• Title/Summary/Keyword: High emission

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Improving the Long-term Field Emission Stability of Carbon Nanotubes by Coating Co and Ni Oxide Layers

  • Choe, Ju-Seong;Lee, Han-Seong;Lee, Nae-Seong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.18.1-18.1
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    • 2011
  • Some applications of carbon nanotubes (CNTs) as field emitters, such as x-ray tubes and microwave amplifiers, require high current emission from a small emitter area. To emit the high current density, CNT emitters should be optimally fabricated in terms of material properties and morphological aspects including high crystallinity, aspect ratio, distribution density, height uniformity, adhesion on a substrate, low outgassing rate during electron emission in vacuum, etc. In particular, adhesion of emitters on the substrate is one of the most important parameters to be secured for high current field emission from CNTs. So, we attempted a novel approach to improve the adhesion of CNT emitters by incorporating metal oxide layers between CNT emitters. In our previous study, CNT emitters were fabricated on a metal mesh by filtrating the aqueous suspensions containing both highly crystalline thin multiwalled CNTs and thick entangled multiwalled CNTs. However, the adhesion of CNT film was not enough to produce a high emission current for an extended period of time even after adopting the metal mesh as a fixing substrate of the CNT film. While a high current was emitted, some part of the film was shown to delaminate. In order to strengthen the CNT networks, cobalt-nickel oxides were incorporated into the film. After coating the oxide layer, the CNT tips seemed to be more strongly adhered on the CNT bush. Without the oxide layer, the field emission voltage-current curve moved fast to a high voltage side as increasing the number of voltage sweeps. With the cobalt-nickel oxide incorporated, however, the curve does not move after the second voltage sweep. Such improvement of emission properties seemed to be attributed to stronger adhesion of the CNT film which was imparted by the cobalt-nickel oxide layer between CNT networks. Observed after field emission for an extended period of time, the CNT film with the oxide layer showed less damage on the surface caused by high current emission.

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Quantified Contribution of High Emitting Vehicles to Emission Inventories for Gasoline Passenger Cars based on Inspection and Maintenance Program Data (운행차 배출가스 정밀검사 결과를 이용한 휘발유 승용차 대기오염물질 배출량 중 고농도 배출 차량의 기여도 분석)

  • Lee, Tae-Woo;Kim, Ji-Young;Lee, Jong-Tae;Kim, Jeong-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.4
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    • pp.396-410
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    • 2012
  • The purpose of this study is to quantify the contribution of high emitting vehicles to mobile emission inventories. Analyzed emission data include $NO_x$, HC, and CO results, which were measured through the vehicle Inspection and Maintenance (I/M) program in Seoul metropolitan area. The high emitting vehicles were identified as the top 5% worst polluting cars of the fleet. We estimated that 5% of the gasoline passenger car fleet, which is high emitters, generated 25.5% of $NO_x$, 34.5% of HC, and 66.1% of CO emissions of total inventories for gasoline passenger car fleet in year 2010. In the study, we identified that the older vehicles (older than ten years) and high mileage vehicles (more than 120,000 km driven) comprised high emitter fleet with 70.9% and 71.2%, respectively. The emission contribution of high emitters became larger in younger fleet than in the older fleet. This is due to the reduced emission rates in newly manufactured vehicles, which were developed under the more stringent emission regulation limits. This analysis implies that high emitters could be responsible for an even larger fraction of total vehicular emissions as more advanced technology vehicles are being incorporated into the current vehicle fleet. The findings suggested that the high emitting vehicles should be primarily considered for in-use vehicle emission management program, such as I/M, accelerated vehicle retirement, or catalytic converter replacement, in order to enhance the effectiveness of selected program.

Evaluations for Representativeness of Light-Duty Diesel Vehicles' Fuel-based Emission Factors on Vehicle Operating Conditions (연료 소비량에 기반한 소형 경유차 대기오염물질 배출계수의 운전조건별 대표성 평가)

  • Lee, Taewoo;Kwon, Sangil;Son, Jihwan;Kim, Jiyoung;Jeon, Sangzin;Kim, Jeongsoo;Choi, Kwangho
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.6
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    • pp.745-756
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    • 2013
  • The purpose of this study is to evaluate representativeness of fuel-based emission factors. Twelve light-duty diesel vehicles which meet Euro-3 to 5 legislative emission limits were selected for emission tests. Second-by-second modal emission rates of vehicles were measured on a standard laboratory chassis dynamometer system. An off-cycle driving cycle was developed as a representative Korean real-world on-road driving cycle. Fuel-based emission factors were developed for short trip segments that involved in the selected driving cycle. Each segment was defined to have unit travel distance, which is 1 km, and characterized by its average speed and Relative Positive Acceleration (RPA). Fuel-based $NO_x$ emission factors demonstrate relatively good representativeness in terms of vehicle operation conditions. $NO_x$ emission factors are estimated to be within ${\pm}20%$ of area-wide emission factor under more than 40% of total driving situations. This result implies that the fuel-based $NO_x$ emission factor could be practically implemented into the on-road emission management strategies, such as a remote sensing device (RSD). High emitting vehicles as well as high emitting operating conditions heavily affect on the mean values and distributions of CO and THC emission factors. Few high emitting conditions are pulling up the mean value and biasing the distributions, which weaken representativeness of fuel-based CO and THC emission factors.

Investigation of field emission mechanism of undoped polyucrystalline diamond films

  • Shim, Jae-Yeob;Chi, Eung-Joon;Song, Kie-Moon;Baik, Hong-Koo
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.62-62
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    • 1999
  • Carbon based materials have many attractive properties such as a wide band gap, a low electron affinity, and a high chemical and mechanical stability. Therefore, researches on the carbon-based materials as field emitters have been drawn extensively to enhance the field emission properties. Especially, diamond gives high current density, high current stability high thermal conductivity durable for high temperature operation, and low field emission behaviors, Among these properties understanding the origin of low field emission is a key factor for the application of diamond to a filed emitter and the verification of the emission site and its distribution of diamond is helpful to clarify the origin of low field emission from diamond There have been many investigations on the origin of low field emission behavior of diamond crystal or chemical vapor deposition (CVD) diamond films that is intentionally doped or not. However, the origin of the low field emission behavior and the consequent field emission mechanism is still not converged and those may be different between diamond crystal and CVD diamond films as well as the diamond that is doped or not. In addition, there have been no systematic studies on the dependence of nondiamond carbon on the spatial distribution of emission sites and its uniformity. Thus, clarifying a possible mechanism for the low field emission covering the diamond with various properties might be indeed a difficult work. On the other hand, it is believed that electron emission mechanisms of diamond are closely related to the emission sites and its distributions. In this context, it will be helpful to compare the spatial distribution of emission sites and field emission properties of the diamond films prepared by systematic variations of structural property. In this study, we have focused on an understanding of the field emission variations of structural property. In this study, we have focused on an understanding of the field emission mechanism for the CVD grown undoped polycrystalline diamond films with significantly different structural properties. The structural properties of the films were systematically modified by varying the CH4/H2 ratio and/or applying positive substrate bias examined. It was confirmed from the present study that the field emission characteristics are strongly dependent on the nondiamond carbon contents of the undoped polycrystalline diamond films, and a possible field emission mechanism for the undoped polycrystalline diamond films is suggested.

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Exhaust Emission Characteristics of in-use Passenger Cars Equipped with Three-way Catalyst (운행중인 삼원촉매부착 승용차의 오염물질 배출특성)

  • 조강래;김종춘;홍유덕
    • Journal of Korean Society for Atmospheric Environment
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    • v.11 no.2
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    • pp.153-162
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    • 1995
  • As exhaust emission standards for new passenger cars amended in 1987 have become more stringent, vehicle manufacturers have employed three-way catalyst in order to meet these requirements. The purpose of this study was to gather informations on new emission control systems in customer use for in-use vehicles from the 1987 through 1992 model years were capable of achieving low exhaust emission levels although high levels do occur due to defects, deterioration or maladjustments with the emission control equipment. The vehicles with closed loop electronic control fuel injection system emitted low exhaust emission, but the carburetor control system equipped vehicles emitted high exhaust emissions and the high mileage vehicles exhibited higher average emissions than low mileage vehicles. It was also found that the useful life of 80, 000km is very important to maintain the low emission levels within customer service period.

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Design of partial emission type liquid nitrogen pump

  • Lee, Jinwoo;Kwon, Yonghyun;Lee, Changhyeong;Choi, Jungdong;Kim, Seokho
    • Progress in Superconductivity and Cryogenics
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    • v.18 no.1
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    • pp.64-68
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    • 2016
  • High Temperature Superconductor power cable systems are being developed actively to solve the problem of increasing power demand. With increases in the unit length of the High Temperature Superconductor power cable, it is necessary to develop highly efficient and reliable cryogenic pumps to transport the coolant over long distances. Generally, to obtain a high degree of efficiency, the cryogenic pump requires a high pressure rise with a low flow rate, and a partial emission type pump is appropriate considering its low specific speed, which is different from the conventional centrifugal type, full emission type. This paper describes the design of a partial emission pump to circulate subcooled liquid nitrogen. It consists of an impeller, a circular case and a diffuser. The conventional pump and the partial emission pump have different features in the impeller and the discharge flow passage. The partial emission pump uses an impeller with straight radial blades. The emission of working fluid does not occur continuously from all of the impeller channels, and the diffuser allows the flow only from a part of the impeller channels. As the area of the diffuser increases gradually, it converts the dynamic pressure into static pressure while minimizing the loss of total pressure. We used the known numerical method for the optimum design process and made a CFD analysis to verify the theoretical performance.

Regional Supply Strategies for Renewable Energy Sources based on Contribution Level of GHG Emission Reduction (신재생에너지의 온실가스감축 기여도에 따른 지역별 보급전략)

  • Kim, Hyun Seok
    • Current Research on Agriculture and Life Sciences
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    • v.32 no.4
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    • pp.215-223
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    • 2014
  • This study examines the contribution level of greenhouse gas(GHG) emission reduction and installation costs of renewable energy facilities. The GHG emission forecasts and industrial structures in the 16 regions of Korea are then analyzed to identify the proper supply of renewable energy sources for each region. The results show that water power is the most effective and efficient renewable energy source to reduce GHG emissions, followed by sunlight, wind power, geothermal heat, and solar heat, respectively. The 16 regions are then categorized into 4 groups based on their GHG emission forecast and industrial structure: high emission and manufacturing group, low emission and manufacturing group, low emission and service group, and high emission and service group. The proper supply of renewable energy sources for each group is then determined based on the contribution level and cost efficiency of GHG emission reduction.

Dyeing of High Strength and High Molecular Weight Polyethylene Fiber Using Super Hydrophobic Fluorescence Dyes (초소수성 형광염료에 의한 고강도/고분자량폴리에틸렌섬유의 염색)

  • Kim, Taekyeong;Park, Jihoon;Lee, Junheon;Kim, Taegun
    • Textile Coloration and Finishing
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    • v.29 no.4
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    • pp.223-230
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    • 2017
  • Three super hydrophobic fluorescence dyes were selected to dye high molecular weight polyethylene fiber and their molar absorptivity, emission spectrum, and quantum yield were measured. From the results of color strength on the fiber, all the three dyes exhibited linear increase according to the dye concentration and Fluoro3 dye showed the highest color strength among them. Emission strength of the fluorescence dyes on the fiber was investigated according to the dye concentrations. The emission was increased with the increase of the dye concentration at relatively low dye concentration and then after showing the maximum emission strength the emission was decreased at higher dye concentrations. The highest emission was obtained in Fluoro2 dye. Color fastness to washing and rubbing was generally good enough, however, especially to light, only Fluoro3 dye exhibited rating 3 acceptable practically and Fluoro1 and 2 was ratings 1 which is unacceptable level.

Experiment on the Characteristics of Jet Diffusion Flames with High Temperature Air Combustion (고온공기를 이용한 제트확산화염의 연소특성에 관한 실험)

  • Cho, Eun-Seong;Ohno, Ken;Kobayashi, Hideaki;Chung, Suk-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.3
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    • pp.359-364
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    • 2004
  • For the development of high efficiency and low emission combustion systems, high temperature air combustion technology has been tested by utilizing preheated air over 1100 K and exhaust gas recirculation. In this system, combustion air is diluted with large amount of recirculated exhaust gases, such that the oxygen concentration is relatively low in the reaction zone, leading to low flame temperature. Since, the temperature fluctuations and sound emissions from the flame are small and flame luminosity is low, the combustion mode is expected to be flameless or mild combustion. Experiment was performed to investigate the turbulent flame structure and NO$_x$ emission characteristics in the high temperature air combustion focused on coflowing jet diffusion flames which has a fundamental structure of many practical combustion systems. The effect of turbulence has also been evaluated by installing perforated plate in the oxidizer inlet nozzle. LPG was used as a fuel. Results showed that even though NO$_x$ emission is sensitive to the combustion air temperature, the present high temperature air combustion system produce low NO$_x$ emission because it is operated in low oxygen concentration condition by the high exhaust gas recirculation.

A Study on Quantity of CO2 Emission about Remodeling Cycle at High-rise Apartment housing (초고층 공동주택 세대내 개보수 주기에 따른 이산화탄소 배출량 연구)

  • Kim, Dayoo;Kang, Seungyi;Je, Haeseong
    • KIEAE Journal
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    • v.10 no.3
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    • pp.75-80
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    • 2010
  • The goal of this study is to figure out the remodeling cycle at high-rise apartment housing and to analysis on quantity of $CO_2$ emission about remodeling cycle. The process of research is as follow; 1) Estimate the remodeling cycle through survey targeting residents at high-rise apartment building. 2) Simulate conditions on the high-rise apartment housing. 3) Calculate quantity of energy consumption and $CO_2$ emission 4) Derive elements that are on high level of environmental load evaluation. The main results of this study is as follow; 1) The cycle of finishing such as wallpaper is shorter than the cycle of building equipment such as elements in a toilet. 2) According to result of calculating $CO_2$ emission, fabric wallpaper and mortar are main factors that impact on the environment. The results is important to show reference points on quantitative measuring evaluation for the environmental-friendly extent.