• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.5
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• pp.47-53
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• 2000

To overcome the shortage of conventional TWC that is activated at high temperature, higher than 25$0^{\circ}C$, photocatalyst is considered as an new technology. Because the photocatalytic reaction of photocatalyst is not a thermo mechanical reaction, it is necessary to heat the system to start the reaction. It can be activated just by ultra violet light that includes wavelengths shorter than 400 nanometers even at ambient temperature. In this study photocatalytic reduction of hydrocarbon was investigated with a model gas test. To understand the effects of co-existence gases on the hydrocarbon reduction by photoreaction, CO and NO, $O_2, H_2O$ gases those are components of exhaust gases of gasoline engine are supplied with C3H8/N2 to a photoreactor. The photoreactor contains $TiO_2$ photocatalyst powders and a UV bulb. The results show that oxygen is the most important factor to reduce HC emission with photocatalyst. Photocatalyst seems to have a good probability for automotive application to reduce cold start HC emissions.

• International Journal of Automotive Technology
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• v.7 no.6
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• pp.675-680
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• 2006

In the direct injected gasoline engine, atomized spray is desired to achieve efficient mixture formation needed to good engine performance because the injection process leaves little time for the evaporation of fuels. Therefore, substantial understanding of global spray structure and quantitative characteristics of spray are decisive technology to optimize combustion system of a GDI engine. The combustion and emission characteristics of gasoline-fueled stratified-charge compression ignition(SCCI) engine according to intake temperature and compression ratio was examined. The fuel was injected directly to the cylinder under the high temperature condition resulting from heating the intake port. With this injection strategy, the SCCI combustion region was expanded dramatically without any increase in NOx emissions, which were seen in the case of compression stroke injection. Injection timing during the intake temperature was found to be an important parameter that affects the SCCI region width. The mixture stratification and the fuel reformation can be utilized to reduce the required intake temperature for suitable SCCI combustion under each set of engine speed and compression ratio conditions.

• Journal of Powder Materials
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• v.20 no.3
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• pp.221-227
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• 2013

$TiB_2$-reinforced iron matrix composite (Fe-$TiB_2$) powder was in-situ fabricated from titanium hydride ($TiH_2$) and iron boride (FeB) powders by the mechanical activation and a subsequent reaction. Phase formation of the composite powder was identified by X-ray diffraction (XRD). The morphology and phase composition were observed and measured by field emission-scanning electron microscopy (FE-SEM) and energy-dispersive X-ray spectroscopy (EDS), respectively. The results showed that $TiB_2$ particles formed in nanoscale were uniformly distributed in Fe matrix. $Fe_2B$ phase existed due to an incomplete reaction of Ti and FeB. Effect of milling process and synthesis temperature on the formation of composite were discussed.

• Journal of the Korean Society of Combustion
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• v.14 no.4
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• pp.7-16
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• 2009

Porous metal plates (Metal fiber, muti-hole metal plate) using mainly in surface burner are known to have a corrosion and durability problem under high temperature condition. In this study, premixed flat flame with perforated ceramic tile of more durable cordierite material was examined with respect to combustion stability and emission. The flat premixed ceramic burner consists of perforated ceramic tile and various type of baffle plates to form stable surface flame. The results show that most stable flat flame is generated using baffle plate with open ratio of 0.193. In downward flat flame mode which is widely used in condensing boiler, CO is measured below 50ppm from equivalence ratio 0.755 to 0.765 and $NO_X$ is measured below 12ppm from equivalence ratio 0.75 to 0.79. It is also found that the range of blue flame in flame stability curve becomes wider with increasing heat capacity.

• KIEAE Journal
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• v.10 no.1
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• pp.19-24
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• 2010

Modern people are spending most of time in interior area. Indoor air environmental problem is one of the most effective factors influenceable to human health. Furthermore, saving energy and making ventilation system for pleasant indoor environment are necessary when it is faced shortage of energy over the world. In our country's case, it is already imposed that required quantity of air ventilation in buildings is 0.7 times per hour on "The regulation on building engineering system". As on the rise of the interests about Indoor air environment, Heat and Carbon dioxide emissions from User's metabolism, activity, furniture, and construction materials etc. could be the causes of Indoor air pollution. If these materials stays in Indoor air for so long, it could directly influence the user's health condition with a disease. As of building's sterilization improved that raised more mechanical ventilation. It also leads much energy waste in a period of high price of fossil fuel. Therefore, the way that saves energy and effective control of indoor ventilation is urgently needed. So, this study places the purpose on validating volume of indoor ventilation and user's comfortable degree by comparison CO2 emission rate through changing floor temperature.

• Korean Journal of Materials Research
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• v.16 no.10
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• pp.624-628
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• 2006

In this study, divalent europium-activated $NaCaPO_4$ green phosphor powders were prepared by the chemical synthetic method followed by heat treatment in reduced atmosphere, and the crystal structures, morphologies and photoluminescent properties of the powders were investigated by x-ray powder diffraction, scanning electron microscope and spectrometer for the first time. The effects of Ca/P and Na/Ca mole ratios on the final products were also investigated. The influences of input amount change of europium as the activator on the light emission intensity were studied, and the resulting concentration quenching phenomenon was observed. The optimized synthesis conditions obtained in this study were Ca/P mole ratio 1.2, Na/Ca mole ratio 3.0 and 4 mole%Eu. The peak wavelength was 505 nm for all the samples. The result of excitation spectrum measurement indicated that the excitation efficiency was high for the long-wavelength UV region. It was thus concluded that the samples prepared in this study can be successfully applied for the light-emitting devices such as LED excited with long-wavelength UV light sources.

• Bulletin of the Korean Chemical Society
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• v.19 no.9
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• pp.927-933
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• 1998

Polycrystalline powder of vanadium-doped forsterite (Vδ $Mg_2SiO_4$) was synthesized by the $H_2O_2$-assisted sol-gel method. The vanadium dopant, which was added as VO$(OMe)_3$ in methanol, went through several redox reactions as the sol-gel reaction proceeded. Upon adding VO$(OMe)_3$ to a mixture of $Mg(OMe)_2$ and Si$(OEt)_4$ in methanol, V(V) reduced to V(IV). As hydrolysis reaction proceeded, the V(IV) oxidized all back to V(V). Apparently, some of the V(V) reduced to V(IV) during subsequent gelation by condensation reaction. The V(IV) remained even after heat treatment of the gel in highly oxidizing atmosphere. The crystallization of the xerogel around 880 ℃ readily produced single phase forsterite without any minor phase. Using the polycrystalline powder as feeding stock, single crystals of vanadium-doped forsterite were grown by the floating zone method in oxidizing or reducing atmosphere. The doping was limited in low level because of the high partitioning of the vanadium in liquid phase during melting. The greenish single crystal absorbed visible light of 700∼1100 nm. But, no emission was obtained in near infrared range.

• Journal of Ceramic Processing Research
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• v.20 no.4
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• pp.411-417
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• 2019

Graphene doped zinc oxide nanoparticles (G-ZnO) were prepared using modified hummer's technique together with the ultrasonic method and characterized by field emission scanning electron microscopy (FESEM), X-ray powder diffraction (XRD), fourier-transform infrared spectroscopy (FTIR) and high-resolution transmission electron microscopy (HRTEM). Different samples of epoxy resin nanocomposites reinforced with G-ZnO nanoparticles were prepared and were marked as F1 (without adding nanoparticles), F2 (1% w/w G-ZnO), and F3 (2% w/w G-ZnO) in combination of ≈ 56:18:18:8w/w% with epoxy resin/hardener, ammonium polyphosphate, boric acid, and Chitosan. The peak heat release rate (PHRR) of the epoxy nanocomposites was observed to decrease dramatically with the increasing G-ZnO nanoparticles. However, the LOI values increased significantly with the increase in wt % of G-ZnO nanoparticles. From the UL-94V data, it was confirmed that the F2 and F3 samples passed the flame test and were rated as V-0. The results obtained in the present work clearly revealed that the synthesized samples can be used as efficient materials in fire-retardant coating technology.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.477-477
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• 2008

For more than three decades, the gate dielectrics in CMOS devices are $SiO_2$ because of its blocking properties of current in insulated gate FET channels. As the dimensions of feature size have been scaled down (width and the thickness is reduced down to 50 urn and 2 urn or less), gate leakage current is increased and reliability of $SiO_2$ is reduced. Many metal oxides such as $TiO_2$, $Ta_2O_4$, $SrTiO_3$, $Al_2O_3$, $HfO_2$ and $ZrO_2$ have been challenged for memory devices. These materials posses relatively high dielectric constant, but $HfO_2$ and $Al_2O_3$ did not provide sufficient advantages over $SiO_2$ or $Si_3N_4$ because of reaction with Si substrate. Recently, $HfO_2$ have been attracted attention because Hf forms the most stable oxide with the highest heat of formation. In addition, Hf can reduce the native oxide layer by creating $HfO_2$. However, new gate oxide candidates must satisfy a standard CMOS process. In order to fabricate high density memories with small feature size, the plasma etch process should be developed by well understanding and optimizing plasma behaviors. Therefore, it is necessary that the etch behavior of $HfO_2$ and plasma parameters are systematically investigated as functions of process parameters including gas mixing ratio, rf power, pressure and temperature to determine the mechanism of plasma induced damage. However, there is few studies on the the etch mechanism and the surface reactions in $BCl_3$ based plasma to etch $HfO_2$ thin films. In this work, the samples of $HfO_2$ were prepared on Si wafer with using atomic layer deposition. In our previous work, the maximum etch rate of $BCl_3$/Ar were obtained 20% $BCl_3$/ 80% Ar. Over 20% $BCl_3$ addition, the etch rate of $HfO_2$ decreased. The etching rate of $HfO_2$ and selectivity of $HfO_2$ to Si were investigated with using in inductively coupled plasma etching system (ICP) and $BCl_3/Cl_2$/Ar plasma. The change of volume densities of radical and atoms were monitored with using optical emission spectroscopy analysis (OES). The variations of components of etched surfaces for $HfO_2$ was investigated with using x-ray photo electron spectroscopy (XPS). In order to investigate the accumulation of etch by products during etch process, the exposed surface of $HfO_2$ in $BCl_3/Cl_2$/Ar plasma was compared with surface of as-doped $HfO_2$ and all the surfaces of samples were examined with field emission scanning electron microscopy and atomic force microscope (AFM).

• Journal of Hydrogen and New Energy
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• v.28 no.1
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• pp.56-62
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• 2017

Although most electricity production contributes to air pollution, the vehicle organizations and environmental agency categorizes all EVs as zero-emission vehicles because they produce no direct exhaust or emissions. Currently available EVs have a shorter range per charge than most conventional vehicles have per tank of gas. EVs manufacturers typically target a range of 160 km over on a fully charged battery. The energy efficiency and driving range of EVs varies substantially based on driving conditions and driving habits. Extreme outside temperatures tend to reduce range, because more energy must be used to heat or cool the cabin. High driving speeds reduce range because of the energy required to overcome increased drag. Compared with gradual acceleration, rapid acceleration reduces range. Additional devices significant inclines also reduces range. Based on these driving modes and climate conditions, this paper discusses the performance characteristics of EVs on energy efficiency and driving range. Test vehicles were divided by low / high-speed EVs. The difference of test vehicles are on the vehicle speed and size. Low-speed EVs is a denomination for battery EVs that are legally limited to roads with posted speed limits as high as 72 km/h depending on the particular laws, usually are built to have a top speed of 60 km/h, and have a maximum loaded weight of 1,400 kg. Each vehicle test was performed according to the driving modes and test temperature ($-25^{\circ}C{\sim}35^{\circ}C$). It has a great influence on fuel efficiency amd driving distance according to test temperature conditions.