• Title/Summary/Keyword: High separation efficiency

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Development of Electrospun Cellulose Acetate Membranes using Carbon Nanotubes for Filtration of Particulate Matter in the Air (전기방사를 이용한 탄소나노튜브 폴리머 공기정화 멤브레인 개발)

  • Park, Soyeon;Kim, Jaehyuk;Han, Sangil
    • Korean Chemical Engineering Research
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    • v.55 no.1
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    • pp.68-73
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    • 2017
  • The removal of particulate matter ranging from $0.01{\mu}m{\sim}10{\mu}m$ can be performed by using membrane filters composed of fibers. Electrospinning techniques offer the production of very thin fibers with a uniform fiber diameter over conventional techniques including template synthesis, melt-blown, phase separation, etc. Air filtration will be improved with electrospun membranes due to the open pore structures, high porosity, and large surface area of the membranes. In the present study, filtration efficiency increased with pore size decrease and fiber density increase induced by carbon nanotube and the increased CA (cellulose acetate) concentration during electrospinning process.

Reuse of Hydrogen Sulfide by Ferric Chelate Reaction of Food Waste Anaerobic Digestion Gas, Sulfur Recovery and its Economic Evaluation (킬레이트 착화학반응에 의한 음식물폐기물 혐기소화가스 중 황화수소의 제거와 황회수 및 경제성평가)

  • Park, Young G.;Yang, Youngsun
    • Clean Technology
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    • v.20 no.4
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    • pp.367-374
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    • 2014
  • Several experiments have been done to investigate the removal of hydrogen sulfide ($H_2S$) synthetic gas from biogas streams by means of chemical absorption and chemical reaction with 0.1-1 M Fe/EDTA solution. The roles of Fe/EDTA were studied to enhance the removal efficiency of hydrogen sulfide because of oxidizing by chelate. The motivation of this investigation is first to explore the feasibility of enhancing the toxic gas treatment in the biogas facility. The biogas purification strategy affords many advantages. For instance, the process can be performed under mild environmental conditions and at low temperature, and it removes hydrogen sulfide selectively. The end product of separation is elemental sulfur, which is a stable material that can be easily disposed with minor potential for further pollution. As the Fe-EDTA concentration increased, the conversion rate of hydrogen sulfide increased because of the high stability of Fe-EDTA complex. pH as an important environmental factor was 9.0 for the stability of chemical complex in the oxidation of hydrogen sulfide.

Development of the Pilot System for Radioactive Laundry Waste Treatment Using UV Photo-Oxidation Process and Reverse Osmosis Membrane

  • Park, Se-Moon;Park, Jong-Kil;Kim, Jong-Bin;Shin, Sang-Woon;Lee, Myung-Chan
    • Nuclear Engineering and Technology
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    • v.31 no.5
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    • pp.506-511
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    • 1999
  • The pilot system for radioactive liquid laundry waste was developed with treatment capacity, 1ton/hr and set up in the Yong Kwang unit #4. The system is composed of tank module, RO systems and a UV/$H_2O$$_2$photo-oxidation unit. The RO system consists of the BW unit (low-pressure RO for brackish water desalination) and the SW unit (high-pressure RO for seawater desalination). The BW unit possesses 4 RO membranes and it can reduce the feed water volume down to 1/10. This concentrated feed water can be reduced again up to 1/10 in its volume in the SW unit composed of 4 RO membranes. The UV/$H_2O$$_2$ photo-oxidation process unit was used for the detergent degradation. The operation of the pilot system was carried out and verified in its capability through the continuous operation and concentration operation using the actual liquid waste from the power plant. The design criteria and data for industrialization were yielded. The efficiency of the UV/$H_2O$$_2$ photo-oxidation process and the optimum operational procedure were evaluated. The decontamination factors for radioactive cobalt and cesium were measured. This on-site test showed the experimental result in the DF$\geq$300 and volume reduction factor$\geq$100.

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Overview and Recent Development of Recycling Waste Refrigerators (폐(廢) 냉장고(冷藏庫) 재활용(再活用) 현황(現況)과 기술(技術) 전망(展望))

  • Yang, Hyunseok;Kim, Geon-Hong;Kong, Man-Sik;Park, Kiejin;Lee, Gwang Weon;Kim, Bo Saeng
    • Resources Recycling
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    • v.22 no.4
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    • pp.70-80
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    • 2013
  • Waste refrigerator is the most large amount of item being recycled and the recycling process is the most complicated in WEEE (Waste Electrical and Electronic Equipment) because refrigerator is biggest product and consists of various parts and materials such as ferrous, non-ferrous, and plastics. Recently, recycling process of waste refrigerator has been being more complex since large capacity 2 door refrigerators and standing Kimchi refrigerators with various material are distributed on custom market. In addition, recycling of valuable resource from waste refrigerator is mandatory by WEEEs recycling legislation; therefore, high efficiency recycling enough for economic and environment-friendly recovery of valuable resource through present technical situation analysis and comparison of recycling technologies of waste refrigerator with advanced country.

The effect of UV-C irradiation and EDTA on the uptake of Co2+ by antimony oxide in the presence and absence of competing cations Ca2+ and Ni2+

  • Malinen, Leena;Repo, Eveliina;Harjula, Risto;Huittinen, Nina
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.627-636
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    • 2022
  • In nuclear power plants and other nuclear facilities the removal of cobalt from radioactive liquid waste is needed to reduce the radioactivity concentration in effluents. In liquid wastes containing strong organic complexing agents such as EDTA cobalt removal can be problematic due to the high stability of the Co-EDTA complex. In this study, the removal of cobalt from NaNO3 solutions using antimony oxide (Sb2O3) synthesized from potassium hexahydroxoantimonate was investigated in the absence and presence of EDTA. The uptake studies on the ion exchange material were conducted both in the dark (absence of UV-light) and under UV-C irradiation. Ca2+ or Ni2+ were included in the experiments as competing cations to test the selectivity of the ion exchanger. Results show that UV-C irradiation noticeably enhances the cobalt sorption efficiency on the antimony oxide. It was shown that nickel decreased the sorption of cobalt to a higher extent than calcium. Finally, the sorption data collected for Co2+ on antimony oxide was modeled using six different isotherm models. The Sips model was found to be the most suitable model to describe the sorption process. The Dubinin-Radushkevich model was further used to calculate the adsorption energy, which was found to be 6.2 kJ mol-1.

Application and optimal design of the bionic guide vane to improve the safety serve performances of the reactor coolant pump

  • Liu, Haoran;Wang, Xiaofang;Lu, Yeming;Yan, Yongqi;Zhao, Wei;Wu, Xiaocui;Zhang, Zhigang
    • Nuclear Engineering and Technology
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    • v.54 no.7
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    • pp.2491-2509
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    • 2022
  • As an important device in the nuclear island, the nuclear coolant pump can continuously provide power for medium circulation. The vane is one of the stationary parts in the nuclear coolant pump, which is installed between the impeller and the casing. The shape of the vane plays a significant role in the pump's overall performance and stability which are the important indicators during the safety serve process. Hence, the bionic concept is firstly applied into the design process of the vane to improve the performance of the nuclear coolant pump. Taking the scaled high-performance hydraulic model (on a scale of 1:2.5) of the coolant pump as the reference, a united bionic design approach is proposed for the unique structure of the guide vane of the nuclear coolant pump. Then, a new optimization design platform is established to output the optimal bionic vane. Finally, the comparative results and the corresponding mechanism are analyzed. The conclusions can be gotten as: (1) four parameters are introduced to configure the shape of the bionic blade, the significance of each parameter is herein demonstrated; (2) the optimal bionic vane is successfully obtained by the optimization design platform, the efficiency performance and the head performance of which can be improved by 1.6% and 1.27% respectively; (3) when compared to the original vane, the optimized bionic vane can improve the inner flow characteristics, namely, it can reduce the flow loss and decrease the pressure pulsation amplitude; (4) through the mechanism analysis, it can be found out that the bionic structure can induce the spanwise velocity and the vortices, which can reduce drag and suppress the boundary layer separation.

Application to Piezoelectric and Triboelectric Generators of Spongy Structured BaTiO3 Prepared by Sputtering (Sputtering에 의해 제조된 해면 구조 BaTiO3의 압전 및 마찰전기 발전기에의 응용)

  • Seon-A Kim;Sang-Shik Park
    • Korean Journal of Materials Research
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    • v.34 no.1
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    • pp.34-43
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    • 2024
  • New piezoelectric and triboelectric materials for energy harvesting are being widely researched to reduce their processing cost and complexity and to improve their energy conversion efficiency. In this study, BaTiO3 films of various thickness were deposited on Ni foams by R.F. magnetron sputtering to study the piezoelectric and triboelectric properties of the porous spongy structure materials. Then piezoelectric nanogenerators (PENGs) were prepared with spongy structured BaTiO3 and PDMS composite. The output performance exhibited a positive dependence on the thickness of the BaTiO3 film, pushing load, and poling. The PENG output voltage and current were 4.4 V and 0.453 ㎂ at an applied stress of 120 N when poled with a 300 kV/cm electric field. The electrical properties of the fabricated PENG were stable even after 5,000 cycles of durability testing. The triboelectric nanogenerators (TENGs) were fabricated using spongy structured BaTiO3 and various polymer films as dielectrics and operated in a vertical contact separation mode. The maximum peak to peak voltage and current of the composite film-based triboelectric nanogenerator were 63.2 V and 6 ㎂, respectively. This study offers new insights into the design and fabrication of high output nanogenerators using spongy structured materials.

Thin Film Nanocomposite Based Nanofiltration Membrane for Wastewater Treatment: Fabrication and Dyes Removal (폐수처리용 박막나노복합체 기반 나노여과막: 제조 및 염료제거)

  • Dohoon Park;Rajkumar Patel
    • Membrane Journal
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    • v.34 no.3
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    • pp.182-191
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    • 2024
  • This review addresses the pressing need for effective wastewater treatment methodologies by exploring advanced thin-film nanocomposite (TFN) nanofiltration membranes aimed at efficient dye removal from industrial effluents. Utilizing insights from recent research, the review focuses on the fabrication of TFN membranes incorporating innovative materials such as nanocarbons, silica nanospheres, metal-organic frameworks (MOFs), and MoS2. The primary goals are to enhance dye removal efficiency, improve antifouling properties, and maintain high selectivity for dye/salt separation. By leveraging the distinct advantages of these nanomaterials-including large surface areas, mechanical robustness, and specific pollutant interaction capabilities-this review aims to overcome the limitations of current nanofiltration technologies and provide sustainable solutions for water treatment challenges.

Characterization and assessment of the dolomite powder for application as fillers in the marble-type ore (대리암형 백운석의 분체 특성과 충전재로서의 응용성 평가)

  • Noh, Jin-Hwan;Lee, Na-Kyoung
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.2 s.52
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    • pp.71-81
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    • 2007
  • The marble-type dolomite from the Jasung Mine, which was farmed by duplicated affects of contact metamorphism and subsequent hydrothermal alteration, corresponds to a high-purity dolomite ranging up to above 98wt.% in dolomite contents. The dolomite contain minor impurities such as quartz, muscovite, and pyrite. It is characteristic that the dolomite is fairy Fe-rich corresponding to 0.4 wt.% due to the presence of pyrite of possible hydrothermal origin. The dolomite is nearly white-colored and constituting with subhedral crystals ranging $0.35{\sim}0.46mm$M in size, forming equigranular texture. Compared to the typical high-Ca limestone from the Pungchon Formation, the powder characteristics of dolomite is rather superior in milling efficiency, yields of fine particles, and size distribution. In addition, except for iron contents, the dolomite powder is no less superior than the limestone in quality and characteristics as fillers with respects to not only whiteness, oil absorption, and specific surface area but also shape characters such as elongation ratio, aspect ratio, and sphericity. This good characteristics of dolomite powder seem to be originated basically from comparatively higher grade and crystallinity of dolomite. Higher iron contents and the presence of sulfides prevents the dolomite from application for uses by thermal treatment, except for metallic manufacture. However, if proper ore separation procedure is available, the dolomite can be sufficiently utilized as substitutes for high-Ca limestone in most fields of filler industries.

Development of a Bioscrubber for Treatment of VOC Emissions from Contaminated Soil with Hydrocarbons (유류오염토양으로부터 발생하는 VOC가스처리를 위한 바이오스크러버 개발)

  • 장윤영;황경엽;곽재호;최대기
    • Journal of Korea Soil Environment Society
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    • v.2 no.1
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    • pp.83-90
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    • 1997
  • Aiming at the treatment of large volumes of gas with a low concentration of poorly water soluble VOC(Volatile Organic Compound), a new system is proposed: the combination absorption tower/bioreactor. In the scrubber part of the bioscrubbing system, the contaminating compounds are absorbed in a aqueous phase. The contaminated scrubbing liquid is transported to the bioreactor, where the compounds are biodegraded by aerobic microorganisms (mainly to carbon dioxide, water, and biomass). In this study, separation of a volatile organic compound(VOC) out of a waste gas stream has been carried out using a re-cyclable high boiling point extrant(HBE). The liquid stream containing a high boiling point entrant(HBE) scrubs the gas stream in a direct gas-liquid countercurrent contacting operation in a packed tower for the removal of said component from the gaseous stream. A packed-bed column using Pall Ring was set up in order to simulate practical conditions for the scrubbing tower. The liquid stream transported to the bioreactor is recovered and recycled to the scrubber. The model gas, which contained 400 mg/$\textrm{m}^3$ of toluene, at a rate of 100 L/min, flowed into the packed column where the scrubbing liquid trickled over the packing in countercurrent to the rising gas at 10~15L/min. The bioscrubber designed for large volume air streams containing VOCs showed removal efficiency up to 80% in an optimum operating conditions during the tests fer removing toluene from an air stream by scrubbing the air stream with HBE.

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