• Corrosion Science and Technology
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• 제16권3호
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• pp.100-108
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• 2017

In this investigation corrosion behavior of newly developed high-pressure die cast Al-Ni (N15) and Al-Ni-Ca (NX1503) alloys was studied in 3.5% NaCl solution. The electrochemical corrosion behavior was evaluated using open circuit potential (OCP) measurement, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) techniques. Potentiodynamic polarization results validated that NX1503 alloy exhibited lower corrosion current density ($i_{corr}$) value ($5.969{\mu}A/cm^2$) compared to N15 ($7.387{\mu}A/cm^2$). EIS-Bode plots revealed a higher impedance (${\mid}Z{\mid}$) value and maximum phase angle value for NX1503 than N15 alloy. Equivalent circuit curve fitting analysis revealed that surface layer ($R_1$) and charge transfer resistance ($R_{ct}$) values of NX1503 alloy was higher compared to N15 alloy. Immersion corrosion studies were also conducted for alloys using fishing line specimen arrangement to simultaneously measure corrosion rates from weight loss ($P_W$) and hydrogen volume ($P_H$) after 72 hours and NX1503 alloy had lower corrosion rate compared to N15 alloy. The addition of Ca to N15 alloy significantly reduced the Al3Ni intermetallic phase and further grain refinement may be attributed for reduction in the corrosion rate.

• Nuclear Engineering and Technology
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• 제41권10호
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• pp.1263-1274
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• 2009

Several experimental tests to simulate a reflood phase of a cold-leg LBLOCA of the APR1400 have been performed using the ATLAS facility. This paper describes the related experimental results with respect to the thermal-hydraulic behavior in the core and the system-core interactions during the reflood phase of the cold-leg LBLOCA conditions. The present descriptions will be focused on the LB-CL-09, LB-CL-11, LB-CL-14, and LB-CL-15 tests performed using the ATLAS. The LB-CL-09 is an integral effect test with conservative boundary condition; the LB-CL-11 and -14 are integral effect tests with realistic boundary conditions, and the LB-CL-15 is a separated effect test. The objectives of these tests are to investigate the thermal-hydraulic behavior during an entire reflood phase and to provide reliable experimental data for validating the LBLOCA analysis methodology for the APR1400. The initial and boundary conditions were obtained by applying scaling ratios to the MARS simulation results for the LBLOCA scenario of the APR1400. The ECC water flow rate from the safety injection tanks and the decay heat were simulated from the start of the reflood phase. The simulated core power was controlled to be 1.2 times that of the ANS-73 decay heat curve for LB-CL-09 and 1.02 times that of the ANS-79 decay curve for LB-CL-11, -14, and -15. The simulated ECC water flow rate from the high pressure safety injection pump was 0.32 kg/s. The present experimental data showed that the cladding temperature behavior is closely related to the collapsed water level in the core and the downcomer.

• 한국표면공학회지
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• 제37권5호
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• pp.296-300
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• 2004

The defects of partial denture frameworks are mainly shrinkage porosity, inclusions, micro-crack, particles from investment, and dendritic structure. In order to investigate a good casting condition of partial denture frameworks, the three casting alloys and casting methods were used and detected casting defects were analyzed by using electrochemical methods. Three casting alloys (63Co-27Cr-5.5Mo, 63Ni-16Cr, 63Co-30Cr-5Mo) were prepared for fabricating partial denture frameworks with various casting methods; centrifugal casting (Kerr, USA), high frequency induction casting (Jelenko Eagle, USA), vacuum pressure casting (Bego, Germany). The casting temperature was $1,380^{\circ}C$ (63Co-27Cr-5.5Mo and 63Ni-16Cr) and $1,420^{\circ}C$ (63Co-30Cr-5Mo). The casting morphologies were analyzed using FE-SEM and EDX. The corrosion test of the dendritic structure was performed through potentiodynamic method in 0.9% NaCl solutions at $36.5^{\circ}C$ and corrosion surface was observed using SEM. The defects of partial denture frameworks improved in the order of centrifugal casting, high frequency induction casting, and vacuum pressure casting method, especially, pore defects were found at part of clasp in the case of centrifugal casting method. The structure of casting showed dendritic structure for three casting alloys. In the 63Co-27Cr-5.5Mo and 63Co-30Cr-5Mo, $\alpha$-Co and $\varepsilon$-Co phases were identified at matrix and $${\gamma}$-Ni_2$Cr second phase were shown in 63Ni-16Cr. Also, the corrosion resistance of cast structure increased in the order of vacuum pressure casting, high frequency induction casting, and centrifugal casting method.

• Journal of Mechanical Science and Technology
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• 제18권12호
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• pp.2310-2318
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• 2004

The effects of change in injection pressure on spray structure in high temperature and pressure field have been investigated. The analysis of liquid and vapor phases of injected fuel is important for emissions control of diesel engines. Therefore, this work examines the evaporating spray structure using a constant volume vessel. The injection pressure is selected as the experimental parameter, is changed from 400 bar to 800 bar by using a common rail injection system. Also, we conducted simulation study by modified KIVA-II code. The results of simulation study are compared with experimental results. The images of liquid and vapor phase for free spray were simultaneously taken by exciplex fluorescence method. As experimental results, the vapor concentration of injected fuel is leaner due to the increase of atomization in the case of the high injection pressure than in that of the low injection pressure. The calculated results obtained by modified KIVA-II code show good agreements with experimental results.

• 한국광물학회지
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• 제29권4호
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• pp.191-198
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• 2016

인회석 광물 군에 속하는 녹연석($Pb_{4.85}(P_{1.02}O_4)_3Cl_{1.04}$)에 대한 상온-고압 상태방정식 연구를 시행하였다. 대칭형 다이아몬드 앤빌기기를 이용하여 33.4 GPa까지 압력을 증가시키면서 각분산 X-선 회절법과 방사광을 이용하여 회절 데이터를 검출하였으며, 시료에 가해준 압력은 루비 형광파의 파장변화를 측정하여 결정하였다. 본 고압실험에서 시행한 압력의 범위 내에서 상변이는 관찰되지 않았으며, 정압상태에서 체적탄성률($K_0$)은 $K{_0}^{\prime}=13(2)$일 때 80(7) GPa로 계산되었다. 본 연구에서 결정된 상온상태에서 녹연석의 체적탄성률 신뢰도를 정규화압력 및 정규화응력변형 분석을 하여 평가하였다.

• 한국항공우주학회지
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• 제33권4호
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• pp.71-78
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• 2005

초임계 상태의 질소 유동 환경에서 헵탄 액적의 기화 특성을 수치적으로 연구하였다. 더불어 실기체 효과와 액적 내부 순환, 다양한 열역학적 물성치 및 고압 효과를 고려하였다. 또한 헵탄 액적 바로 근처에서의 저속 유동 문제를 풀기 위하여 예조건화 스킴을 적용한 시간 전진법을 수치 코드에 적용하였다. 주위 유동 속도와 주위 압력을 변화 시켜가면서 액적의 거동을 살펴보았다. 유동 속도 증가로 인한 레이놀즈수의 증가에 따라 액적의 변형이 활발히 이루어졌고, 동일한 레이놀즈수에 대해서는 압력이 높아질수록 액적의 변형이 약화되었다.

• 한국세라믹학회지
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• 제50권4호
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• pp.288-293
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• 2013

Zn-In-Sn-O films were prepared at room temperature by combinatorial RF-magnetron co-sputtering system. The cationic contents of the films were varied using a compositionally combinatorial technique. The effects of the oxygen partial pressure and film compositionon the structural and electrical properties were investigated. The Zn-In-Sn-O films deposited at Ar gas atmosphere showed an amorphous phaseirrespective of the film composition. However, the amorphous Zn-In-Sn-O films with a Zn content below 30.0 at% were converted into a bixbyite type-ITO polycrystalline phase with an increase in the oxygen partial pressure. The resistivity, carrier concentration, and Hall mobility were strongly affected by the oxygen partial pressure and chemical composition of the film. At sufficiently high carrier densities above $5{\times}10^{18}cm^{-3}$, the conduction behavior of amorphous Zn-In-Sn-O film changes from thermally activated to degenerate band conduction accompanied with high mobility.

• 열처리공학회지
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• 제36권3호
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• pp.128-136
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• 2023

In this study, the effects of heat treatment on the nano-scale creep behavior of CoCrFeMnNi high-entropy alloy (HEA) processed by high-pressure torsion (HPT) was investigated through nanoindentation technique. Nanoindentation experiments with a Berkovich indenter were performed on HPT-processed alloy subjected to heat treatment at 450℃, revealing that the hardness of the HPT-processed alloy (HPT sample) significantly increased with the heat treatment time. The heat treatment-induced microstructural change in HPT-processed alloy was analyzed using transmission electron microscopy, which showed the nano-sized Cr-, NiMn-, and FeCo-rich phases were formed in the HPT-processed alloy subjected to 10 hours of heat treatment (HPT+10A sample). To compare the creep behavior of HPT and HPT+10A samples, constant load nanoindentation creep experiments were performed using spherical indentation indenters with two different radii. It was revealed that the predominant mechanism for creep highly depended on the applied stress level. At low stress level, both HPT and HPT+10A samples were dominated by Coble creep. At high stress level, however, the mechanism transformed to dislocation creep for HPT sample, but continued to be Coble creep for HPT+10A sample, leading to higher creep resistance in the HPT+10A sample.

• Journal of Advanced Marine Engineering and Technology
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• 제26권2호
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• pp.181-191
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• 2002

Spray calculation has been studied to understand the behavior of the spray in a combustion chamber But the spray dispersion has not been predicted properly in a high velocity injection spray or a wall impaction spray. In this study the extended grazing collision model is applied to improve the problem. The gas phase is modelled by the Eulerian continuum conservation equations of mass, momentum, energy and fuel vapour fraction. The liquid phase is modelled following the discrete droplet model approach in Lagrangian form. The droplet distributions, penetration, width and gas flows are compared for the cases with or without extended model. The extended collision model makes the results better.

• Nuclear Engineering and Technology
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• 제54권1호
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• pp.72-83
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• 2022

This paper presents a numerical investigation of two-phase natural circulation flows established when external reactor vessel cooling is applied to a severe accident of the APR1400 reactor for the in-vessel retention of the core melt. The coolability limit due to external reactor vessel cooling is associated with the natural circulation flow rate around the lower head of the reactor vessel. For an elaborate prediction of the natural circulation flow rate using a thermal-hydraulic system code, MARS-KS1.5, a three-dimensional computational fluid dynamics (CFD) simulation is conducted to estimate the flow rate and pressure distribution of a liquid-state coolant at the brink of significant void generation. The CFD calculation results are used to determine the loss coefficient at major flow junctions, where substantial pressure losses are expected, in the nodalization scheme of the MARS-KS code such that the single-phase flow rate is the same as that predicted via CFD simulations. Subsequently, the MARS-KS analysis is performed for the two-phase natural circulation regime, and the transient behavior of the main thermal-hydraulic variables is investigated.