광전자분광분석, 산-염기점 분석을 통해 IPA 분해반응의 촉매활성과 연관하여 특성분석을 수행하였다. 환류방법을 사용할 시, tetragonal 상이 높은 지르코니아를 얻기 위해서는 Zr 용액의 pH가 높아야 하며, pH 9 이상에서는 순수한 tetragonal 상의 지르코니아 합성이 가능하였다. 또한, 비표면적이 큰 지르코니아를 얻기 위해서는 높은 pH가 요구되었으며, pH 10에서 합성한 경우에는 $600^{\circ}C$에서 소성 후에도 $260m^2g^{-1}$의 높은 비표면적이 얻어졌다. 하지만 같은 조건 하에서 고압이 수반되는 수열합성에는 $40m^2g^{-1}$ 이하의 매우 낮은 비표면적을 보였으며, monoclinic 상의 지르코니아가 합성되었다. 고 비표면적 tetragonal 상의 지르코니아를 얻기 위해서는 용액의 pH가 가장 큰 영향을 미쳤으며, 용액의 pH와 무관하게 높은 압력이 필요한 수열합성에서는 monoclinic 지르코니아가 생성되었으며 상대적으로 비표면적이 낮게 나타났다. 높은 비표면적과 tetragonal 상을 갖는 지르코니아는 염기점에 비해 산점이 우세하여 IPA 분해반응에서 선택적 탈수반응만 진행되는 프로필렌만 생성되었다.

• Bulletin of the Korean Chemical Society
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• 제24권10호
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• pp.1437-1443
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• 2003

Thermal decomposition of hydrated surface layer of $Mg(OH)_2$ at $500^{\circ}C$ in vacuum turned non-porous MgO into porous one with high surface area of around $270 m^2$/g. Most of its surface area, 74 %, was from micropores, and rest of it was from mesopores in wedge-shaped slits, exhibiting bimodal size distribution centered around 30 and 90${\AA}$. Rehydration followed by subsequent dehydration at $300 ^{\circ}C$ in dynamic vacuum further raised the surface area to 340 $m^2$/g. Fraction of microporous surface area was increased to 93%, and the shape of the mesopores was modified into parallel slits with a specific dimension of 32 ${\AA}$. Application of $Fe_2O_3$ over MgO via iron complex formation did not alter the pore characteristics of MgO core, except slightly increased pore dimension. Over the course of the modification, $Fe_2O_3$ stayed on the surface possibly via spill-over reaction.

• 한국방사선학회논문지
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• 제6권6호
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• pp.521-529
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• 2012

본 연구의 목표는 신발 굽 높이에 따른 Kager씨 삼각 면적의 방사선영상 변화와 후종족부의 표면온도 변화를 알아보고자 연구하였다. 카이거씨 면적은 단순 방사선촬영검사와 인피니티 영상저장전송시스템을 이용하여 측정 하였다. 후종족부의 표면온도는 전산화적외선체열검사를 이용하여 측정하였다. 운동화 착용 대상자에게 신발 굽 높이가 다른 하이힐을 착용시켜 카이거씨 삼각 면적과 후종족부의 표면온도 차이를 분석 하였다. 하이힐 대상자들은 운동화 대상자들에 비하여 카이거씨 삼각 면적이 $0.88cm^2$, 후종족부의 표면온도가 $1.4^{\circ}C$ 각각 감소하였다. 최고신장과 최저신장의 카이거씨 면적과 표면온도의 차이는 운동화와 하이힐에서 각각 $0.9cm^2$, $1.2cm^2$, $1.6^{\circ}C$, $0.5^{\circ}C$이며 모두 미세한 차이를 나타냈다. 최고체중과 최저체중의 카이거씨 면적과 표면온도의 차이는 운동화와 하이힐에서 각각 $1.8cm^2$, $0.8cm^2$, $1.1^{\circ}C$, $0.2^{\circ}C$이며 체중이 높을수록 카이거씨 면적과 표면온도가 감소하였다. 하이힐 최장시간 착용자와 최저시간 착용자의 카이거씨 면적과 표면온도의 차이는 각각 $0.8cm^2$, $1.4^{\circ}C$, 이며 착용시간이 증가함에 따라 카이거씨 면적과 표면온도가 감소하였다. 결론적으로 하이힐을 장시간 착용하면 후종족부 통증과 혈류 장애를 유발 할 것으로 고려된다.

• 한국재료학회지
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• 제32권2호
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• pp.107-113
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• 2022

Fibrous supercapacitors (FSs), owing to their high power density, good safety characteristic, and high flexibility, have recently been in the spotlight as energy storage devices for wearable electronics. However, despite these advantages, FCs face many challenges related to their active material of carbon fiber (CF). CF has low surface area and poor wettability between electrode and electrolyte, which result in low capacitance and poor long-term stability at high current densities. To overcome these limits, fibrous supercapacitors made using surface-activated CF (FS-SACF) are here suggested; these materials have improved specific surface area and better wettability, obtained by introducing porous structure and oxygen-containing functional groups on the CF surface, respectively, through surface engineering. The FS-SACF shows an improved ion diffusion coefficient and better electrochemical performance, including high specific capacity of 223.6 mF cm^-2 at current density of 10 ㎂ cm^-2, high-rate performance of 171.2 mF cm^-2 at current density of 50.0 ㎂ cm^-2, and remarkable, ultrafast cycling stability (96.2 % after 1,000 cycles at current density of 250.0 ㎂ cm^-2). The excellent electrochemical performance is definitely due to the effects of surface functionalization on CF, leading to improved specific surface area and superior ion diffusion capability.

• 한국재료학회지
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• 제27권4호
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• pp.192-198
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• 2017

Carbon nanofiber (CNF) is used as an electrode material for electrical double layer capacitors (EDLCs), and is being consistently researched to improve its electrochemical performance. However, CNF still faces important challenges due to the low mesopore volume, leading to a poor high-rate performance. In the present study, we prepared the unique architecture of the activated mesoporous CNF with a high specific surface area and high mesopore volume, which were successfully synthesized using PMMA as a pore-forming agent and the KOH activation. The activated mesoporous CNF was found to exhibit the high specific surface area of $703m^2g^{-1}$, total pore volume of $0.51cm^3g^{-1}$, average pore diameter of 2.9 nm, and high mesopore volume of 35.2 %. The activated mesoporous CNF also indicated the high specific capacitance of $143F\;g^{-1}$, high-rate performance, high energy density of $17.9-13.0W\;h\;kg^{-1}$, and excellent cycling stability. Therefore, this unique architecture with a high specific surface area and high mesopore volume provides profitable synergistic effects in terms of the increased electrical double-layer area and favorable ion diffusion at a high current density. Consequently, the activated mesoporous CNF is a promising candidate as an electrode material for high-performance EDLCs.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2011년도 춘계학술대회 논문집
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• pp.937-938
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• 2011

• 대기
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• 제23권4호
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• pp.485-500
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• 2013

This study conducted WRF-Fire simulations in order to investigate sensitivities of the resolution of fire fuel and terrain data sets, and the surface wind to simulated fire area. The sensitivity simulations were consisted of 8 different WRF-Fire runs, each of which used different combination of data sets of fire fuel and terrain with different resolution. From the results it was turned out that the surface wind was most sensitive. The next was fire fuel and then fire terrain. Unfortunately, every run produced too much fire area. In other words no simulations succeeded in simulating such proper fire area so as for the WRF-Fire to be used realistically. It was verified that the errors of fire area from each runs were contributed by 41%, 53%, and 6% from surface wind, fire fuel, and fire terrain, respectively. Finally this study suggested that the selection of Anderson fuel category in the area of interest seemed to be very critical in the performance of WRF-Fire simulations.

• Current Photovoltaic Research
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• 제2권3호
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• pp.84-87
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• 2014

Protection of solar cell surface is important to prevent from dust, pollen, sand, etc. Therefore, development of large area antifouling film is urgent for high performance of solar cells. The surface of silica spheres was modified to fabricate large area antifouling film. The surface of monodisperse silica spheres has been modified with 3-(trimethoxysilyl) propylmethacrylate (TMSPM) to fabricate large area photonic crystal. Although the surface modification of silica spheres with TMSPM has been failed for the base catalyst, the second trial using acid catalyst showed the following results. The FTIR absorption peak at $1721cm^{-1}$ representing C=O stretching vibration indicates that the TMSPM was attached on the surface of silica spheres. The methanol solution comprised of the surface modified silica spheres (average diameter of 380 nm) and a photoinitiator was poured in the patterned silicon wafer with the dimension of 10 cm x 10 cm and irradiated UV-light during the self-assembly process. The result showed large area crack and defect free nanostructures.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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• pp.779-782
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• 2004

Establishing and maintaining optimum lamp operating temperature is critically important in backlight systems for large area displays. The information presented in this paper is based upon work completed for a tiled 37.5" AM LCD, plus projections for a 37.5", 42" & 50" monolithic display. Due to the size of the units, a requirement for highly collimated light and a requirement for high brightness, >550 nits at the display surface, significant wattage is required which generates high heat levels in the backlight display assembly and potentially, at the display rear surface. Uniformity of illumination becomes an important element in the system design because of the large area involved.

• 한국환경과학회지
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• 제9권4호
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• pp.295-302
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• 2000

This study was conducted to investigate the characteristics of surface ozone concentration and occurrence of high ozone concentration using hourly ozone, nitrogen dioxide and meteorological data for 1997~1998 in Pusan coastal area. Monthly mean ozone concentration was the highest at Dongsamdong in Spring(35.4ppb), at Kwangbokdong in Fall(25.1ppb) and the lowest Dongsamdong(22.2ppb) and Kwangbokdong(16.0ppb) in Winter. Relative standard deviation indicating clearness of observation site was 0.42 at Dongsamdong and 0.49 at Kwangbokdong that is similar to urban area. The diurnal variation of ozone concentration of Dongsamdong and Kwangbokdong showed maximum at 1500~1600LST and minimum 0700~0800LST that typical pattern of ozone concentration. In ozone episode period(Sept. 10~15, 1998), diurnal change of ozone concentration was very high, and ozone concentration was related to meteorological parameters such as temperature, relative humidity, wind speed, cloud amount and radiation on a horizontal surface. During the episode days peak ozone concentrations are much higher than the normal values, wind speeds are always lower, and solar radiation is high with the exception of the September episode.